Composition for solar cell electrode and electrode prepared using the same
A composition for solar cell electrodes and a solar cell electrode, the composition including silver powder; glass frit that contains tellurium, the glass frit having a glass transition temperature (Tg) of about 150° C. to about 300° C.; an organosilane compound; and an organic vehicle.
1. A composition for solar cell electrodes, the composition comprising:
about 60 wt % to about 95 wt % of silver powder;
about 0.1 wt % to about 20 wt % of a glass frit that contains tellurium, the glass frit having a glass transition temperature (Tg) of about 150° C. to about 300° C.;
about 0.01 wt % to about 3 wt % of an organosilane compound; and
about 1 wt % to about 30 wt % of an organic vehicle.
2. The composition as claimed in claim 1 , wherein the glass frit is a Bi—Te—O-containing glass frit and contains about 50 mole % to about 90 mole % of elemental tellurium (Te).
3. The composition as claimed in claim 2 , wherein, in the Bi—Te—O-containing glass frit, a mole ratio of bismuth (Bi) to tellurium (Te) is about 1:1.5 to about 1:3.5.
4. The composition as claimed in claim 2 , wherein the Bi—Te—O-containing glass frit further includes lithium (Li), phosphorus (P), germanium (Ge), gallium (Ga), cerium (Ce), iron (Fe), silicon (Si), zinc (Zn), tungsten (W), magnesium (Mg), cesium (Cs), strontium (Sr), molybdenum (Mo), titanium (Ti), tin (Sn), indium (In), vanadium (V), barium (Ba), nickel (Ni), copper (Cu), sodium (Na), potassium (K), arsenic (As), cobalt (Co), zirconium (Zr), manganese (Mn), or aluminum (Al).
5. The composition as claimed in claim 2 , wherein the glass frit contains about 5 mole % to about 20 mole % of elemental bismuth (Bi).
6. The composition as claimed in claim 1 , wherein the glass frit is a lead-free glass frit.
7. The composition as claimed in claim 1 , wherein the organosilane compound includes a siloxane compound represented by the following Formula 1:
wherein, in Formula 1, R 1 to R 3 are each independently a C 1 to C 6 alkyl group, an ether group, an amino group, a hydroxyl group, a fluoroalkyl group, a phenyl group, an epoxy group, or a carboxyl group, and y is an integer from 0 to 3,000.
8. The composition as claimed in claim 7 , wherein the glass frit and the organosilane compound are included in the composition in a weight ratio of about 1:0.005 to about 1:30.
9. The composition as claimed in claim 1 , wherein the glass frit has an average particle diameter (D50) of about 0.1 μm to about 10 μm.
10. The composition as claimed in claim 1 , further comprising a thixotropic agent, a viscosity stabilizer, an anti-foaming agent, a pigment, a UV stabilizer, an antioxidant, or a coupling agent.
11. A solar cell electrode prepared from the composition for solar cell electrodes as claimed in claim 1 .
12. The solar cell electrode as claimed in claim 11 , wherein the solar cell electrode has an aspect ratio of about 0.1 to about 0.3, as represented by the following equation:
Aspect ratio= D 1/ L 3
wherein D1 is a thickness in μm of the electrode after baking and L3 is a line width in of the electrode after baking.