IP Library Granted Patent US 10,106,745
Granted Patent B2
US 10,106,745 · App. 15/334,134 · Granted Oct 23, 2018

Bitumen solidification and prilling

Inventors: Subodh Gupta (Calgary, CA); Michael N. Holmes (Calgary, CA); Eric A. MacDonald (Calgary, CA); Jennifer D. Wood (Calgary, CA)
Assignee: Cenovus Energy Inc.
C10C3/14B01J2/30C08L91/00C08L95/00
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Quick Facts
Patent No.
US 10,106,745
App. No.
15/334,134
Granted
Oct 23, 2018
Kind
B2
Abstract

Methods, processes, and apparatuses for preparing and transporting bitumen. Bitumen may be prilled such that a bitumen product comprising a prill core and a non-stick coating is produced. The non-stick coating may comprise asphaltenes and the prill core may comprise bitumen, deasphalted oil, or both bitumen and deasphalted oil. The resultant non-stick coated prills have reduced adhesion to transportation vessels and other non-stick coated prills at a temperature below an adhesion temperature, facilitating transport.

Claims (34)

1. A method for transporting bitumen, the method comprising:

generating a first non-stick coated prill comprising a prill core and a non-stick coating, the prill core comprising bitumen, deasphalted oil, or a combination thereof, and the non-stick coating comprising asphaltenes; and

transporting the non-stick coated prill in a transportation vessel;

the non-stick coated prill having reduced adhesion to the transportation vessel or a second non-stick coated prill having the non-stick coating at a temperature below an adhesion temperature, wherein the adhesion temperature is a temperature below which the first non-stick coated prill tends not to adhere a surface or to the second non-stick coated prill.

2. The method according to claim 1 , wherein at least some of the asphaltenes of the non-stick coating are asphaltenes separated from a bitumen or deasphalted oil prior to using the bitumen or deasphalted oil for generating the prill core.

3. The method according to claim 1 , wherein the adhesion temperature is above an ambient transportation temperature.

4. The method according to claim 1 , wherein the non-stick coating comprises asphaltenes applied to the prill core as a powder, as a liquid which subsequently solidifies, as a solvent-diluted asphaltenes solution which subsequently solidifies, or a combination thereof.

5. The method according to claim 4 , wherein the non-stick coating comprises asphaltenes applied as toluene-diluted asphaltenes.

6. A non-stick coated prill comprising:

a prill core comprising bitumen, deasphalted oil, or a combination thereof; and

a non-stick coating comprising asphaltenes, the non-stick coating having reduced adhesion to another non-stick coated prill having the non-stick coating at a temperature below an adhesion temperature, wherein the adhesion temperature is a temperature below which the non-stick coated prill tends not to adhere a surface or to the another non-stick coated prill.

7. The non-stick coated prill according to claim 6 , wherein the non-stick coated prill is prepared by:

generating the prill core comprising bitumen, deasphalted oil, or a combination thereof; and

coating the prill core with the non-stick coating.

8. The non-stick coated prill according to claim 7 , wherein at least some of the asphaltenes of the non-stick coating are asphaltenes separated from a bitumen or deasphalted oil prior to using the bitumen or deasphalted oil for generating the prill core.

9. The non-stick coated prill according to claim 6 , wherein the non-stick coated prill is prepared by:

introducing bitumen, deasphalted oil, or a combination thereof, into a prilling vessel and forming the prill core comprising bitumen, deasphalted oil, or a combination thereof;

cooling the prill core; and

coating the prill core with the non-stick coating.

10. The non-stick coated prill according to claim 9 , wherein at least some of the asphaltenes of the non-stick coating are asphaltenes separated from a bitumen or deasphalted oil prior to using the bitumen or deasphalted oil for generating the prill core.

11. The non-stick coated prill according to claim 10 , wherein the non-stick coating comprises asphaltenes applied to the prill core as a powder, as a liquid which subsequently solidifies, as a solvent-diluted asphaltenes solution which subsequently solidifies, or a combination thereof.

12. The non-stick coated prill according to claim 11 , wherein the non-stick coating comprises asphaltenes applied as toluene-diluted asphaltenes.

13. The non-stick coated prill according to claim 6 , wherein the prill core comprises up to 100% deasphalted oil.

14. The non-stick coated prill according to claim 6 , wherein the non-stick coating comprises asphaltenes applied to the prill core as a powder, as a liquid which subsequently solidifies, as a solvent-diluted asphaltenes solution which subsequently solidifies, or a combination thereof.

15. The non-stick coated prill according to claim 14 , wherein the non-stick coating comprises asphaltenes applied as toluene-diluted asphaltenes.

16. A method for generating a non-stick coated prill, the method comprising:

generating a prill core comprising bitumen, deasphalted oil (DAO), or a combination thereof; and

coating the prill core with a non-stick coating comprising asphaltenes, the non-stick coating having reduced adhesion to another non-stick coated prill having the non-stick coating at a temperature below an adhesion temperature of the non-stick coated prill.

17. The method according to claim 16 , wherein at least some of the asphaltenes of the non-stick coating are asphaltenes separated from a bitumen or DAO prior to using the bitumen or DAO for generating the prill core.

18. The method according to claim 16 , wherein the step of generating the prill core comprises:

introducing bitumen, deasphalted oil (DAO), or a combination thereof, into a prilling vessel and forming the prill core; and

cooling the prill core prior to the step of coating the prill core with the non-stick coating.

19. The method according to claim 16 , wherein the step of coating the prill core with the non-stick coating comprises applying the non-stick coating to the prill core as a powder, as a liquid which subsequently solidifies, as a solvent-diluted asphaltenes solution which subsequently solidifies, or a combination thereof.

20. The method according to claim 19 , wherein the non-stick coating comprises asphaltenes applied as toluene-diluted asphaltenes.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 1, 2016
From: GUPTA, SUBODH; HOLMES, MICHAEL N.; MACDONALD, ERIC A.; WOOD, JENNIFER D.
To: CENOVUS ENERGY INC.
Reel/Frame 040187/0613 →
Continuity (2)
Provisional Application 62246556 · Oct 26, 2015
Related Publication 20170114281A1 · Apr 27, 2017