IP Library Granted Patent US 10,122,012
Granted Patent B2
US 10,122,012 · App. 15/131,362 · Granted Nov 6, 2018

Positive electrode active material for lithium-ion battery, a positive electrode for lithium-ion battery, and lithium-ion battery

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Quick Facts
Patent No.
US 10,122,012
App. No.
15/131,362
Granted
Nov 6, 2018
Kind
B2
Abstract

The present invention provides a positive electrode active material for lithium ion batteries having excellent battery property. The positive electrode active material for lithium ion batteries is represented by composition formula: Li x Ni 1−y M y O 2+α , wherein M is Co as an essential component and at least one species selected from a group consisting of Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr, 0.9≤x≤1.2, 0<y≤0.7, α>0.05, and an average particle size (D50) is 5 μm to 15 μm.

Claims (14)

1. A manufacturing method for a positive electrode active material for lithium ion batteries, represented by composition formula: Li x Ni 1−y M y O 2+α , wherein

M is Co as an essential component and at least one species selected from a group consisting of Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr, 0.9≤x≤1.2, 0<y≤0.7, α>0.05, and

an average particle size (D50) is 5 μm to 15 μm,

comprising the steps of (1) to (5):

(1) producing metal salt solution of Ni and at least one species selected from a group consisting of Sc, Ti, V, Cr, Mn, Fe, Co, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr,

(2) suspending lithium carbonate in pure water, and then pouring the metal salt solution in the water to produce metal carbonate solution slurry,

(3) filtering the metal carbonate solution slurry to produce a filtered lithium-containing carbonate, and then drying the lithium-containing carbonate to produce powders of a precursor for positive electrode active material for lithium ion batteries,

(4) classifying the powders of a precursor for positive electrode active material for lithium ion batteries to produce powders having a particle size of 1 μm to 30 μm, and

(5) conducting a calcination of the powders of a precursor for positive electrode active material for lithium ion batteries having a particle size of 1 μm to 30 μm to produce a positive electrode active material for lithium ion batteries.

2. The manufacturing method of claim 1 , wherein the average particle size (D50) is 7 μm to 13 μm.

3. The manufacturing method of claim 1 , wherein M is Co and Mn.

4. The manufacturing method of claim 1 , wherein α>0.15.

5. The manufacturing method of claim 4 , wherein α>0.20.

6. The manufacturing method of claim 1 , wherein D90 is 20 μm or less in particle size distribution.

Assignments (1)
CHANGE OF ADDRESS Recorded Aug 11, 2021
From: JX NIPPON MINING & METALS CORPORATION
To: JX NIPPON MINING & METALS CORPORATION
Reel/Frame 057160/0114 →