IP Library Granted Patent US 10,066,080
Granted Patent B2
US 10,066,080 · App. 15/312,801 · Granted Sep 4, 2018

Rubber composition, tire, bisanilino compound, and anti-aging agent

Inventors: Aya Saiki (Kunitachi, JP); Hidehiro Minashima (Kodaira, JP); Yuzaburo Yano (Kodaira, JP); Noriaki Shiina (Osaka, JP); Kazuhiro Kodama (Osaka, JP); Mifuyu Ueno (Osaka, JP); Takashi Sato (Osaka, JP); Shinya Nakashima (Osaka, JP); Masaki Abe (Osaka, JP)
Assignee: OTSUKA CHEMICAL CO., LTD.
C08K5/20B60C1/0016B60C1/0025C07C211/55C07C217/08C07C235/16C07C237/04C07C321/14C07D295/13C08K5/3462C08K5/375
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Quick Facts
Patent No.
US 10,066,080
App. No.
15/312,801
Granted
Sep 4, 2018
Kind
B2
Abstract

Provided is a rubber composition that contains at least one rubber component selected from natural rubber and diene-based synthetic rubbers and, blended therewith, at least one bisanilino compound represented by formula (I). In formula (I), R 1 and R 2 each represent, independently of one another, a hydrogen atom or an alkyl group having a carbon number of 1-6, m and n each represent an integer of 0 or 1, A 1 represents an alkylene group having a carbon number of 1-7, A 2 represents an alkylene group having a carbon number of 1-8, X 1 represents an oxygen atom, a sulfur atom, or an —NR 3 — group, and X 2 represents an oxygen atom, a sulfur atom, or an —NR 4 — group, where R 3 and R 4 each represent a hydrogen atom or an alkyl group having a carbon number of 1-4, or collectively form an alkylene group having a carbon number of 1-4.

Claims (13)

1. A rubber composition comprising

at least one rubber component selected from natural rubber and diene-based synthetic rubbers and, blended therewith, at least one bisanilino compound represented by formula (I) shown below

where, in formula (I), R 1 and R 2 each represent, independently of one another, a hydrogen atom or an alkyl group having a carbon number of 1-6, m and n each represent an integer of 0 or 1, A 1 represents an alkylene group having a carbon number of 1-7, A 2 represents an alkylene group having a carbon number of 1-8, X 1 represents an oxygen atom or an —NR 3 — group, and X 2 represents an oxygen atom or an —NR 4 — group, where R 3 and R 4 each represent a hydrogen atom or an alkyl group having a carbon number of 1-4, or collectively form an alkylene group having a carbon number of 1-4.

2. The rubber composition of claim 1 , wherein

in the at least one bisanilino compound represented by formula (I), R 1 and R 2 are each, independently of one another, an alkyl group having a carbon number of 3-6, m and n are each 0, A 1 is an alkylene group having a carbon number of 1-4, A 2 is an alkylene group having a carbon number of 5-8, and X 1 and X 2 are each an oxygen atom.

3. The rubber composition of claim 1 , wherein

a blending amount of the at least one bisanilino compound represented by formula (I) is in a range of from 0.2 parts by mass to 10 parts by mass relative to 100 parts by mass of the at least one rubber component.

4. A tire comprising a tire member comprising the rubber composition of claim 1 .

5. The tire of claim 4 , wherein

the tire member is either or both of a tread and a sidewall.

6. A bisanilino compound represented by formula (I) shown below

where, in formula (I), R 1 and R 2 each represent, independently of one another, a hydrogen atom or an alkyl group having a carbon number of 1-6, m and n each represent an integer of 0 or 1, A 1 represents an alkylene group having a carbon number of 1-7, A 2 represents an alkylene group having a carbon number of 1-8, X 1 represents an oxygen atom or an —NR 3 — group, and X 2 represents an oxygen atom or an —NR 4 — group, where R 3 and R 4 each represent a hydrogen atom or an alkyl group having a carbon number of 1-4, or collectively form an alkylene group having a carbon number of 1-4.

7. An anti-aging agent for natural rubber and diene-based synthetic rubber-use comprising the bisanilino compound of claim 6 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 7, 2017
From: BRIDGESTONE CORPORATION; OTSUKA CHEMICAL CO., LTD.
To: OTSUKA CHEMICAL CO., LTD.
Reel/Frame 041649/0817 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2017
From: SAIKI, AYA; MINASHIMA, HIDEHIRO; YANO, YUZABURO; SHIINA, NORIAKI; KODAMA, KAZUHIRO; UENO, MIFUYU; SATO, TAKASHI; NAKASHIMA, SHINYA; ABE, MASAKI
To: BRIDGESTONE CORPORATION; OTSUKA CHEMICAL CO., LTD.
Reel/Frame 041166/0864 →
Priority Claims (1)
JP 2014-106398 · May 22, 2014 · national
Continuity (1)
Related Publication 20170166728A1 · Jun 15, 2017