Adhesive film and display member using same
An adhesive film of the present invention comprises a (meth)acrylate-based copolymer and a cross-linking agent, and a gel fraction thereof is approximately 50-95%, and a ratio of change G′ in storage modulus thereof, represented by the following formula 1, is 20% or less. G ′=( G 7− G 1)/ G 1×100 [Formula 1] (In formula 1, G1 is a storage modulus at 25° C. when the adhesive film is matured at 23° C. and a relative humidity (RH) of 55% for one day, and G7 represents a storage modulus at 25° C. when the adhesive film is matured at 23° C. and an RH of 55% for seven days.)
1. A pressure-sensitive adhesive film comprising a (meth)acrylate copolymer and a crosslinker and having a gel fraction of about 50% to about 95% and a storage modulus variation G′ of about 20% or less as represented by Equation 1:
G ′=( G 7− G 1)/ G 1×100 [Equation 1]
where G1 is the storage modulus of the pressure-sensitive adhesive film at 25° C. after aging at 23° C. and 55% RH for 1 day and G7 is the storage modulus of the pressure-sensitive adhesive film at 25° C. after aging at 23° C. and 55% RH for 7 days.
2. The pressure-sensitive adhesive film according to claim 1 , wherein the pressure-sensitive adhesive film has a storage modulus variation G′ of about 0.5% to about 10%.
3. The pressure-sensitive adhesive film according to claim 1 , wherein the pressure-sensitive adhesive film has storage moduli G1 and G7 at 25° C. of about 10 5 Pa to about 10 6 Pa.
4. The pressure-sensitive adhesive film according to claim 1 , wherein the pressure-sensitive adhesive film has a gel fraction difference of about 10% or less as calculated by Equation 2:
Gel fraction difference=GF7−GF1 [Equation 2]
where GF7 is the gel fraction after aging for 7 days as calculated by Equation 3 and GF1 is the gel fraction after aging for 1 day as calculated by Equation 3:
Gel fraction (%)=( WC−WA )/( WB−WA )×100 [Equation 3]
where WA is the weight of a wire mesh; WB is the total weight of 0.5 g of a specimen covered with the wire mesh, in which the specimen is obtained by aging the pressure-sensitive adhesive film at 23° C. and 55% RH for 1 day or 7 days; and WC is the total weight of the pressure-sensitive adhesive film and the wire mesh obtained by placing a specimen, obtained by aging the pressure-sensitive adhesive film and covered with the wire mesh, in a sample bottle and adding 50 cc of ethyl acetate to the sample bottle, followed by storage at 25° C. for 1 day and drying at 100° C. for 12 hours.
5. The pressure-sensitive adhesive film according to claim 1 , wherein the pressure-sensitive adhesive film has an acid value of about 0.
6. The pressure-sensitive adhesive film according to claim 1 , wherein the (meth)acrylate copolymer has a weight average molecular weight of about 100,000 g/mol to about 1,500,000 g/mol.
7. The pressure-sensitive adhesive film according to claim 1 , wherein the (meth)acrylate copolymer has a polydispersity index (PDI) of about 2.5 to about 6.0.
8. The pressure-sensitive adhesive film according to claim 1 , wherein the (meth)acrylate copolymer has a glass transition temperature (Tg) of about −40° C. to about −10° C.
9. The pressure-sensitive adhesive film according to claim 1 , wherein the (meth)acrylate copolymer is a copolymer of a monomer mixture comprising an alkyl (meth)acrylate monomer, a monomer having a glass transition temperature (Tg) of about 50° C. or higher, and an oxygen-containing heterocyclic ring containing monomer.
10. The pressure-sensitive adhesive film according to claim 9 , wherein the (meth)acrylate copolymer comprises about 60 wt % to about 94.9 wt % of the alkyl (meth)acrylate monomer, about 5 wt % to about 30 wt % of the monomer having a glass transition temperature (Tg) of about 50° C. or higher, and about 0.1 wt % to about 10 wt % of the oxygen-containing heterocyclic ring containing monomer.
11. A display member comprising the pressure-sensitive adhesive film of claim 1 .
12. A pressure-sensitive adhesive film comprising:
a (meth)acrylate copolymer, the (meth)acrylate copolymer comprising a copolymer of a monomer mixture comprising an alkyl (meth)acrylate monomer, a monomer having a glass transition temperature (Tg) of about 50° C. or higher and an oxygen-containing heterocyclic ring containing monomer; and a crosslinker,
wherein the pressure-sensitive adhesive film has a storage modulus variation G′ of about 20% or less as represented by Equation 1:
G ′=( G 7− G 1)/ G 1×100 [Equation 1]
where G1 is the storage modulus of the pressure-sensitive adhesive film at 25° C. after aging at 23° C. and 55% RH for 1 day and G7 is the storage modulus of the pressure-sensitive adhesive film at 25° C. after aging at 23° C. and 55% RH for 7 days.
13. The pressure-sensitive adhesive film according to claim 12 , wherein the alkyl (meth)acrylate monomer comprises (meth)acrylate esters having a C 1 to C 20 linear or branched alkyl group.
14. The pressure-sensitive adhesive film according to claim 12 , wherein the monomer having a glass transition temperature (Tg) of about 50° C. or higher comprises at least one of N-vinylpyrrolidone, acrylamide, N-alkyl substituted acrylamide, acryloylmorpholine, isobornyl acrylate, and cyclohexyl methacrylate.
15. The pressure-sensitive adhesive film according to claim 12 , wherein the oxygen-containing heterocyclic ring containing monomer comprises at least one oxygen-containing heterocyclic ring of an epoxy group, an oxetane group, and a tetrahydrofurfuryl group.
16. The pressure-sensitive adhesive film according to claim 12 , wherein the oxygen-containing heterocyclic ring containing monomer comprises at least one of glycidyl methacrylate, oxetane methacrylate, and tetrahydrofurfuryl acrylate.
17. The pressure-sensitive adhesive film according to claim 12 , wherein the pressure-sensitive adhesive film further comprises a silane coupling agent.
18. The pressure-sensitive adhesive film according to claim 12 , wherein the pressure-sensitive adhesive film has storage moduli G1 and G7 at 25° C. of about 10 5 Pa to about 10 6 Pa.
19. A pressure-sensitive adhesive film comprising:
a (meth)acrylate copolymer, the (meth)acrylate copolymer comprising a copolymer of a monomer mixture comprising an alkyl (meth)acrylate monomer, a monomer having a glass transition temperature (Tg) of about 50° C. or higher and an oxygen-containing heterocyclic ring containing monomer; and a crosslinker,
wherein the pressure-sensitive adhesive film has a gel fraction difference of about 10% or less as calculated by Equation 2:
Gel fraction difference=GF7−GF1 [Equation 2]
where GF7 is the gel fraction after aging for 7 days as calculated by Equation 3 and GF1 is the gel fraction after aging for 1 day as calculated by Equation 3:
Gel fraction (%)=( WC−WA )/( WB−WA )×100 [Equation 3]
where WA is the weight of a wire mesh; WB is the total weight of 0.5 g of a specimen covered with the wire mesh, in which the specimen is obtained by aging the pressure-sensitive adhesive film at 23° C. and 55% RH for 1 day or 7 days; and WC is the total weight of the pressure-sensitive adhesive film and the wire mesh obtained by placing the specimen, which is obtained by aging the pressure-sensitive adhesive film and covered with the wire mesh, in a sample bottle and adding 50 cc of ethyl acetate to the sample bottle, followed by storage at 25° C. for 1 day and drying at 100° C. for 12 hours.