Polydiphenylsiloxane coating formulation and method for forming a coating
Provided is composition for a liquid coating. The composition may include a silanol terminated copolymer, at least one cross-linker, and a catalyst. The silanol terminated copolymer may include from about 10 to about 25 mol % of a diphenylsiloxane repeat unit and greater than about 50 mol % of a dialkylsiloxane repeat unit. The at least one cross-linker may be one or more selected from: tetraethoxysilane (TEOS), a trialkoxysilane terminated polydialkylsiloxane and/or one or more of a trialkoxysilyl terminated polymer.
1. A composition for a liquid coating, comprising:
a silanol terminated siloxane copolymer comprising from about 10 to about 25 mol % of a diphenylsiloxane repeat unit and greater than about 50 mol % of a dialkylsiloxane repeat unit;
at least one cross-linker comprising tetraethoxysilane (TEOS) and one or more trialkoxysilyl terminated polymer; and
a catalyst.
2. The composition of claim 1 , further comprising at least one solvent.
3. The composition of claim 1 , wherein the silanol terminated siloxane copolymer is represented by:
where R is a linear, branched, or cyclic saturated or unsaturated alkyl group containing from about 1 to 30 carbon atoms and s is from about 1 to about 500 and t is from about 1 to about 300.
4. The composition of claim 1 , wherein the silanol terminated siloxane copolymer comprises a molecular weight of from about 500 g/mol to about 50,000 g/mol.
5. The composition of claim 1 , wherein the at least one crosslinker further comprises a trialkoxysilane terminated polydialkylsiloxane, wherein the trialkoxysilane terminated polydialkylsiloxane is represented by
wherein R is a linear, branched, or cyclic saturated or unsaturated alkyl group containing from about 1 to 30 carbon atoms, R′ is a hydrogen atom or a linear, branched, or cyclic saturated or unsaturated alkyl group containing from about 1 to 30 carbon atoms, n is from about 0 to about 50 and q is from about 1 to about 500.
6. The composition of claim 1 , wherein the one or more trialkoxysilyl terminated polymer is represented by formulae I or II:
where,
L 1 , L 2 and L 3 are linker groups comprising C 1 to C 6 alkyl bridge groups; X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are independently selected from the group consisting of a hydroxyl, a reactive alkoxide functionality and an unreactive aliphatic functionality; and
R 1 and R 2 are independently selected from the group consisting of: a) a linear, branched or cyclic, saturated or unsaturated alkyl group, b) a perfluorinated linear, branched or cyclic carbon chain, c) a group having one or more dialkylsiloxane units,d) a substituted or unsubstituted polyether group optionally comprising one or more amide moieties, carbonyl moieties, carboxylic acid ester moieties or amine moieties, and e)a polyamine group optionally comprising a saturated hydrocarbon chain moiety.
7. The composition of claim 6 , wherein the one or more trialkoxysilyl terminated polymer comprises at least one of a first trialkoxysilyl terminated polymer, a second trialkoxysilyl terminated polymer and a third trialkoxysilyl terminated polymer, wherein the first second and third trialkoxysilyl terminated polymers have different structures.
8. The composition of claim 7 , wherein the one or more trialkoxysilyl terminated polymer further comprises at least one of a fourth trialkoxysilyl terminated polymer, a fifth trialkoxysilyl terminated polymer and a sixth trialkoxysilyl terminated polymer, wherein the first, second, third, fourth, fifth and sixth trialkoxysilyl terminated polymers have different structures.
