IP Library Granted Patent US 10,253,191
Granted Patent B2
US 10,253,191 · App. 13/992,116 · Granted Apr 9, 2019

Magnetic pigments

Inventors: Kaiman Shimizu (Roth, DE); Fumiko Sasaki (Iwaki, JP); Yukitaka Watanabe (Iwaki, JP); Masahiko Yazawa (Iwaki, JP)
Assignee: MERCK PATENT GMBH
C09D5/23B42D15/00C09C1/0015C09D11/037C09D11/322C01P2006/42C09C2200/102C09C2200/1004C09C2200/301C09C2200/302C09C2200/401C09C2220/106H01F1/37
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Quick Facts
Patent No.
US 10,253,191
App. No.
13/992,116
Granted
Apr 9, 2019
Kind
B2
Abstract

The present invention is related to magnetic pigments comprising a transparent flaky homogeneously composed substrate having two parallel major surfaces and a coating comprising a layered structure composed of a hematite and a magnetite layer, to a process for the production of said pigments as well as to their use.

Claims (12)

1. A magnetic pigment, comprising

a transparent flaky homogeneous substrate having two parallel major surfaces wherein said substrate is a synthetically produced material of Al 2 O 3 , of Al 2 O 3 containing up to 5% by weight TiO 2 , of SiO 2 , of SiO 2 containing up to 20% by weight silicon hydroxide, of glass or of a borosilicate

and

a coating comprising a layered structure, said layered structure consisting of a first layer comprising hematite and/or goethite having a thickness, and of a second layer comprising magnetite, the second layer having a thickness and being located on the first layer, in this sequence, at least on the two major surfaces of the substrate, wherein the thickness of the second layer of magnetite is larger than the thickness of the first layer of hematite and/or goethite

and

wherein the magnetic pigments further comprise one or more dielectric layers on top of the magnetite layer wherein said dielectric layer comprises a silicon oxide hydrate layer being located directly on the magnetite layer and a high refractive index layer on the silicon oxide hydrate layer.

2. A magnetic pigment according to claim 1 , wherein the substrate has a mean thickness between 100 and 1000 nm.

3. A magnetic pigment according to claim 1 , wherein the layer composed of hematite and/or goethite is located directly onto the substrate.

4. A magnetic pigment according to claim 1 , wherein there is at least one dielectric coating located between the substrate and the layer composed of hematite and/or goethite.

5. A magnetic pigment according to claim 1 , wherein the magnetite layer is doped with an aluminum compound.

6. A magnetic pigment according to claim 5 , wherein the aluminum compound is an oxide and/or an oxide hydrate.

7. A magnetic pigment according to claim 5 , wherein the content of the aluminum compound is between 0.1 and less than 5% by weight, based on the weight of the magnetite layer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 6, 2013
From: SHIMIZU, KAIMAN; SASAKI, FUMIKO; WATANABE, YUKITAKA; YAZAWA, MASAHIKO
To: MERCK PATENT GMBH
Reel/Frame 030561/0215 →
Priority Claims (1)
EP 10015472 · Dec 9, 2010 · regional
Continuity (1)
Related Publication 20130257035A1 · Oct 3, 2013
Cited By (2)
US 12,194,698 US 12,503,604