Use of strobilurin type compounds for combating phytopathogenic fungi resistant to Qo inhibitors
The present invention relates to the use of strobilurine type compounds of formula I and the N-oxides and the salts thereof for combating phytopathogenic fungi containing a mutation in the mitochondrial cytochrome b gene conferring resistance to Qo inhibitors, and to methods for combating such fungi. The invention also relates to novel compounds, processes for preparing these compounds, to compositions comprising at least one such compound, to plant health applications, and to seeds coated with at least one such compound.
1. A method for combating phytopathogenic fungi containing a mutation in the mitochondrial cytochrome b gene conferring resistance to Qo inhibitors, wherein the mutations is G143A, comprising applying agrochemical composition wherein said composition comprises an auxiliary and a pesticidally effective amount of at least one compound of formula (I)
wherein:
R 1 and R 2 together with the two carbon atoms linking them form a phenyl ring and
R 4 is 4-methyl-1,4-dihydro-tetrazol-5-one-1-yl, and
wherein the abovementioned phenyl ring may carry 1, 2, 3 or up to the maximum number of identical or different groups R a which independently of one another are selected from:
R a halogen, CN, nitro, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkyl and C 1 -C 4 -haloalkoxy;
Y is a direct bond or a divalent group selected from —OCH 2 —, —CH 2 —, —CH 2 CH 2 —, —C(Z)═N—O—CH 2 —, —CHZ—C(Z)═N—O—CH 2 —, —O—N═C(Z)—C(Z)═N—O—CH 2 —, —C(═O)—C(Z)═N—O—CH 2 — and —C(═N—O—Z)—C(Z)═N—O—CH 2 —,
where the bond depicted on the left side of the divalent group Y is attached to R 3 , and the bond depicted on the right side is attached to the carbon atom being substituted by R 2 , and
Z, which may be the same or different to any other Z, is hydrogen, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl;
R 3 is
wherein # indicates the point of attachment to the linker moiety Y;
wherein the phenyl may carry 1, 2, 3 or up to the maximum possible number of identical or different groups R c , which may be the same or different to any other R c , is halogen;
or an N-oxide or an agriculturally acceptable salt thereof.
2. The method of claim 1 , wherein in formula (I) Y is —OCH 2 , —CH 2 CH 2 —, —C(CH 3 )═N—O—CH 2 —, —O—N═C(CH 3 )—C(CH 3 )═N—O—CH 2 — or —C(═N—O—CH 3 )—C(CH 3 )═N—O—CH 2 —.
3. The method of claim 1 , wherein the phytopathogenic fungi are selected from the group consisting of Alternaria alternata, Blumeria graminis, Pyricularia oryzae, Septoria tritici, Mycosphaerella fijiensis, Venturia inaequalis, Pyrenophora teres, Pyrenophora tritici - repentis and Plasmopara viticola.
4. The method of claim 3 , wherein the phytopathogenic fungus is Septoria tritici.
5. The method of claim 1 , comprising:
treating the phytopathogenic fungi or the materials, plants, the soil or seeds that are at risk of being diseased from phytopathogenic fungi with an effective amount of a composition comprising at least one compound of formula I.
6. The method of claim 5 , comprising:
a) identifying the phytopathogenic fungi, or the materials, plants, the soil or seeds that are at risk of being diseased from phytopathogenic fungi,
and
b) treating said fungi or the materials, plants, the soil or seeds with an effective amount of a composition comprising at least one compound of formula I.