Positive active material and rechargeable lithium battery including same
The present invention provides a positive active material including a lithium-containing compound represented by the following Chemical Formula 1 and a rechargeable lithium battery including the positive active material. LiFe 1-x-z M x M′ z P y O 4 . Chemical Formula 1
1. A positive active material comprising a lithium-containing compound represented by the following Chemical Formula 1:
LiFe 1-x-z M x M′ z P y O 4 Chemical Formula 1
wherein, M is vanadium (V), M′ is cobalt (Co), manganese (Mn), magnesium (Mg), zirconium (Zr), nickel (Ni), or a combination thereof, and about 0<x<about 0.20, about 0≤z<about 0.20, and about 0.90<y<about 1.20,
wherein the lithium-containing compound comprises secondary particles formed of agglomerated primary particles, the secondary particles having a particle size in the range of about 5 μm to about 30 μm, and wherein x and z have a ratio of about 0.5≤x/z≤about 5.
2. The positive active material of claim 1 , wherein x and y have a ratio of about 0.009≤x/y≤ about 0.07.
3. The positive active material of claim 1 , wherein x and y have a ratio of about 0.03≤x/y≤ about 0.07.
4. The positive active material of claim 1 , wherein x and y have an x/y ratio of about 0.05.
5. The positive active material of claim 1 , wherein M is vanadium (V) and M′ is cobalt (Co).
6. The positive active material of claim 1 , wherein the lithium-containing compound is selected from the group consisting of LiFe 0.96 V 0.05 Co 0.01 PO 4 , LiFe 0.925 V 0.05 Co 0.025 PO 4 , LiFe 0.9 V 0.05 Co 0.05 PO 4 , and combinations thereof.
7. The positive active material of claim 1 , wherein a particle size of the primary particles is in a range of about 50 nm to about 1000 nm.
8. The positive active material of claim 7 , wherein the particle size of the primary particles is in a range of about 50 nm to about 200 nm.
9. A rechargeable lithium battery comprising a positive electrode comprising the positive active material according to claim 1 , a negative electrode, and an electrolyte.
10. The positive active material of claim 1 , wherein 1.03≤y< about 1.20.
11. The positive active material of claim 1 , wherein x and y have a ratio of about 0.048≤x/y≤ about 0.07.
12. A positive active material comprising a lithium-containing compound represented by the following Chemical Formula 1:
LiFe 1-x-z M x M′ z P y O 4 Chemical Formula 1
wherein, M is vanadium (V), M′ is cobalt (Co), manganese (Mn), magnesium (Mg), zirconium (Zr), nickel (Ni), or a combination thereof, and about 0<x<about 0.20, about 0≤z<about 0.20, and about 0.90<y<about 1.20,
wherein the lithium-containing compound comprises secondary particles formed of agglomerated primary particles, the secondary particles having a particle size in the range of about 5 μm to about 30 μm, and wherein x and z have an x/z ratio of about 2.