Use of hollow polymeric microspheres in composite materials requiring flame resistance
Disclosed is method of preparing microspheres wherein the microspheres do not increase the self-extinguishing time of a composition they are added to by more than 5% and their presence does not increase a viscosity of the composition by more than 65%. The microspheres are coated with a very high level of from 80 to 90% by weight of a flame retardant, preferably aluminum trihydroxide. Unexpectedly, the presence of the flame retardant on the microspheres at this high level reduces the need to add additional flame retardant to a composition along with the microspheres. Also unexpectedly, the location of the flame retardant on the microspheres completely prevents the normally expected increase in viscosity of the composition based on the level of the flame retardant added. The microspheres find use in many compositions requiring flame resistance including weld through sealants and adhesives.
1. A composition comprising:
a base component comprising a weld through sealant;
a plurality of hollow, expanded microspheres having a composite density of 0.1 g/cm 3 or greater and comprising from 80 to 90% by weight of aluminum trihydroxide, wherein said microspheres are present in an amount of from 1 to 25% by weight based on the total weight of said composition and wherein the presence of said microspheres does not increase a self-extinguishing time of said base component by more than 5%.
2. The composition as recited in claim 1 , wherein said weld through sealant has a self-extinguishing time of from 3 to 5 seconds.
3. The composition as recited in claim 1 , wherein a viscosity of said composition is not increased by more than 65% by addition of said microspheres.
4. The composition as recited in claim 1 , wherein said hollow, expanded microspheres have a composite density of 0.12 g/cm 3 or greater.
5. The composition as recited in claim 1 , wherein said hollow, expanded microspheres comprise acrylonitrile.
6. The composition as recited in claim 1 , wherein said microspheres are present in an amount of from 1 to 5% by weight based on the total weight of the composition.
7. The composition as recited in claim 1 , wherein the presence of said microspheres does not increase a self-extinguishing time of said base component by more than 3%.
8. A method of maintaining the nonflammability of a base component while reducing its density comprising the steps of:
a) providing a base component comprising a weld through sealant;
b) providing a plurality of hollow, expanded microspheres having a composite density of 0.1 g/cm 3 or greater and comprising from 80 to 90% by weight of aluminum trihydroxide;
c) combining said microspheres in an amount of from 1 to 25% by weight based on the total weight of said composition with said base composition, wherein addition of said microspheres does not increase self-extinguishing time of said base component by more than 5%.
9. The method as recited in claim 8 , comprising providing the weld through sealant having a self-extinguishing time of from 3 to 5 seconds.
10. The method as recited in claim 8 , wherein step b) comprises providing hollow, expanded microspheres having a composite density of 0.12 g/cm 3 or greater.
11. The method as recited in claim 8 , wherein step b) comprises providing hollow, expanded microspheres comprising acrylonitrile.
12. The method as recited in claim 8 , wherein step c) comprises combining said microspheres in an amount of from 1 to 5% by weight based on the total weight of said composition.
13. The method as recited in claim 8 , comprising providing hollow expanded microspheres that do not increase said self-extinguishing time of said base component by more than 3%.
14. The method as recited in claim 8 , comprising providing hollow expanded microspheres that do not increase a viscosity of said base component by more than 65%.
15. A laminate comprising:
a metal substrate; and
a composition applied to said metal substrate; said composition comprising a weld through sealant and a plurality of microspheres, said microspheres present in an amount of from 1 to 25% by weight based on a total weight of said composition and wherein said microspheres comprise 80 to 90% by weight of aluminum trihydroxide and have a composite density of 0.1 g/cm 3 or greater, and wherein the presence of said microspheres does not increase a self-extinguishing time of said weld through sealant by more than 5%.
16. The laminate of claim 15 wherein said microspheres are present in an amount of 1 to 5% by weight.
17. The laminate of claim 15 wherein said self-extinguishing time of said weld through sealant is from 3 to 5 seconds.
18. The laminate of claim 15 wherein the presence of said microspheres does not increase a viscosity of said weld through sealant by more than 65%.