Systems and methods for producing dimethyl ether from natural gas
Integrated methods and systems are disclosed for the production of dimethyl ether. The method may include reforming natural gas to syngas in a first reactor; contacting the syngas produced in the first reactor with a catalyst system in a second reactor to produce dimethyl ether and carbon dioxide; and supplying steam as a cofeed to at least one of the first reactor and the second reactor in an amount sufficient to achieve a M m value of 1.4 to 1.8 or to improve the hydrocarbon or oxygenate selectivity.
1. An integrated method for the production of dimethyl ether comprising:
reforming natural gas to syngas in a first reactor;
contacting the syngas produced in the first reactor with a catalyst system in a second reactor to produce dimethyl ether and carbon dioxide; and
supplying steam as a cofeed to at least one of the first reactor and the second reactor in an amount sufficient to achieve a M m value of 1.4 to 1.8 wherein M m =(H 2 −CO 2 +H 2 O)/(CO+CO 2 −H 2 O) and H 2 is moles of H 2 fed to the second reactor, CO 2 is moles of CO 2 fed to the second reactor, CO is moles of CO fed to the second reactor and H 2 O is moles of H 2 O fed to the second reactor,
wherein the first reactor is a reverse flow reactor.
2. The method of claim 1 , further comprising recycling carbon dioxide produced in the second reactor to the first reactor.
3. The method of claim 1 , wherein the method has a carbon efficiency is at least 85%.
4. The method of claim 3 , wherein the method has a carbon efficiency is at least 90%.
5. The method of claim 1 , wherein the steam is supplied in an amount sufficient to achieve a hydrocarbon selectivity of less than 3 mole % in the second reactor with the catalyst system.
6. The method of claim 1 , wherein the hydrocarbon selectivity is less than 2 mole % with the catalyst system.
7. The method of claim 1 , further comprising separating the carbon dioxide from dimethyl ether before recycling the carbon dioxide to the first reactor.
8. The method of claim 1 , wherein the syngas is converted to methanol and the methanol is dehydrated to dimethyl ether in the second reactor.
9. The method of claim 1 , wherein the steam is supplied in an amount sufficient to achieve a thermal efficiency of at least 70%.
10. The method of claim 1 , wherein the steam is supplied in an amount sufficient to achieve a oxygenate selectivity of less than 0.005 mole %.
11. The method of claim 10 , wherein the oxygenate selectivity of less than 0.001 mole %.
12. The method of claim 1 , wherein the syngas comprises CO and H 2 in a CO:H 2 mole ratio from about 0.8:1 to about 1.1:1.