Colored resin particle dispersion, method for producing same, and inkjet ink
A colored resin particle dispersion and an inkjet ink are provided which preferably exhibit excellent rub fastness and alcohol resistance, and yield printed items having high image density. Specifically, a colored resin particle dispersion includes colored resin particles, a basic dispersant and a non-aqueous solvent. The colored resin particles include a colorant, a thermoplastic solid resin and a liquid organic compound having an acidic group, and the thermoplastic solid resin has a polar parameter δp and a hydrogen bonding parameter δh from the Hansen solubility parameters that satisfy δp=2.5 to 11.0 and δh=5.0 to 12.0 respectively is provided.
1. A colored resin particle dispersion comprising colored resin particles, a dispersant and a non-aqueous solvent,
wherein the colored resin particles comprise a colorant, a thermoplastic solid resin and a liquid organic compound having an acidic group, a basic group, or a combination thereof,
the liquid organic compound has at least the acidic group when the dispersant is a basic dispersant, and the liquid organic compound has at least the basic group when the dispersant is an acidic dispersant, and
the thermoplastic solid resin has a polar parameter δp and a hydrogen bonding parameter δh from the Hansen solubility parameters that satisfy δp=2.5 to 11.0 and δh=5.0 to 12.0 respectively.
2. The colored resin particle dispersion according to claim 1 , wherein the liquid organic compound has at least the acidic group, and the acidic group of the liquid organic compound comprises a phosphoric acid group.
3. The colored resin particle dispersion according to claim 1 , wherein the non-aqueous solvent has a Hansen solubility parameter of 14 to 18 MPa 1/2 , a dispersion parameter δd of 12 to 20, a polar parameter δp of 0 to 4, and a hydrogen bonding parameter δh of 0 to 4.
4. The colored resin particle dispersion according to claim 1 , wherein the colored resin particles further comprise a plasticizer.
5. The colored resin particle dispersion according to claim 1 , wherein an average particle size of the colored resin particles is not more than 1 μm.
6. The colored resin particle dispersion according to claim 1 , wherein the liquid organic compound has at least the acidic group, and the acidic group of the liquid organic compound comprises at least one of a phosphoric acid group, a carboxyl group, a sulfonic acid group, a phosphate ester group, a sulfate ester group, a nitrate ester group, a phosphorous acid group, a phosphonic acid group and a sulfinic acid group.
7. The colored resin particle dispersion according to claim 1 , when the liquid organic compound has at least the basic group, and the basic group of the liquid organic compound comprises at least one of an aminogroup, a pyridyl group, a nitrogen-containing functional group having a urethane linkage and a nitrogen-containing functional group having an amide linkage.
8. The colored resin particle dispersion according to claim 1 , wherein the thermoplastic solid resin comprises at least one of styrene-(meth)acrylic-based resins, (meth)acrylic-based resins, polyester resins, epoxy resins, styrene resins, thermoplastic polyurethane-based resins, polyvinyl alcohols, styrene-maleic acid resins, alkylphenol resins, cellulose-based resins, polyamide resins, ketone resins, rosin resins, vinyl acetate resins, phosphorylated resins, nitrated resins, alkoxy group-containing resins, and derivatives of these resins.
9. The colored resin particle dispersion according to claim 4 , wherein the melting point of the plasticizer is 23 degrees C. or lower, and the plasticizer comprises at least one of alcohols, esters, ethers, polyesters, polyethers, epoxy resins and (meth)acrylic polymers.
10. A method for producing a colored resin particle dispersion,
the method comprising preparing a resin emulsion by dispersing a dispersion phase containing a colorant, a thermoplastic solid resin and a liquid organic compound having an acidic group, a basic group, or a combination thereof with the thermoplastic solid resin in a melted state in a continuous phase containing a dispersant and a non-aqueous solvent, and
then cooling the resin emulsion,
wherein the thermoplastic solid resin has a solubility in the non-aqueous solvent of 3 g/100 g or less, and
the liquid organic compound has at least the acidic group when the dispersant is a basic dispersant, and the liquid organic compound has at least the basic group when the dispersant is an acidic dispersant.
11. The method for producing a colored resin particle dispersion according to claim 10 , wherein the thermoplastic solid resin has a polar parameter δp and a hydrogen bonding parameter δh from the Hansen solubility parameters that satisfy δp=2.5 to 11.0 and δh=5.0 to 12.0 respectively.
12. The method for producing a colored resin particle dispersion according to claim 10 , wherein an average particle size of the colored resin particles is not more than 1 μm.
13. The method for producing a colored resin particle dispersion according to claim 10 , wherein the liquid organic compound has at least the acidic group, and the acidic group of the liquid organic compound comprises at least one of a phosphoric acid group, a carboxyl group, a sulfonic acid group, a phosphate ester group, a sulfate ester group, a nitrate ester group, a phosphorous acid group, a phosphonic acid group and a sulfinic acid group.
14. The method for producing a colored resin particle dispersion according to claim 10 , wherein the liquid organic compound has at least the basic group, an the basic group of the liquid organic compound comprises at least one of an amino group, a pyridyl group, a nitrogen-containing functional group having a urethane linkage and a nitrogen-containing functional group having an amide linkage.
15. The method for producing a colored resin particle dispersion according to claim 10 , wherein the thermoplastic solid resin comprises at least one of styrene-(meth)acrylic-based resins, (meth)acrylic-based resins, polyester resins, epoxy resins, styrene resins, thermoplastic polyurethane-based resins, polyvinyl alcohols, styrene-maleic acid resins, alkylphenol resins, cellulose-based resins, polyamide resins, ketone resins, rosin resins, vinyl acetate resins, phosphorylated resins, nitrated resins, alkoxy group-containing resins, and derivatives of these resins.
16. The method for producing a colored resin particle dispersion according to claim 10 , wherein the dispersion phase further contains a plasticizer which melting point is 23 degrees C. or lower, and the plasticizer comprises at least one of alcohols, esters, ethers, polyesters, polyethers, epoxy resins and (meth)acrylic polymers.
17. An inkjet ink comprising the colored resin particle dispersion according to claim 1 .