Micro-nano composite plugging agent for drilling fluid and preparation method thereof, and drilling fluid and use thereof
The present invention discloses a micro-nano composite plugging agent for drilling fluid, a preparation method of the micro-nano composite plugging agent for drilling fluid, a drilling fluid, and an application thereof. The composite plugging agent contains nanometer calcium carbonate, nanometer zinc oxide whiskers, nanometer emulsified paraffin, a flocculating agent, and a lubricant, wherein in the composite plugging agent, the nanometer calcium carbonate is in 10-36 parts by weight, the nanometer zinc oxide whiskers are in 20-40 parts by weight, the nanometer emulsified paraffin is in 30-70 parts by weight, the flocculating agent is in 1-10 parts by weight, and the lubricant is 5-20 parts by weight.
1. A micro-nano composite plugging agent for drilling fluid,
containing nanometer calcium carbonate, nanometer zinc oxide whiskers, nanometer emulsified paraffin, a flocculating agent, and a lubricant, wherein in the composite plugging agent, the nanometer calcium carbonate is in 10-36 parts by weight, the nanometer zinc oxide whiskers are in 20-40 parts by weight, the nanometer emulsified paraffin is in 30-70 parts by weight, the flocculating agent is in 1-10 parts by weight, and the lubricant is in 5-20 parts by weight.
2. The micro-nano composite plugging agent according to claim 1 , wherein in the composite plugging agent, the nanometer calcium carbonate is in 18-22 parts by weight, the nanometer zinc oxide whiskers are in 32-34 parts by weight, the nanometer emulsified paraffin is in 52-54 parts by weight, the flocculating agent is in 3-5 parts by weight, and the lubricant is in 7-9 parts by weight.
3. The micro-nano composite plugging agent according to claim 1 , wherein the nanometer calcium carbonate is spherical white powder in 20-30 nm average particle diameter.
4. The micro-nano composite plugging agent according to claim 3 , wherein the nanometer calcium carbonate is in 22-28 nm average particle diameter.
5. The micro-nano composite plugging agent according to claim 1 , wherein the nanometer zinc oxide whiskers are in a slender needled shape in 100-150 nm average length.
6. The micro-nano composite plugging agent according to claim 5 , wherein the nanometer zinc oxide whiskers are in a slender needled shape in 120-130 nm average length.
7. The micro-nano composite plugging agent according to claim 1 , wherein the nanometer emulsified paraffin is in a spherical shape at normal temperature, and the average particle diameter of the nanometer emulsified paraffin is 10-15 nm.
8. The micro-nano composite plugging agent according to claim 7 , wherein the average particle diameter of the nanometer emulsified paraffin is 11-13 nm.
9. The micro-nano composite plugging agent according to claim 1 , wherein the flocculating agent is polyacrylamide powder in 25-80 μm average particle diameter.
10. The micro-nano composite plugging agent according to claim 9 , wherein the the flocculating agent is in 30-60 μm average particle diameter.
11. The micro-nano composite plugging agent according to claim 1 , wherein the lubricant is sulfonated bitumen powder in 30-60 nm average particle diameter.
12. The micro-nano composite plugging agent according to claim 11 , wherein the lubricant is in 40-50 nm average particle diameter.
13. A method for preparing the micro-nano composite plugging agent according to claim 1 , comprising: mixing the nanometer calcium carbonate, the nanometer zinc oxide whiskers, the nanometer emulsified paraffin, the flocculating agent, and the lubricant sequentially while stirring.