9. A composition for a liquid coating, comprising:
a silanol terminated copolymer comprising from about 10 to about 25 mol % of a diphenylsiloxane repeat unit and greater than about 50 mol % of a dialkylsiloxane repeat unit;
at least one cross-linker; and
a catalyst,
wherein the one or more trialkoxysilyl terminated polymer is represented by formulae I or II:
where,
L 1 , L 2 and L 3 are linker groups comprising C 1 to C 6 alkyl bridge groups; X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are independently selected from the group consisting of a hydroxyl, a reactive alkoxide functionality and an unreactive aliphatic functionality; and
R 1 and R 2 are independently selected from the group consisting of: a) a linear, branched or cyclic, saturated or unsaturated alkyl group, b) a perfluorinated linear, branched or cyclic carbon chain, c) a group having one or more dialkylsiloxane units,d) a substituted or unsubstituted polyether group optionally comprising one or more amide moieties, carbonyl moieties, carboxylic acid ester moieties or amine moieties, and e)a polyamine group optionally comprising a saturated hydrocarbon chain moiety,
wherein the at least one crosslinker comprises tetraethoxysilane (TEOS) and at least one of a first trialkoxysilyl terminated polymer, a second trialkoxysilyl terminated polymer, a third trialkoxysilyl terminated polymer, a fourth trialkoxysilyl terminated polymer, a fifth trialkoxysilyl terminated polymer, and a sixth trialkoxysilyl terminated polymer, wherein each of the first, second, third, fourth, fifth and sixth trialkoxysilyl terminated polymers have different structures.
10. The composition of claim 1 , wherein the catalyst comprises about 0.1 wt % to about 5 wt % of the composition and selected from at least one in the group consisting of titanate, zirconate and tin.
11. A transfix blanket for a printer, comprising:
a substrate layer; and
a topcoat layer disposed on the substrate layer, wherein the topcoat layer comprises a silanol terminated copolymer crosslinked with at least one cross-linker,
wherein the silanol terminated copolymer comprises from about 10 to about 25 mol % of a diphenylsiloxane repeat unit and greater than about 50 mol % of a dialkylsiloxane repeat unit,
wherein the silanol terminated siloxane copolymer is represented by:
where R is a linear, branched, or cyclic saturated or unsaturated alkyl group containing from about 1 to 30 carbon atoms and s is from about 1 to about 500 and t is from about 1 to about 300, and
wherein the at least one crosslinker comprises tetraethoxysilane (TEOS) and one or more trialkoxysilyl terminated polymer.
12. The transfix blanket of claim 11 , wherein the at least one crosslinker further comprises a trialkoxysilane terminated polydialkylsiloxane, wherein the trialkoxysilane terminated polydialkylsiloxane is represented by
wherein R is a linear, branched, or cyclic saturated or unsaturated alkyl group containing from about 1 to 30 carbon atoms, R′ is a hydrogen atom or a linear, branched, or cyclic saturated or unsaturated alkyl group containing from about 1 to 30 carbon atoms, n is from about 0 to about 50 and q is from about 1 to about 500, and
the one or more trialkoxysilyl terminated polymer is represented by formulae I or II:
where,
L 1 , L 2 and L 3 are linker groups comprising C 1 to C 6 alkyl bridge groups; X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are independently selected from the group consisting of a hydroxyl, a reactive alkoxide functionality and an unreactive aliphatic functionality; and
R 1 and R 2 are independently selected from the group consisting of: a) a linear, branched or cyclic, saturated or unsaturated alkyl group, b) a perfluorinated linear, branched or cyclic carbon chain, c) a group having one or more dialkylsiloxane units, d) a substituted or unsubstituted polyether group optionally comprising one or more amide moieties, carbonyl moieties, carboxylic acid ester moieties or amine moieties, and e) a polyamine group optionally comprising a saturated hydrocarbon chain moiety.
13. The transfix blanket of claim 11 , wherein s and t are integers and are selected such that the silanol terminated copolymer comprises from about 10 to about 25 mol % of the diphenylsiloxane repeat unit and greater than about 50 mol % of the dialkylsiloxane repeat unit.
14. The composition of claim 5 , wherein s and t are integers and are selected such that the silanol terminated copolymer comprises from about 10 to about 25 mol % of the diphenylsiloxane repeat unit and greater than about 50 mol % of the dialkylsiloxane repeat unit.