Methods and systems for treating vinasse
Systems and methods for treating vinasse are disclosed. The methods treat vinasse to generate useable water. The methods include providing vinasse, reacting the vinasse with persulfate to generate an oxidized mixture, reacting the oxidized mixture with peroxide to generate a peroxide-treated mixture, adjusting the pH of the peroxide-treated mixture to above about pH 6 to generate a pH-adjusted mixture, reacting the pH-adjusted mixture with an inorganic coagulant and a low molecular weight cationic polymer to generate solid particles, and removing the solid particles to generate a liquid fraction.
1. A method for treating vinasse, the method comprising:
obtaining a quantity of vinasse;
reacting the vinasse with persulfate to form an oxidized mixture;
reacting the oxidized mixture with peroxide to form a peroxide-treated mixture;
adjusting the pH of the peroxide-treated mixture to a pH value in the range from pH 6 to pH 7, to form a pH-adjusted mixture;
reacting the pH-adjusted mixture with an inorganic coagulant and a low molecular weight cationic polymer to form solid particles; and
removing the solid particles to yield a liquid fraction.
2. The method of claim 1 , further comprising vacuum distilling the liquid fraction to yield a distilled fraction.
3. The method of claim 1 , further comprising evaporating the liquid fraction to yield an evaporative fraction.
4. The method of claim 1 , further comprising reacting the vinasse with ferrous iron ions before reacting with persulfate.
5. The method of claim 4 , wherein the ferrous iron ions are added to the vinasse to achieve a concentration of between 1 mg/L and 25 mg/L in the vinasse.
6. The method of claim 1 , wherein reacting the oxidized mixture with peroxide comprises reacting the oxidized mixture with the peroxide for 2 to 4 hours.
7. The method of claim 1 , wherein the vinasse is at a temperature above 65° C.
8. The method of claim 1 , wherein the vinasse is at an acidic pH below 5.
9. The method of claim 1 , wherein the inorganic coagulant comprises an aluminum-based inorganic coagulant.
10. The method of claim 9 , wherein the inorganic coagulant comprises aluminum chlorohydrate.
11. The method of claim 1 , wherein the polymer comprises epi-dma (poly(epichlorhydrin-dimethylamine).
12. A method for treating vinasse, the method comprising:
obtaining a quantity of vinasse at an acidic pH;
measuring the chemical oxygen demand (COD) of the vinasse;
reacting the vinasse with persulfate at a ratio of 1 gram of persulfate per 40,000 mg/L of COD to form an oxidized mixture;
reacting the oxidized mixture with peroxide to form a peroxide-treated mixture;
adjusting the pH of the peroxide-treated mixture to a pH value in the range from pH 6 to 7, to form a pH-adjusted mixture;
reacting the pH-adjusted mixture with an aluminum-based inorganic coagulant and a low molecular weight cationic polymer to form solid particles; and removing the solid particles to yield a liquid fraction.
13. The method of claim 12 , further comprising reacting the vinasse with ferrous iron ions after measuring the COD and before reacting with persulfate.
14. The method of claim 13 , wherein the ferrous iron ions are added to the vinasse to achieve a concentration of between 1 mg/L and 25 mg/L in the vinasse.
15. The method of claim 12 , wherein reacting the oxidized mixture with peroxide comprises reacting the oxidized mixture with a 3% hydrogen peroxide solution at a ratio of 1.2 hydrogen peroxide to 1.5 persulfate by weight.
16. The method of claim 12 , wherein removing the solid particles comprises one or more of lamella clarification, belt press, filter press, screw press, microfiltering, and centrifuging.
17. A method for generating distillation condensate water from vinasse, the method comprising:
obtaining a quantity of vinasse at a pH of below 5;
reacting the vinasse with ferrous iron ions to form a ferrous mixture, wherein the ferrous iron ions are added to the vinasse to achieve a concentration of between 1 mg/L and 25 mg/L in the vinasse;
reacting the ferrous mixture with persulfate to generate an oxidized mixture;
reacting the oxidized mixture with peroxide to generate a peroxide-treated mixture;
adjusting the pH of the peroxide-treated mixture to a pH value above pH 6 to form a pH-adjusted mixture;
reacting the pH-adjusted mixture with an aluminum-based inorganic coagulant and a low molecular weight cationic polymer to form solid particles;
removing the solid particles to yield a liquid fraction; and distilling the liquid fraction to yield distillation condensate water.
18. The method of claim 17 , wherein the vinasse comprises a chemical oxygen demand of above 50,000 mg/L.
19. The method of claim 17 , wherein adjusting the pH of the peroxide-treated mixture comprises adjusting the pH to a pH value between 6.0 and 6.9.
20. The method of claim 17 , wherein distilling comprises single pass vacuum distillation.