Catalytic wall-flow filter having a membrane
The present invention relates to a catalytic wall-flow monolith for use in an emission treatment system, the monolith comprising a porous substrate and having a first face and a second face defining a longitudinal direction therebetween and first and second pluralities of channels extending in the longitudinal direction, the first plurality of channels provides a first plurality of inner surfaces and is open at the first face and closed at the second face, and the second plurality of channels is open at the second face and closed at the first face, a first catalytic material is distributed within the porous substrate, a microporous membrane is provided in the first plurality of channels on a first portion, extending in the longitudinal direction, of the first plurality of inner surfaces, and the first portion extends from the first face for 75 to 95% of a length of the first plurality of channels.
1. A catalytic wall-flow monolith for use in an emission treatment system, the monolith comprising a porous substrate and having a first face and a second face defining a longitudinal direction therebetween and first and second pluralities of channels extending in the longitudinal direction,
wherein the first plurality of channels provides a first plurality of inner surfaces and is open at the first face and closed at the second face, and wherein the second plurality of channels is open at the second face and closed at the first face,
wherein a first catalytic material is distributed within the porous substrate,
wherein a microporous membrane is provided in the first plurality of channels on a first portion, extending in the longitudinal direction, of the first plurality of inner surfaces, and
wherein the first portion extends from the first face for 75 to 95% of a length of the first plurality of channels, wherein the length is the internal length of a cavity from the first face to the internal sealed end of the first plurality of channels.
2. The catalytic wall-flow monolith according to claim 1 , wherein the first portion extends 80 to 90% of a length of the first plurality of channels.
3. The catalytic wall-flow monolith according to claim 1 , wherein the microporous membrane has a thickness which decreases along the longitudinal direction, such that the thickness is greatest in a region adjacent the first face.
4. The catalytic wall-flow monolith according to claim 1 , wherein the porous substrate has a first section extending in the longitudinal direction from the first face and a second section extending in the longitudinal direction from the second face and extending to the first section, and wherein the first catalytic material is distributed throughout the second section.
5. The catalytic wall-flow monolith according to claim 4 , wherein a ratio of a length of the first section in the longitudinal direction to the length of the second section in the longitudinal direction is from 5:95 to 15:85.
6. An emission treatment system for treating a flow of a combustion exhaust gas, the system comprising the catalytic wall-flow monolith according to claim 1 , wherein the second face is downstream of the first face.
7. A method for the manufacture of a catalytic wall-flow monolith according to claim 1 , the method comprising:
providing a porous substrate having a first face and an second face defining a longitudinal direction therebetween and first and second pluralities of channels extending in the longitudinal direction, wherein the first plurality of channels is open at the first face and closed at the second face, and wherein the second plurality of channels is open at the second face and closed at the first face, wherein the first plurality of channels provide a first plurality of inner surfaces and wherein the second plurality of channels provide a second plurality of inner surfaces,
infiltrating the porous substrate with a washcoat containing a first catalytic material to provide the first catalytic material distributed within the porous substrate; and
forming a microporous membrane on the first plurality of inner surfaces.
8. A method for treating a flow of a combustion exhaust gas comprising NO x and particulate matter, the method comprising passing the exhaust stream through the monolith of claim 1 , wherein the second face is downstream of the first face.