Personal care compositions containing complexing polyelectrolytes
Compositions of the invention contain, in a cosmetically acceptable aqueous medium, a) a cationic polyelectrolyte, b) at least one surfactant; and (c) from about 0.01 to about 1.2 weight percent of an anionic polyelectrolyte, where the weight ratio of the anionic polyelectrolyte to the cationic polyelectrolyte is from about 0.05 to about 1.2, and where the composition exhibits a viscosity change that is below a minimum significant-change-threshold (Δηmin) and exhibits no measurable yield stress or increase in yield stress value when compared to a substantially identical composition that does not contain from about 0.01 to about 1.2 weight percent of the anionic polyelectrolyte, at a weight ratio of anionic polyelectrolyte to cationic polyelectrolyte of from about 0.05 to about 1.2.
1. A composition, comprising, in a cosmetically acceptable aqueous medium,
a) about 0.6 weight percent of a cationic polyelectrolyte,
b) at least one surfactant; and
(c) from about 0.01 to about 1.2 weight percent of an anionic polyelectrolyte, wherein the weight ratio of said anionic polyelectrolyte to said cationic polyelectrolyte is from about 0.05 to about 1.2, wherein said composition exhibits a viscosity change that is below a minimum significant-change-threshold (Δη min ) and exhibits no measurable yield stress or increase in yield stress value when compared to a substantially identical composition that does not contain from about 0.01 to about 1.2 weight percent of said anionic polyelectrolyte, at a weight ratio of anionic polyelectrolyte to cationic polyelectrolyte of from about 0.05 to about 1.2.
2. The composition of claim 1 wherein the weight ratio of said anionic polyelectrolyte to said cationic polyelectrolyte is about 0.1 to about 1.
3. The composition of claim 1 comprising from about 0.1 weight percent to about 1 weight percent of said anionic polyelectrolyte.
4. The composition of claim 1 comprising from about 1 weight percent to about 25 weight percent of said surfactant.
5. The composition of claim 1 comprising from about 3 weight percent to about 15 weight percent of said surfactant.
6. The composition of claim 1 wherein a Dry Precipitate Mass Yield upon dilution of said composition is greater than of a Dry Precipitate Mass Yield upon dilution of a substantially identical composition that does not comprise from about 0.01 weight percent to about 1.2 weight percent of said anionic polyelectrolyte, at a weight ratio of said anionic polyelectrolyte to said cationic polyelectrolyte of from about 0.05 to about 1.
7. The composition of claim 1 wherein a Dry Precipitate Mass Yield upon dilution of said composition is increased by 10% or more compared to a substantially identical composition that does not contain from about 0.01 to about 1.2 weight percent of said anionic polyelectrolyte, at a weight ratio of anionic polyelectrolyte to cationic polyelectrolyte of from about 0.05 to about 1.2.
8. The composition of claim 1 wherein a Dry Precipitate Mass Yield upon dilution of said composition is increased by 20% or more compared to a substantially identical composition that does not comprise from about 0.01 weight percent to about 1.2 weight percent of said anionic polyelectrolyte.
9. The composition of claim 1 wherein a Dry Precipitate Mass Yield upon dilution of said composition is increased by 40% or more compared to a substantially identical composition that does not comprise from about 0.01 weight percent to about 1.2 weight percent of said anionic polyelectrolyte.
10. The composition of claim 1 wherein said anionic polyelectrolyte is selected from the group consisting of polyelectrolytes derived from ethylenically unsaturated monomers containing anionic and anionically-ionizable monomers, anionic and anionically ionizable polysaccharides and polysaccharide derivatives thereof and anionic or anionically ionizable polypeptides or proteins or hybrid (co)polymers.
11. The composition of claim 1 wherein said cationic polyelectrolyte is selected from the group consisting of polyelectrolytes derived from ethylenically unsaturated monomers containing cationic protonated amine or quaternary ammonium functionalities, cationic and cationically-ionizable polysaccharides and polysaccharide derivatives thereof, and cationic or cationically-ionizable polypeptides or proteins or hybrid (co)polymers.
12. The composition of claim 1 wherein said surfactant is selected from the group consisting of anionic, zwitterionic, nonionic and cationic surfactants.