Bifunctional acid monolayers for the selective placement of carbon nanotubes
Techniques for selective placement of carbon nanotubes using bifunctional acid monolayers are provided. In one aspect, a method for selective placement of carbon nanotubes on a metal oxide surface includes the steps of: dispersing poly-fluorene polymer-wrapped carbon nanotubes in an organic solvent; creating a patterned monolayer of a bifunctional acid on the metal oxide surface, wherein the bifunctional acid comprises a first acid functional group for binding to the metal oxide surface, and a second acid functional group for binding to the poly-fluorene polymer-wrapped carbon nanotubes; and contacting the poly-fluorene polymer-wrapped carbon nanotubes dispersed in the organic solvent with the patterned monolayer of the bifunctional acid on the metal oxide surface to selectively place the carbon nanotubes on the metal oxide surface via the patterned monolayer of the bifunctional acid. A carbon nanotube-based device and method of formation thereof are also provided.
1. A method for selective placement of carbon nanotubes on a metal oxide surface, the method comprising the steps of:
dispersing poly-fluorene polymer-wrapped carbon nanotubes in an organic solvent, wherein the organic solvent is selected from the group consisting of: toluene, dichloroethane, and combinations thereof;
creating a patterned monolayer of a bifunctional acid on the metal oxide surface, wherein the bifunctional acid comprises a first acid functional group for binding to the metal oxide surface, and a second acid functional group for binding to the poly-fluorene polymer-wrapped carbon nanotubes; and
contacting the poly-fluorene polymer-wrapped carbon nanotubes dispersed in the organic solvent with the patterned monolayer of the bifunctional acid on the metal oxide surface to selectively place the carbon nanotubes on the metal oxide surface via the patterned monolayer of the bifunctional acid.
2. The method of claim 1 , wherein the metal oxide surface comprises hafnium oxide.
3. The method of claim 1 , wherein the poly-fluorene polymer is selected from the group consisting of: poly[9,9-dioctylfluorenyl-2,7-diyl], poly[9,9-dihexylfluorenyl-2,7-diyl], poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-phenylene)], poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(1,4-benzo-2,1′,3-thiadiazole)], poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(2,2′-bipyridine-5,5′-diyl)] and combinations thereof.
4. The method of claim 1 , further comprising the step of:
contacting the carbon nanotubes, the poly-fluorene polymer, and the organic solvent to form the poly-fluorene polymer-wrapped carbon nanotubes dispersed in the organic solvent.
5. The method of claim 1 , wherein the first acid functional group is hydroxamic acid or phosphonic acid.
6. The method of claim 1 , wherein the second acid functional group is carboxylic acid, phosphoric acid, or sulfonic acid.
7. The method of claim 1 , wherein the patterned monolayer of a bifunctional acid is created on the metal oxide surface using microcontact printing.
8. The method of claim 1 , further comprising the step of:
removing the carbon nanotubes from bare portions of the metal oxide surface.
9. The method of claim 8 , wherein the carbon nanotubes are removed from the bare portion of the metal oxide surface using sonication.
10. A method for forming a carbon nanotube-based device, the method comprising the steps of:
dispersing poly-fluorene polymer-wrapped carbon nanotubes in an organic solvent, wherein the organic solvent is selected from the group consisting of: toluene, dichloroethane, and combinations thereof;
providing a substrate comprising a metal oxide layer;
creating a patterned monolayer of a bifunctional acid on the metal oxide layer, wherein the bifunctional acid comprises a first acid functional group for binding to the metal oxide layer, and a second acid functional group for binding to the poly-fluorene polymer-wrapped carbon nanotubes;
contacting the poly-fluorene polymer-wrapped carbon nanotubes dispersed in the organic solvent with the patterned monolayer of the bifunctional acid on the metal oxide layer to selectively place the carbon nanotubes on the metal oxide layer via the patterned monolayer of the bifunctional acid; and
forming metal contacts to the poly-fluorene polymer-wrapped carbon nanotubes.
11. The method of claim 10 , wherein the poly-fluorene polymer is selected from the group consisting of: poly[9,9-dioctylfluorenyl-2,7-diyl], poly[9,9-dihexylfluorenyl-2,7-diyl], poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-phenylene)], poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(1,4-benzo-2,1′,3-thiadiazole)], poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(2,2′-bipyridine-5,5′-diyl)] and combinations thereof.
12. The method of claim 10 , wherein the first acid functional group is hydroxamic acid or phosphonic acid.
13. The method of claim 10 , wherein the second acid functional group is carboxylic acid, phosphoric acid, or sulfonic acid.
14. The method of claim 1 , wherein the poly-fluorene polymer is poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(2,2′-bipyridine-5,5′-diyl)].