Composition with self-healing property, film with self-healing property and device including the film
A self-healing composition including, urethane (meth)acrylate having two (meth)acrylate groups, six or more urethane groups, and a substituted or unsubstituted polyhedral silsesquioxane.
1. A self-healing composition comprising,
a urethane (meth)acrylate having two (meth)acrylate groups, and six or more urethane groups, and
a substituted or unsubstituted polyhedral silsesquioxane;
wherein the urethane (meth)acrylate is a reaction product of a C1 to C20 aliphatic diisocyanate, a C1 to C100 aliphatic diol, and a C1 to C20 hydroxyalkyl(meth)acrylate;
wherein the C1 to C100 aliphatic diol comprises
about 50 weight percent to about 99 weight percent of a C10 to C100 polyalkylene glycol or a polylactone glycol, and
about 1 weight percent to about 50 weight percent of C1 to C9 alkylene glycol, based on a total weight of the C1-C100 aliphatic diol in the urethane (meth)acrylate.
2. The self-healing composition of claim 1 , wherein the urethane (meth)acrylate is represented by Chemical Formula 1:
wherein, in Chemical Formula 1,
n is a number ranging from 2 to 30,
R 1 is a hydrogen atom or a methyl group,
R 2 and R 3 are each independently a substituted or unsubstituted C1 to C20 alkylene group, or a substituted or unsubstituted C3 to C20 cycloalkylene group, and
R 4 is a substituted or unsubstituted C1 to C10 alkylene, a C2 to C100 divalent functional group including an ether group, an ester group, or a combination of the ether group and the ester group, or a combination thereof.
3. The self-healing composition of claim 2 , wherein the —O—R 4 —O— moiety of Chemical Formula 1 is represented by Chemical Formula 4-1 to Chemical Formula 4-4, or a combination thereof:
wherein, in Chemical Formula 4-1 to Chemical Formula 4-4, R 11 to R 18 are each independently a substituted or unsubstituted C1 to C10 alkylene group, and
wherein, in Chemical Formula 4-2 to Chemical Formula 4-4, a, b, x, and y are each independently a number ranging from 2 to 100.
4. The self-healing composition of claim 3 , wherein the —O—R 4 —O— moiety of Chemical Formula 1 is represented by Chemical Formula 4-11 to Chemical Formula 4-17, or a combination thereof:
wherein, in Chemical Formula 4-14 to Chemical Formula 4-17, a1, a2, a3, x1, and y1 are each independently a number ranging from 2 to 100.
5. The self-healing composition of claim 2 , wherein R 3 of Chemical Formula 1 is represented by Chemical Formula 3-1 to Chemical Formula 3-6, or a combination thereof:
6. The self-healing composition of claim 2 , wherein R 2 of Chemical Formula 1 is a substituted or unsubstituted C2 to C6 alkylene group.
7. The self-healing composition of claim 1 , wherein a weight average molecular weight of the urethane (meth)acrylate ranges from about 3,000 grams per mole to about 100,000 grams per mole.
8. The self-healing composition of claim 1 , wherein a glass transition temperature of the urethane (meth)acrylate ranges from about −40° C. to about 40° C.
9. The self-healing composition of claim 1 , wherein the polyhedral silsesquioxane is substituted with an alkyl group, an aryl group, a (meth)acryl group, a vinyl group, an amino group, an alcohol group, a carboxyl group, a halogen group, or a combination thereof.
10. The self-healing composition of claim 1 , wherein the polyhedral silsesquioxane is substituted with a phenyl group.
11. The self-healing composition of claim 1 , wherein the composition further includes a hardener, a solvent, or a combination thereof.
12. The self-healing composition of claim 11 , wherein the polyhedral silsesquioxane is present in an amount of about 0.1 weight percent to about 20 weight percent based on a total solid content of the self-healing composition.
13. The self-healing composition of claim 11 , wherein the hardener is present in an amount of about 0.01 wt % to about 5 weight percent based on a total solid content of the composition.
14. A self-healing film comprising, a cured product of a self-healing composition, the self-healing composition comprising:
a urethane (meth)acrylate having two (meth)acrylate groups and six or more urethane groups, and
a substituted or unsubstituted polyhedral silsesquioxane,
wherein the urethane (meth)acrylate is a reaction product of a C1 to C20 aliphatic diisocyanate, a C1 to C100 aliphatic diol, and a C1 to C20 hydroxyalkyl(meth)acrylate;
wherein the C1 to C100 aliphatic diol comprises
about 50 weight percent to about 99 weight percent of a C10 to C100 polyalkylene glycol or a polylactone glycol, and
about 1 weight percent to about 50 weight percent of C1 to C 9 alkylene glycol, based on a total weight of the C1-C100 aliphatic diol in the urethane (meth)acrylate.
15. The self-healing film of claim 14 , wherein a scratch in the self-healing film formed by a pencil having a hardness of 4H at a load of 1 kilogram-force is self-healed in 20 minutes.
16. The self-healing film of claim 14 , wherein light transmittance of the self-healing film is greater than or equal to about 90% and a yellowness index of the self-healing film is less than or equal to about 1.
17. A device comprising the self-healing film of claim 14 .
18. The device of claim 17 , wherein the device is a foldable display.
19. A self-healing composition comprising,
a urethane (meth)acrylate having two (meth)acrylate groups, and six or more urethane groups, and
a substituted or unsubstituted polyhedral silsesquioxane,
wherein the polyhedral silsesquioxane is substituted with an alkyl group, an aryl group, a (meth)acryl group, an amino group, an alcohol group, a carboxyl group, a halogen group, a phenyl group, or a combination thereof.
20. A device comprising a self-healing film, the self-healing film comprising a cured product of a self-healing composition, the self-healing composition comprising:
a urethane (meth)acrylate having two (meth)acrylate groups and six or more urethane groups, and
a substituted or unsubstituted polyhedral silsesquioxane,
wherein the device is a foldable display.