Pneumatic tire
The present invention provides a pneumatic tire provided with a tread formed from a rubber composition that can achieve balanced improvements in fuel economy and wet-grip performance. The present invention relates to a pneumatic tire provided with a tread formed from a rubber composition, the rubber composition containing a rubber component, silica, and a specific silane coupling agent, the rubber component containing, based on 100% by mass of the rubber component, not less than 5% by mass of a conjugated diene polymer containing a constituent unit based on a conjugated diene and a specific constituent unit, at least one terminal of the polymer being modified with a specific compound, the rubber composition containing the silica in an amount of 5 to 150 parts by mass relative to 100 parts by mass of the rubber component.
1. A pneumatic tire, provided with a tread formed from a rubber composition, the rubber composition comprising:
a rubber component,
silica, and
a silane coupling agent represented by Formula (1) below,
the rubber component comprising, based on 100% by mass of the rubber component, 5% to 90% by mass of a conjugated diene polymer containing a constituent unit based on a conjugated diene and a constituent unit represented by Formula (I) below, wherein at least one terminal of the polymer is modified with at least one compound selected from the group consisting of a compound represented by Formula (II) below, a compound containing a group represented by Formula (III) below, a compound represented by Formula (IV) below, a silicon compound containing at least one of a group represented by Formula (V) below or a group represented by Formula (VI) below, and a compound containing a group represented by Formula (VII) below,
the rubber composition comprising the silica in an amount of 5 to 150 parts by mass relative to 100 parts by mass of the rubber component, and
the rubber composition comprising the silane coupling agent represented by Formula (1) in an amount of 2 to 20 parts by mass relative to 100 parts by mass of silica
(C p H 2p+1 O) 3 Si—C q H 2q —S—CO—C k H 2k+1 (1)
wherein p represents an integer of 1 to 3; q represents an integer of 1 to 5; and k represents an integer of 5 to 12, and
wherein Formulas (I) to (VII) are represented below:
wherein X 1 , X 2 , and X 3 each independently represent a group represented by Formula (Ia) below, a hydroxy group, a hydrocarbyl group, or a substituted hydrocarbyl group, and at least one of X 1 , X 2 , and X 3 is a hydroxy group or a group represented by the following Formula (Ia):
wherein R 1 and R 2 each independently represent a C 1-6 hydrocarbyl group, a C 1-6 substituted hydrocarbyl group, a silyl group, or a substituted silyl group, and R 1 and R 2 may be bonded to each other to form a cyclic structure together with the nitrogen atom,
wherein n represents an integer of 1 to 10; R 11 , R 12 , and R 13 each independently represent a C 1-4 hydrocarbyl group or a C 1-4 hydrocarbyloxy group, and at least one of R 11 , R 12 , and R 13 is a hydrocarbyloxy group; and A 1 represents a nitrogen atom-containing functional group,
wherein p represents an integer of 0 or 1; T represents a C 1-20 hydrocarbylene group or a C 1-20 substituted hydrocarbylene group; and A 2 represents a nitrogen atom-containing functional group,
wherein g represents an integer of 1 to 10; R 21 represents a hydrogen atom, a C 1-6 hydrocarbyl group, or a C 1-6 substituted hydrocarbyl group; A 3 represents an oxygen atom or the following group: —NR 22 — where R 22 represents a hydrogen atom or a C 1-10 hydrocarbyl group; and A 4 represents a functional group containing at least one of a nitrogen atom or an oxygen atom,
wherein w represents an integer of 1 to 11; and A 5 represents a nitrogen atom-containing functional group.
2. The pneumatic tire according to claim 1 , wherein R 1 and R 2 in Formula (Ia) are C 1-6 hydrocarbyl groups.
3. The pneumatic tire according to claim 1 , wherein two of X 1 , X 2 , and X 3 in Formula (I) are each a group represented by Formula (Ia) or a hydroxy group.
4. The pneumatic tire according to claim 1 , wherein A 1 in Formula (II) is a group represented by the following Formula (IIa):
wherein R 14 and R 15 each independently represent a C 1-6 group optionally containing at least one atom selected from the group consisting of a nitrogen atom, an oxygen atom, and a silicon atom, R 14 and R 15 may be bonded to each other to form a cyclic structure together with the nitrogen atom, and R 14 and R 15 may form a single group bonded to the nitrogen via a double bond.
5. The pneumatic tire according to claim 1 , wherein the group represented by Formula (III) is a group represented by the following Formula (IIIa):
6. The pneumatic tire according to claim 5 , wherein the compound containing a group represented by Formula (III) is at least one compound selected from the group consisting of a compound represented by Formula (IIIa-1) below, a compound represented by Formula (IIIa-2) below, and a compound represented by Formula (IIIa-3) below,
wherein R 31 represents a hydrogen atom, a C 1-10 hydrocarbyl group, a C 1-10 substituted hydrocarbyl group, or a heterocyclic group containing at least one of a nitrogen atom or an oxygen atom as a heteroatom; and R 32 and R 33 each independently represent a C 1-10 group optionally containing at least one atom selected from the group consisting of a nitrogen atom, an oxygen atom, and a silicon atom, R 32 and R 33 may be bonded to each other to form a cyclic structure together with the nitrogen atom, and R 32 and R 33 may form a single group bonded to the nitrogen via a double bond,
wherein e represents an integer of 0 to 10; and R 34 and R 35 each independently represent a C 1-20 hydrocarbyl group or a C 1-20 substituted hydrocarbyl group,
wherein f represents an integer of 0 to 10; and R 36 represents a C 1-20 hydrocarbyl group or a C 1-20 substituted hydrocarbyl group.
