Fluorine-containing polymer powder, film, and method for producing fluorine-containing polymer powder
The present invention aims to provide a fluorine-containing polymer powder that is environmentally less harmful and forms a sufficiently smooth film without impairing the properties of the fluorine-containing polymers. The present invention relates to a fluorine-containing polymer powder including a fluorine-containing polymer prepared by suspension polymerization, which contains less than 0.1 ppm of a fluorine-containing surfactant and has an average particle size of not less than 1 μm and less than 100 μm and a bulk density of 0.90 to 1.50 g/cm 3 .
1. A method for producing a fluorine-containing polymer powder comprising a fluorine-containing polymer prepared by suspension polymerization,
wherein the fluorine-containing polymer powder contains less than 0.1 ppm of a fluorine-containing surfactant and has an average particle size of at least 100 μm but at most 1000 μm and a bulk density of 1.00 to 1.50 g/cm 3 ,
wherein the fluorine-containing polymer is at least one selected from the group consisting of tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymers, tetrafluoroethylene-hexafluoropropylene copolymers, and tetrafluoroethylene-ethylene copolymers,
wherein the tetrafluoroethylene-perfluoro (alkyl vinyl ether) copolymer is a copolymer in which the molar ratio of tetrafluoroethylene (TFE) unit and perfluoro (alkyl vinyl ether)(PAVE) unit (TFE unit/PAVE unit) is 80/20 to 98/2, and
(i) consists of TFE unit and PAVE unit, or
(ii) comprises TFE unit, PAVE unit and a monomer unit derived from a monomer copolymerizable with TFE and PAVE wherein the total of the TFE unit and PAVE unit is 90 to 99.9 mol % and the monomer unit derived from a monomer copolymerizable with TFE and PAVE is 0.1 to 10 mol %,
wherein tetrafluoroethylene-hexafluoropropylene copolymer is a copolymer in which the molar ratio of TFE unit and hexafluoropropylene (HFP) unit (TFE unit/HFP unit) is 80/20 to 97/3, and
(iii) consists of TFE unit and HFP unit, or
(iv) comprises TFE unit, HFP unit and a monomer unit derived from a monomer copolymerizable with TFE and HFP wherein the total of the TFE unit and HFP unit is 90 to 99.9 mol % and the monomer unit derived from a monomer copolymerizable with TFE and HFP is 0.1 to 10 mol %, and
wherein the fluorine-containing polymer is a melt-processible fluorine resin,
the method comprising:
polymerizing fluorine-containing ethylenic monomers by suspension polymerization to prepare fluorine-containing polymer powder;
optionally densifying the polymer powder with a roll mill under the conditions that enable the specific gravity of the resulting powder to reach at least 90% of the absolute specific gravity, to prepare ground powder;
putting the polymer powder or ground powder into an attrition mill;
processing the polymer powder or ground powder into a desired shape; and
collecting the fluorine-containing polymer powder from the attrition mill.