Three-dimensional semiconductor memory device and method for manufacturing the same
View Patent ↗A semiconductor memory device includes first and second electrode films, an interlayer insulating film, a semiconductor pillar, and a first insulating film. The first electrode film extends in a first direction. The second electrode film is provided separately from the first electrode film in a second direction and extends in the first direction. The interlayer insulating film is provided between the first and the second electrode films. The first insulating film includes first and second insulating regions. A concentration of nitrogen in the first position of the second insulating region is higher than a concentration of nitrogen in the second position between the first position and the semiconductor pillar. A concentration of nitrogen in the first insulating region is lower than the concentration of the nitrogen in the first position.
1. A device, comprising:
a first electrode film extending in a first direction;
a second electrode film being provided separately from the first electrode film in a second direction intersecting the first direction and extending in the first direction;
an interlayer insulating film being provided between the first electrode film and the second electrode film;
a semiconductor pillar piercing the first electrode film, the second electrode film, and the interlayer insulating film in the second direction;
a first insulating film including a first insulating region and a second insulating region, the first insulating region being provided between the first electrode film and the semiconductor pillar and between the second electrode film and the semiconductor pillar, and the second insulating region being provided between the interlayer insulating film and the semiconductor pillar;
a second insulating film directly contacting the semiconductor pillar; and
a charge storage film directly contacting and between the second insulating film and the first insulating film, the first insulating film including (i) a first silicon oxide layer, (ii) a second silicon oxide layer, (iii) a silicon nitride layer between the first silicon oxide layer and the second silicon oxide layer, wherein the maximum length of the silicon nitride layer along the second direction is shorter than a first length of the interlayer insulating film along the second direction,
a first concentration of nitrogen in a first position of the second insulating region being higher than a second concentration of nitrogen in a second position of the second insulating region between the first position and the semiconductor pillar, and
an average concentration of nitrogen in the first insulating region being lower than the first concentration of the nitrogen in the first position.
2. The device according to claim 1 , wherein
a third concentration of nitrogen in a third position between the first position and the interlayer insulating film is lower than the first concentration of the nitrogen in the first position.
3. The device according to claim 2 , further comprising the charge storage film being provided between the semiconductor pillar and the first insulating film.
4. The device according to claim 3 , further comprising the second insulating film being provided between the semiconductor pillar and the charge storage film.
5. The device according to claim 3 , wherein
the first insulating region is provided between the first electrode film and the charge storage film and between the second electrode film and the charge storage film, and includes silicon oxide, and
the second insulating region is provided between the interlayer insulating film and the charge storage film, and includes silicon nitride.
6. The device according to claim 5 , wherein
a silicon nitride film is provided on the first position,
a first silicon oxide film is provided on the second position, and
a second silicon oxide film is provided on the third position.
7. The device according to claim 6 , wherein
a first length along the second direction of the silicon nitride film is shorter than a second length along the second direction of the interlayer insulating film.
8. The device according to claim 3 , wherein the charge storage film includes silicon nitride.
9. The device according to claim 4 , wherein the second insulating film includes silicon oxide.
10. The device according to claim 1 , further comprising:
a barrier metal film being provided between the first electrode film and the first insulating region and between the first electrode film and the interlayer insulating film; and
a third insulating film being provided between the barrier metal film and the first insulating region and between the barrier metal film and the interlayer insulating film.
11. The device according to claim 10 , wherein the third insulating film includes aluminum oxide.
12. The device according to claim 1 , wherein the interlayer insulating film includes silicon oxide.
13. The device according to claim 6 , further comprising a fourth insulating film being provided between the silicon nitride film provided on the first position and the first silicon oxide film provided on the second position.
14. The device according to claim 13 , wherein the fourth insulating film includes aluminum oxide.
15. The device according to claim 6 , further comprising a fourth insulating film being provided between the silicon nitride film provided on the first portion and the second silicon oxide film provided on the third portion.
16. The device according to claim 15 , wherein the fourth insulating film includes aluminum oxide.