Organic glass laminate coated with inorganic oxide film
An objective of the present invention is to provide an organic glass laminate that exhibits excellent weathering resistance and abrasion resistance, and that can be used as an exterior member. This organic glass laminate comprises at least the following, in order: an organic glass base, a cured layer formed from the cured product of a resin composition, which comprises a curable resin and a UV absorber agent; and an inorganic oxide film. The glass transition temperature of the cured product which constitutes the cured layer is adjusted to 80-160° C., and the thickness of the inorganic oxide film is set to at least 0.01 μm and less than 0.5 μm, whereby weathering resistance and abrasion resistance are significantly improved, and the organic glass laminate is made suitable for use as an exterior member.
1. An organic glass laminate used as an exterior member, the organic glass laminate having at least an organic glass base substrate, a cured layer, and an inorganic oxide film in this order, the cured layer being formed of a cured product of a resin composition containing a curable resin and an ultraviolet absorbent, wherein
the thickness of the organic glass base substrate is 0.8 mm or more,
the cured product has a glass transition point of 80-160° C., and
the inorganic oxide film has a thickness of 0.01 μm or more and less than 0.5 μm.
2. The organic glass laminate according to claim 1 , wherein the curable resin is an ionizing-radiation-curable resin containing (i) a tri-or more functional (meth)acrylate and (ii) a bifunctional (meth)acrylate.
3. The organic glass laminate according to claim 1 , wherein the cured layer contains filler particles at 20-70% by mass.
4. The organic glass laminate according to claim 1 , wherein the cured layer has a thickness of 1-10 μm.
5. The organic glass laminate according to claim 1 , wherein the resin composition contains the ultraviolet absorbent at 0.5-10 parts by mass per 100 parts by mass of a total amount of the ionizing-radiation-curable resin.
6. The organic glass laminate according to claim 1 , further having an adhesive layer and a primer layer in this order, as viewed from the organic glass base substrate side, between the organic glass base substrate and the cured layer, wherein the glass transition point of the primer layer is lower than the glass transition point of the cured product constituting the cured layer.
7. The organic glass laminate according to claim 1 , further having a colored layer that has been partially formed between the organic glass base substrate and the inorganic oxide film.
8. A laminating sheet for producing the organic glass laminate according to claim 1 , wherein, the laminating sheet comprising
at least a cured layer is laminated on a base material film,
the cured layer is formed of a cured product of a resin composition containing a curable resin and an ultraviolet absorbent, and
the cured product has a glass transition point of 80-160° C.
9. The laminating sheet according to claim 8 , wherein the base material film is a release film layer capable of being released from the cured layer, and the laminating sheet transfers the cured layer onto the organic glass base substrate.
10. The laminating sheet according to claim 8 , wherein the base material film is a transparent resin film layer, and the laminating sheet is used by laminating the laminating sheet onto the organic glass base substrate.
11. Use of a laminating sheet for producing the organic glass laminate according to claim 1 , wherein, the laminating sheet comprising
at least a cured layer is laminated on a base material film,
the cured layer is formed of a cured product of a resin composition containing a curable resin and an ultraviolet absorbent, and
the cured product has a glass transition point of 80-160° C.
12. A laminating sheet for producing the organic glass laminate according to claim 1 , wherein, the laminating sheet comprising
at least a cured layer and an inorganic oxide film are laminated on a base material film,
the cured layer is formed of a cured product of a resin composition containing a curable resin and an ultraviolet absorbent,
the cured product has a glass transition point of 80-160° C., and
the inorganic oxide film has a thickness of 0.01 μm or more and less than 0.5 μm.
13. The laminating sheet according to claim 12 , wherein
the base material film is a release film layer capable of being released from the inorganic oxide film,
at least the inorganic oxide film and the cured layer are laminated in this order on the release film layer, and
the laminating sheet is used for transferring the cured layer and the inorganic oxide film onto the organic glass base substrate.
14. The laminating sheet according to claim 12 , wherein
the base material film is a transparent resin film layer,
at least the inorganic oxide film and the cured layer are laminated on the resin film layer, and
the laminating sheet is used by laminating the laminating sheet itself onto the organic glass base substrate.
15. Use of a laminating sheet for producing the organic glass laminate according to claim 1 , wherein, the laminating sheet comprising
at least a cured layer and an inorganic oxide film are laminated on a base material film,
the cured layer is formed of a cured product of a resin composition containing a curable resin and an ultraviolet absorbent,
the cured product has a glass transition point of 80-160° C., and
the inorganic oxide film has a thickness of 0.01 μm or more and less than 0.5 μm.
16. A method of producing an organic glass laminate, comprising:
a step 1 of laminating at least a cured layer onto an organic glass base substrate by using the laminating sheet according to claim 8 ; and
a step 2 of forming an inorganic oxide film having a thickness of 0.01 μm or more and less than 0.5 μm on the cured layer that has been laminated on the organic glass base substrate.
17. A method of producing an organic glass laminate, comprising a step of laminating at least a cured layer and an inorganic oxide film in this order onto an organic glass base substrate by using the laminating sheet according to claim 12 .
18. The organic glass laminate according to claim 2 , wherein the cured layer contains filler particles at 20-70% by mass.
19. The organic glass laminate according to claim 2 , wherein the cured layer has a thickness of 1-10 μm.
20. The organic glass laminate according to claim 3 , wherein the cured layer has a thickness of 1-10 μm.