IP Library Granted Patent US 10,396,397
Granted Patent B2
US 10,396,397 · App. 15/445,433 · Granted Aug 27, 2019

Graphene compound, method for forming graphene compound, and lithium-ion storage battery

Inventors: Hiroshi Kadoma (Kanagawa, JP); Teppei Oguni (Kanagawa, JP); Satoshi Seo (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01M10/0565C01B32/194C01B32/198C01B32/23H01M2/0275H01M10/0525H01M10/0585C01B2204/22H01M2300/0082Y02E60/122Y02P70/54Y02T10/7011
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Quick Facts
Patent No.
US 10,396,397
App. No.
15/445,433
Granted
Aug 27, 2019
Kind
B2
Abstract

A material that can be used in a wide temperature range is provided. A graphene compound includes graphene or graphene oxide and a substituted or unsubstituted chain group, the chain group includes two or more ether bonds, and the chain group is bonded to the above graphene or graphene oxide through a Si atom. Alternatively, a method for forming a graphene compound includes a first step and a second step after the first step. In the first step, graphene oxide and a base are stirred under a nitrogen stream. In the second step, the mixture is cooled to room temperature, a silylating agent that has a group having two or more ether bonds is introduced into the mixture, and the obtained mixture is stirred. The base is butylamine, pentylamine, hexylamine, diethylamine, dipropylamine, dibutylamine, triethylamine, tripropylamine, or pyridine.

Claims (25)

1. A graphene compound comprising:

graphene or graphene oxide; and

a substituted or unsubstituted chain group,

wherein the chain group comprises at least two or more ether bonds,

wherein the chain group is bonded to the graphene or graphene oxide through a Si atom, and

wherein a structure of the graphene compound is represented by a formula (200) shown below:

wherein GO represents the graphene or graphene oxide, and

wherein R represents the substituted or unsubstituted chain group.

2. The graphene compound according to claim 1 ,

wherein the chain group comprises 2 to 20 ether bonds.

3. The graphene compound according to claim 1 ,

wherein the chain group comprises 4to 20 ether bonds.

4. The graphene compound according to claim 1 ,

wherein the structure of the graphene compound is represented by a formula (201) shown below:

wherein GO represents the graphene or graphene oxide.

5. The graphene compound according to claim 1 ,

wherein the structure of the graphene compound is represented by a formula (202) shown below:

wherein GO represents the graphene or graphene oxide.

6. The graphene compound according to claim 1 ,

wherein a length in the longitudinal direction of the graphene or graphene oxide is greater than or equal to 50 nm and less than or equal to 100 μm.

7. A lithium-ion storage battery comprising:

the graphene compound according to claim 1 ;

an exterior body;

a positive electrode current collector; and

a negative electrode current collector.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 28, 2017
From: KADOMA, HIROSHI; OGUNI, TEPPEI; SEO, SATOSHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 041403/0310 →
Priority Claims (1)
JP 2016-040093 · Mar 2, 2016 · national
Continuity (1)
Related Publication 20170256817A1 · Sep 7, 2017
Cited By (1)
US 12,218,305