Esterified poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced properties
Resin compositions, layers, and interlayers comprising an acetoacetylized poly(vinyl acetal) resin are provided. Such compositions, layers, and interlayers can exhibit enhanced or optimized properties as compared to non-acetoacetylized poly(vinyl acetal) resins. The acetoacetylized poly(vinyl acetal) resins may be used in a layer or an interlayer for in an architectural application, or the acetoacetylized poly(vinyl acetal) resins may be used in a layer or interlayer, or combined with other layers, to provide an interlayer having good acoustic and other properties.
1. An acetoacetylized polymer comprising units having the structure:
wherein R′ is hydrogen, a substituted or unsubstituted C 1 to C 12 alkyl, a substituted or unsubstituted C 6 to C 14 aryl, a substituted or unsubstituted C 6 to C 14 alkaryl, or a combination thereof, “x” is from about 52 to about 78 mole %, “y” is from about 26 to about 45 mole %, “z” is from about 0 to about 20 mole %, and “a” is present in an amount greater than 0 to 45 mole % such that 0≤y−a≤10 mole % and x+y+z=100; wherein the glass transition temperature of the acetoacetylized polymer is less than the glass transition temperature of the non-acetoacetylized polymer, or wherein the loss factor at the glass transition temperature of the acetoacetylized polymer is less than the loss factor at the glass transition temperature of the non-acetoacetylized polymer, or wherein both the glass transition temperature of the acetoacetylized polymer is less than the glass transition temperature of the non-acetoacetylized polymer and the loss factor at the glass transition temperature of the acetoacetylized polymer is less than the loss factor at the glass transition temperature of the non-acetoacetylized polymer.
2. The acetoacetylized polymer of claim 1 , wherein a is from about 5 to about 40 mole %, z is from about 0 to about 15 mole % and y−a≤8 mole %.
3. The acetoacetylized polymer of claim 1 , further comprising an ultraviolet absorber.
4. The acetoacetylized polymer of claim 1 , further comprising up to 35 wt. % plasticizer.
5. The acetoacetylized polymer of claim 1 , wherein R′ is a substituted or unsubstituted C 1 to C 12 alkyl.
6. The acetoacetylized polymer of claim 1 , wherein R′ is n-propyl or iso-propyl or combinations thereof.
7. The acetoacetylized polymer of claim 1 , wherein the acetoacetylized polymer is made by acetoacetylation of a non-acetoacetylized poly(vinyl acetal) polymer comprising units having the structure:
wherein “x” is from about 52 to about 78 mole %, “y” is from about 26 to about 45 mole %, “z” is from about 0 to about 20 mole %, x+y+z=100 and R′ is a substituted or unsubstituted C 1 to C 12 alkyl, a substituted or unsubstituted C 6 to C 14 aryl, a substituted or unsubstituted C 6 to C 14 alkaryl, or a combination thereof, and wherein the poly(vinyl acetal) polymer has a weight average molecular weight, Mw, of about 120,000 to 170,000 Daltons.
8. The acetoacetylized polymer of claim 1 , wherein the acetoacetylized polymer is prepared by reactive extrusion and the residence time in the extruder is from 3 to 10 minutes.
9. The acetoacetylized polymer of claim 8 , further comprising an organophosphate thermal stabilizer.
10. An interlayer comprising:
an acetoacetylized polymer comprising units having the structure:
wherein R′ is hydrogen, a substituted or unsubstituted C 1 to C 12 alkyl, a substituted or unsubstituted C 6 to C 14 aryl, a substituted or unsubstituted C 6 to C 14 alkaryl, or a combination thereof, “x” is from about 52 to about 78 mole %, “y” is from about 26 to about 45 mole %, “z” is from about 0 to about 20 mole %, and “a” is present in an amount greater than 0 to 45 mole % such that 0≤y−a≤10 mole % and x+y+z=100; wherein the glass transition temperature of the acetoacetylized polymer is less than the glass transition temperature of the non-acetoacetylized polymer, or wherein the loss factor at the glass transition temperature of the acetoacetylized polymer is less than the loss factor at the glass transition temperature of the non-acetoacetylized polymer, or wherein both the glass transition temperature of the acetoacetylized polymer is less than the glass transition temperature of the non-acetoacetylized polymer and the loss factor at the glass transition temperature of the acetoacetylized polymer is less than the loss factor at the glass transition temperature of the non-acetoacetylized polymer.
11. The interlayer of claim 10 , wherein the interlayer further comprises up to 75 phr plasticizer.
12. The interlayer of claim 10 , wherein the interlayer further comprises an ultraviolet absorber, an organophosphate thermal stabilizer or both.