Method for preparing carbon nanotube fiber reinforced with carbon precursor
The present invention relates to carbon nanotube fibers reinforced with a carbon precursor and a method for manufacturing the same. The carbon nanotube fibers reinforced with a carbon precursor according to the present invention are carbonized by the empty space inside the carbon nanotube fibers being filled with a carbon precursor, and therefore, are highly effective in that the mechanical and thermal properties are improved due to effective stress transfer and contact resistance decrease, and these properties are maintained intact even at high temperatures.
1. A method for manufacturing carbon nanotube yarn reinforced with carbon, the method comprising:
(a) pretreating carbon nanotube yarn using any one step selected from: acid treatment; ultraviolet irradiation; plasma treatment; electron beam treatment; and immersion in a solvent or a surfactant;
(b) immersing the carbon nanotube yarn pretreated in step (a) in a carbon precursor in a solvent, thereby obtaining carbon nanotube yarn coated with a carbon precursor;
(c) drying the carbon nanotube yarn coated with the carbon precursor in step (b);
(d) stabilizing the carbon nanotube yarn dried in step (c) through heat treatment at 100 to 400° C. under air atmosphere; and
(e) carbonizing the carbon nanotube yarn stabilized in step (d) through heat treatment at 500 to 1600° C. for 30 minutes to 1 hour under inert gas atmosphere.
2. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , further comprising:
(f) graphitizing the carbon nanotube yarn carbonized in step (e) through heat treatment at 1700 to 3000° C. for 30 minutes to 1 hour under inert gas atmosphere after the step (e).
3. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the acid treatment is carried out by immersing the carbon nanotube fibers in an acidic solution of 4 to 15 moles at 30 to 100° C.
4. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the ultraviolet irradiation is carried out by irradiating ultraviolet light in a wavelength of 100 to 400 nm for 10 to 120 minutes.
5. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the electron beam treatment is carried out with electron beam absorbed dose of 10 kGy to 500 kGy.
6. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the solvent is 5 to 15% by weight of an aqueous NH 2 OH.HCl solution.
7. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the surfactant is one or more surfactants selected from the group consisting of sodium dodecyl sulfate, t-Oct-C 6 H 4 —(OCH 2 CH 2 ) x OH wherein x=9-10, lithium dodecyl sulfate, gum arabic, sodium lignosulfonate and polystyrene sulfonate.
8. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein, in step (b), the carbon precursor is one or more carbon precursor selected from the group consisting of polyacrylonitrile, polyvinyl alcohol, cellulose and pitch.
9. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the solvent in step (b) is one or more solvents selected from the group consisting of dimethylsulfoxide, dimethylformamide, dimethylamylamine, water, a mixture of N-methylmorpholine N-oxide and water, a mixture of lithium chloride and dimethylacetamide, a mixture of sodium hydroxide (NaOH) and urea, quinoline and toluene.
10. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the drying in step (c) is carried out at 50 to 70° C. for 20 to 30 hours.
11. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the heat treatment in step (d) is carried out for 20 minutes to 24 hours with the temperature being elevated for 0.5 to 1.5° C. per minute.
12. The method for manufacturing carbon nanotube yarn reinforced with carbon of claim 1 , wherein the inert gas is nitrogen, argon or helium.