IP Library Granted Patent US 9,969,899
Granted Patent B2
US 9,969,899 · App. 14/177,784 · Granted May 15, 2018

Fluoropolymers containing a copolymerized fluoromonomer and a functional hydrocarbon comonomer and articles made from such fluoropolymers

Inventors: Alagappan Thenappan (Hackettstown, NJ); Bruno Ameduri (Montpellier, FR); Gerald Lopez (Lunel-Viel, FR); Eric Rainal (Morristown, NJ); Noureddine Ajellal (Montpellier, FR); Gary Martin (Piscataway, NJ)
Assignee: HONEYWELL INTERNATIONAL INC.
C09D127/12B32B27/08B32B27/304B32B27/308B32B27/322B32B27/36C08F214/18C08J5/18C08J7/047B32B2307/412B32B2307/714B32B2307/7265B32B2439/00B32B2439/80B32B2581/00B32B2597/00C08J2327/06C08J2327/12C08J2367/02C08J2379/08C08J2427/04C08J2427/12Y10T428/31507Y10T428/31544
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Quick Facts
Patent No.
US 9,969,899
App. No.
14/177,784
Granted
May 15, 2018
Kind
B2
Abstract

Disclosed is a copolymer film that includes a first comonomer including a chlorofluoro olefin and a second comonomer that is selected from the group consisting of itaconic acid, 2,3-dihydropyran, D-glucal, glycerine carbonate vinyl ether, 2-hydroxypropyl acrylate, maleic anhydride, vinylidene chloride, and mixtures thereof.

Claims (16)

1. A copolymer film comprising a copolymer that consists of a reaction product consisting of a first comonomer and a second comonomer, wherein:

the first comonomer is a chlorofluoro olefin;

the second comonomer is one of: D-glucal, glycerine carbonate vinyl ether, and 2-hydroxypropylacrylate; and

the first and second comonomers are randomly copolymerized in the copolymer.

2. The copolymer film of claim 1 , wherein the first comonomer is chlorotrifluoroethylene.

3. The copolymer film of claim 1 , wherein the copolymer film is disposed on an article, and wherein the article is a pharmaceutical packaging product.

4. A coated substrate packaging film comprising:

a substrate comprising polyvinyl chloride (PVC) or polyethylene terephthalate (PET) or polyethylene naphthalate (PEN) or polyimide; and

a copolymer in the form of a copolymer film coated on at least one surface of the substrate, the copolymer consisting of a reaction product consisting of a first comonomer and a second comonomer, wherein the first comonomer is a chlorofluoro olefin, wherein the second comonomer is one of: D-glucal, glycerine carbonate vinyl ether, and 2-hydroxypropylacrylate, and wherein the first and second comonomers are randomly copolymerized in the copolymer.

5. The coated substrate of claim 4 , wherein the first comonomer is chlorotrifluoroethylene.

6. The coated substrate of claim 4 , wherein the copolymer is applied on at least two surfaces of the substrate.

7. A copolymer film comprising:

a first comonomer that comprises chlorotrifluoroethylene (CTFE); and

a second comonomer that comprises either D-glucal or glycerine carbonate vinyl ether,

wherein the first and second comonomers are randomly copolymerized.

8. The copolymer film of claim 7 , wherein the copolymer film is disposed on an article, and wherein the article is a pharmaceutical packaging product.

Assignments (5)
NUNC PRO TUNC ASSIGNMENT Recorded Apr 13, 2026
From: HONEYWELL INTERNATIONAL INC.
To: SOLSTICE ADVANCED MATERIALS US, INC.
Reel/Frame 074351/0018 →
SECURITY INTEREST Recorded Jan 12, 2026
From: SOLSTICE ADVANCED MATERIALS US, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 074569/0260 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY DATA PREVIOUSLY RECORDED AT REEL: 034832 FRAME: 0930. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jul 20, 2015
From: AMEDURI, BRUNO; LOPEZ, GERALD; AJELLAL, NOUREDDINE
To: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
Reel/Frame 036139/0058 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 28, 2015
From: THENAPPAN, ALGAPPAN; RAINAL, ERIC; MARTIN, GARY
To: HONEYWELL INTERNATIONAL INC.
Reel/Frame 034832/0862 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 28, 2015
From: AMEDURI, BRUNO; LOPEZ, GERALD; AJELLAL, NOUREDDINE
To: HONEYWELL INTERNATIONAL INC.
Reel/Frame 034832/0930 →
Continuity (2)
Provisional Application 61765964 · Feb 18, 2013
Related Publication 20140234630A1 · Aug 21, 2014