7. The pneumatic tire according to claim 1 , wherein the compound containing a group represented by Formula (III) is a compound represented by the following Formula (IIIb-1):
wherein R 37 represents a hydrogen atom, a C 1-10 hydrocarbyl group, a C 1-10 substituted hydrocarbyl group, or a heterocyclic group containing at least one of a nitrogen atom or an oxygen atom as a heteroatom; R 38 and R 39 each independently represent a C 1-10 group optionally containing at least one atom selected from the group consisting of a nitrogen atom, an oxygen atom, and a silicon atom, R 38 and R 39 may be bonded to each other to form a cyclic structure together with the nitrogen atom, and R 38 and R 39 may form a single group bonded to the nitrogen via a double bond; and T represents a C 1-20 hydrocarbylene group or a C 1-20 substituted hydrocarbylene group.
8. The pneumatic tire according to claim 7 , wherein the compound represented by Formula (IIIb-1) is at least one compound selected from the group consisting of a compound represented by Formula (IIIb-1-1) below and a compound represented by Formula (IIIb-1-2) below,
wherein r represents an integer of 1 or 2; and Y 1 represents a nitrogen atom-containing functional group that is a substituent on the benzene ring, and when plural Y 1 groups are present, the plural Y 1 groups may be the same as or different from one another,
wherein s represents an integer of 1 or 2; t represents an integer of 0 to 2; and Y 2 and Y 3 each represent a nitrogen atom-containing functional group that is a substituent on the benzene ring, and when plural Y 2 groups are present, the plural Y 2 groups may be the same as or different from one another, and when plural Y 3 groups are present, the plural Y 3 groups may be the same as or different from one another.
9. The pneumatic tire according to claim 1 , wherein A 4 in Formula (IV) is a hydroxy group or a group represented by the following Formula (IVa):
wherein R 23 and R 24 each independently represent a C 1-6 group optionally containing at least one atom selected from the group consisting of a nitrogen atom, an oxygen atom, and a silicon atom, R 23 and R 24 may be bonded to each other to form a cyclic structure together with the nitrogen atom, and R 23 and R 24 may form a single group bonded to the nitrogen via a double bond.
10. The pneumatic tire according to claim 1 , wherein the silicon compound contains a group represented by the following Formula (VIII):
wherein R 41 , R 42 , and R 43 each independently represent a C 1-4 hydrocarbyl group or a C 1-4 hydrocarbyloxy group, and at least one of R 41 , R 42 , and R 43 is a hydrocarbyloxy group.
11. The pneumatic tire according to claim 1 , wherein the silicon compound contains a group represented by the following Formula (Va):
wherein h represents an integer of 1 to 10; and R 44 , R 45 , and R 46 each independently represent a C 1-4 hydrocarbyl group or a C 1-4 hydrocarbyloxy group, and at least one of R 44 , R 45 , and R 46 is a hydrocarbyloxy group.
12. The pneumatic tire according to claim 1 , wherein the compound containing a group represented by Formula (VII) is a compound represented by the following Formula (VII-1):
wherein z represents an integer of 0 to 10; R 71 represents a C 1-5 hydrocarbyl group; R 72 , R 73 , R 74 and R 75 each independently represent a hydrogen atom, a C 1-5 hydrocarbyl group, a C 1-5 substituted hydrocarbyl group, or a C 1-5 hydrocarbyloxy group, and when plural R 72 groups and plural R 73 groups are present, the plural R 72 groups and the plural R 73 groups may be the same as or different from one another; and R 76 and R 77 each independently represent a C 1-6 group optionally containing at least one atom selected from the group consisting of a nitrogen atom, an oxygen atom, and a silicon atom, R 76 and R 77 may be bonded to each other to form a cyclic structure together with the nitrogen atom, and R 76 and R 77 may form a single group bonded to the nitrogen via a double bond.
13. The pneumatic tire according to claim 12 , wherein one of R 74 and R 75 in Formula (VII-1) is a hydrogen atom.
14. The pneumatic tire according to claim 1 , wherein the conjugated diene polymer has a vinyl bond content of at least 10 mol % but not more than 80 mol % per 100 mol % of the constituent unit based on a conjugated diene.
15. The pneumatic tire according to claim 1 , wherein the rubber component comprises at least one of natural rubber or polybutadiene rubber.
16. The pneumatic tire according to claim 1 , wherein the silica has a nitrogen adsorption specific surface area of 40 to 400 m 2 / g.
17. The pneumatic tire according to claim 1 , wherein the rubber component comprises 10 to 30% by mass of natural rubber, 10 to 30% by mass of polybutadiene rubber and 30 to 80% by mass of the conjugated diene polymer; and wherein the silica is present in an amount of 45 to 100 parts by mass relative to 100 parts by mass of the rubber component.
18. The pneumatic tire according to claim 1 , wherein the rubber component comprises 10 to 30% by mass of natural rubber, 10 to 30% by mass of polybutadiene rubber and 30 to 80% by mass of the conjugated diene polymer.