IP Library Granted Patent US 10,396,306
Granted Patent B2
US 10,396,306 · App. 15/970,252 · Granted Aug 27, 2019

Electroluminescent device capable of improving luminous efficiency by preventing a leakage current and improving electron transport properties and a display device including the same

Inventors: Sung Woo Kim (Hwaseong-si, KR); Tae Ho Kim (Suwon-si, KR); Kun Su Park (Seongnam-si, KR); Chan Su Kim (Seoul, KR); Eun Joo Jang (Suwon-si, KR)
Assignee: SAMSUNG ELECTRONICS CO., LTD.
H01L51/5072G09G3/3208H01L51/504H01L51/508H01L51/5024H01L51/5056H01L51/5076H01L51/5203H05B33/20
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Quick Facts
Patent No.
US 10,396,306
App. No.
15/970,252
Granted
Aug 27, 2019
Kind
B2
Abstract

An electroluminescent device, a method of manufacturing the same, and a display device including the same are disclosed. The electroluminescent device electroluminescent device includes a first electrode; a hole transport layer disposed on the first electrode; an emission layer disposed on the hole transport layer and including at least two light emitting particles; a first electron transport layer disposed on the emission layer and including at least two inorganic-organic composite particles; a second electron transport layer disposed on the first electron transport layer and including at least two inorganic oxide particles; and a second electrode disposed on the second electron transport layer, wherein the first electron transport layer has a lower work function than the second electron transport layer.

Claims (24)

1. An electroluminescent device, comprising

a first electrode;

a hole transport layer disposed on the first electrode;

an emission layer disposed on the hole transport layer and comprising at least two light emitting particles;

a first electron transport layer disposed on the emission layer and comprising at least two inorganic-organic composite particles;

a second electron transport layer disposed on the first electron transport layer and comprising at least two inorganic oxide particles; and

a second electrode disposed on the second electron transport layer,

wherein the first electron transport layer has a lower work function than the second electron transport layer.

2. The electroluminescent device of claim 1 , wherein each of the inorganic-organic composite particles comprises an inorganic material core and at least two organic polymers bound to a surface of the inorganic material core.

3. The electroluminescent device of claim 2 , wherein the organic polymers is present in an amount in a range of about 3 weight percent to about 20 weight percent, based on a total amount of the first electron transport layer.

4. The electroluminescent device of claim 2 , wherein the organic polymers comprises at least one of an imine compound, an imine compound, an alcohol compound, an acrylic compound, a glycol compound, or a derivative thereof.

5. The electroluminescent device of claim 2 , wherein the inorganic material core comprises at least one of ZnO, TiO 2 , ZrO 2 , SnO 2 , WO 3 , Ta 2 O 3 , or a combination thereof.

6. The electroluminescent device of claim 2 , wherein an average particle diameter of the inorganic material cores is less than or equal to about 100 nanometers.

7. The electroluminescent device of claim 1 , wherein a difference between lowest unoccupied molecular orbital energy levels of the first electron transport layer and the second electron transport layer is greater than about 0 electronvolts and less than or equal to about 0.5 electronvolts.

8. The electroluminescent device of claim 1 , wherein the second electron transport layer is directly on the first electron transport layer.

9. The electroluminescent device of claim 1 , wherein the first electron transport layer has a thickness in a range of about 5 nanometers to about 25 nanometers.

10. The electroluminescent device of claim 1 , wherein the second electron transport layer has a thickness in a range of about 15 nanometers to about 35 nanometers.

11. The electroluminescent device of claim 1 , wherein the second electron transport layer consists of the at least two inorganic oxide particles.

12. The electroluminescent device of claim 1 , wherein the inorganic oxide particles comprise at least one of ZnO, TiO 2 , ZrO 2 , SnO 2 , WO 3 , Ta 2 O 3 , or a combination thereof.

13. The electroluminescent device of claim 1 , wherein at least one of the light emitting particles has a core-shell structure.

14. The electroluminescent device of claim 1 , wherein at least one of the light emitting particles comprises a Group II-VI compound that does not comprise Cd, a Group III-V compound, a Group IV-VI compound, a Group IV element or compound, a Group compound, a Group I-II-IV-VI compound that does not comprise Cd, or a combination thereof.

15. The electroluminescent device of claim 1 , wherein the first electron transport layer has a higher lowest unoccupied molecular orbital energy level than the second electron transport layer, and

the emission layer has a same lowest unoccupied molecular orbital energy level as the first electron transport layer or a higher lowest unoccupied molecular orbital energy level than the first electron transport layer.

16. A display device comprising the electroluminescent device of claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2019
From: KIM, SUNG WOO; KIM, TAE HO; PARK, KUN SU; KIM, CHAN SU; JANG, EUN JOO
To: SAMSUNG ELECTRONICS CO., LTD.
Reel/Frame 049139/0550 →
Priority Claims (1)
KR 10-2017-0181077 · Dec 27, 2017 · national
Continuity (1)
Related Publication 20190198796A1 · Jun 27, 2019
Cited By (1)
US 12,684,937