Plastic organic electroluminescent display device and method of fabricating the same
Disclosed are a plastic organic electroluminescent display device to realize flexibility and prevent visualization of exterior light and a method for fabricating the same. The plastic organic electroluminescent display device includes a light emitting cell including a first electrode, a light emitting organic layer and a second electrode arranged on a substrate in this order, a barrier film adhered to the substrate provided with the light emitting cell, to seal the light emitting cell, the barrier film including an optically isotropic support film, and a circular polarizer adhered onto the optically isotropic barrier film.
1. A plastic organic electroluminescent display device comprising:
a light emitting cell including a first electrode, a light emitting organic layer and a second electrode formed on a substrate in this order;
a barrier film adhered to the substrate provided with the light emitting cell, to seal the light emitting cell;
a barrier protective film located between the barrier film and the second electrode; and
a circular polarizer adhered onto the barrier film,
wherein the barrier film includes:
an optically isotropic support film having a mixture of glass fiber and a cyclic olefin copolymer (COC);
a barrier layer having a multilayer structure, formed at at least one of a front surface and a rear surface of the optically isotropic support film;
a lower adhesive adhered to the substrate provided with the light emitting cell; and
an upper adhesive adhered to the circular polarizer;
wherein the multilayer structure of the barrier layer includes an organic barrier layer composed entirely of organic materials, and an inorganic barrier layer,
wherein the barrier protective film has a multilayer structure in which an organic barrier protective film and an inorganic barrier protective film are alternately laminated at least once,
wherein the organic barrier protective film shields pores formed in the inorganic barrier protective film, and
wherein the lower adhesive is a thermosetting or natural-setting type adhesive.
2. The device according to claim 1 , wherein the optically isotropic support film has a retardation of 0 to 5 nm.
3. The device according to claim 1 , wherein the organic barrier protective film is formed of a polymer material such as an acrylic resin, an epoxy resin, polyimide or polyethylene, and the inorganic barrier protective film is formed of aluminum oxide (Al x O y ), silicon oxynitride (SiON x ), silicon oxide (SiO x ) or silicon nitride (SiN x ).
4. A method for manufacturing a plastic organic electroluminescent display panel comprising:
sequentially forming a first electrode, a light emitting organic layer, and a second electrode on a substrate to form a light emitting cell;
forming a barrier protective film on the second electrode,
adhering a barrier film to the substrate provided with the light emitting cell and the barrier protective film to seal the light emitting cell through a thermal lamination process;
adhering a circular polarizer to the barrier film; and
wherein the barrier film includes an optically isotropic support film having a mixture of a glass fiber and a cyclic olefin copolymer (COC), a barrier layer having a multilayer structure, formed at at least one of a front surface and a rear surface of the optically isotropic support film, a lower adhesive adhered to the substrate provided with the light emitting cell and the barrier protective film, and an upper adhesive adhered to the circular polarizer,
wherein the multilayer structure of the barrier layer includes an organic barrier layer composed of entirely of organic materials, and an inorganic barrier layer,
wherein the barrier protective film has a multilayer structure in which an organic barrier protective film and an inorganic barrier protective film are alternately laminated at least once,
wherein the organic barrier protective film shields pores formed in the inorganic barrier protective film, and
wherein the lower adhesive is a thermosetting or natural-setting type adhesive.
5. The method according to claim 4 , wherein the optically isotropic support film has a retardation of 0 to 5 nm.
6. The method according to claim 4 , wherein the organic barrier protective film is formed of a polymer material such as an acrylic resin, an epoxy resin, polyimide or polyethylene, and the inorganic barrier protective film is formed of aluminum oxide (Al x O y ), silicon oxynitride (SiON x ), silicon oxide (SiO x ) or silicon nitride (SiN x ).
7. The device according to claim 1 , wherein the organic barrier protective film is sandwiched between the inorganic barrier protective film and another inorganic barrier protective film.
8. The method according to claim 4 , wherein the organic barrier protective film is sandwiched between the inorganic barrier protective film and another inorganic barrier protective film.
9. The device according to claim 1 , wherein the barrier protective film is adhered to the barrier layer by the lower adhesive.
10. The method according to claim 4 , wherein the barrier protective film is adhered to the barrier layer by the lower adhesive.
11. The device according to claim 1 , wherein the optically isotropic support film has a substantially same coefficient of thermal expansion as the substrate.
12. The device according to claim 1 , wherein the barrier film has a moisture permeability of 10 −3 g/m 2 /day or less.
13. The device according to claim 1 , wherein the inorganic barrier protective film has a thickness of 1 to 2 μm.
14. The device according to claim 13 , wherein the organic barrier protective film has a thickness of 8 to 10 μm.
15. The method according to claim 4 , wherein the optically isotropic support film has a substantially same coefficient of thermal expansion as the substrate.
16. The method according to claim 7 , wherein the barrier film has a moisture permeability of 10 −3 g/m 2 /day or less.
17. The method according to claim 4 , wherein the inorganic barrier protective film has a thickness of 1 to 2 μm.
18. The method according to claim 17 , wherein the organic barrier protective film has a thickness of 8 to 10 μm.
19. The device according to claim 1 , further comprising a bank insulating film between the first electrode and the second electrode, and exposing the first electrode,
wherein the barrier layer is formed on an entire surface of the at least one of a front surface and a rear surface of the optically isotropic support film to overlap an upper surface of the bank insulating film.
20. The method according to claim 4 , wherein the sequentially forming includes forming a bank insulating film between the first electrode and the second electrode, and exposing the first electrode, and
wherein the barrier layer is formed on an entire surface of the at least one of a front surface and a rear surface of the optically isotropic support film to overlap an upper surface of the bank insulating film.