IP Library Granted Patent US 10,435,537
Granted Patent B2
US 10,435,537 · App. 15/097,660 · Granted Oct 8, 2019

Binder of vegetable origin, compositions comprising same and method for reducing the amount of petroleum-based bitumen

Inventors: Pierre Etienne Bindschedler (Strasbourg, FR); Rémi Perrin (Boersch, FR); Christine Robach (Osthoffen, FR); Marion Kerbrat (Margny les Compiegne, FR); Matthieu Chatillon (Compiegne, FR); Franck Raymond (Linxe, FR)
Assignees: SOPREMA; OLEON SAS
C08K5/103C08K5/105C08K5/13C08L91/00C08L93/00C08L93/04C08L95/00C09D5/002C09D199/00C09K3/12C08L2555/82
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Quick Facts
Patent No.
US 10,435,537
App. No.
15/097,660
Granted
Oct 8, 2019
Kind
B2
Abstract

Disclosed is a binder of vegetable origin based on oil, modified vegetable resin and optionally a heat stabilizer. Also disclosed are leakproofing membrane compositions, soundproofing membrane compositions, liquid sealing system compositions, asphalt mix coating compositions, asphalt coating compositions, primer compositions, varnish compositions, mastic compositions, adhesive compositions or binder emulsion compositions which comprise said binder. In addition, a method is disclosed for reducing the amount of bitumen of petroleum origin in said compositions.

Claims (74)

1. A binder of vegetable origin comprising:

30% to 50% of a plasticizing fraction comprising an oil;

50% to 70% of a structuring fraction comprising a modified vegetable resin;

the % being % by weight relative to the weight of the binder;

in which the modified vegetable resin is a phenolic terpene resin that has a softening point above 120° C. and a residual acidity of less than 50 milligrams of KOH per gram of phenolic terpene resin.

2. A binder according to claim 1 , wherein the plasticizing fraction of the binder further comprises a heat stabilizer selected from phenolic antioxidants, aromatic amines, phosphites, thioesters, epoxidized soybean oil, tall-oil pitch, modified tall-oil pitch, and mixtures thereof.

3. A binder according to claim 1 , wherein the oil of the plasticizing fraction of the binder is an unsaturated polyester oil.

4. A binder according to claim 1 , wherein the modified vegetable resin has a softening point above 130° C.

5. A binder according to claim 1 , wherein the modified vegetable resin has a residual acidity of less than 25 milligrams of KOH per gram of modified vegetable resin.

6. A binder according to claim 1 , wherein said binder has a ring-and-ball temperature of from 30 to 40° C.

7. A binder according to claim 1 , wherein said binder has a needle penetrability at 25° C. of from 170 to 300 tenths of one mm.

8. A leakproofing membrane composition comprising:

the binder of vegetable origin according to claim 1 ;

a polymer;

a filler;

optionally an additive.

9. A method for reducing the amount of bitumen of petroleum origin in a leakproofing membrane composition as described in claim 8 , said method comprising the addition of a binder of vegetable origin to said composition as a replacement for a part or all of the bitumen of petroleum origin, wherein the binder of vegetable origin comprises:

30 to 50% of a plasticizing fraction comprising an oil;

50 to 70% of a structuring fraction comprising a modified vegetable resin;

the % being % by weight relative to the weight of the binder;

in which the modified vegetable resin is a phenolic terpene resin that has a softening point above 120° C. and a residual acidity of less than 50 milligrams of KOH per gram of phenolic terpene resin.

10. A soundproofing membrane composition comprising:

the binder of vegetable origin according to claim 1 ;

a filler;

optionally a polymer;

optionally an additive.

11. A method for reducing the amount of bitumen of petroleum origin in a soundproofing membrane composition as described in claim 10 , said method comprising the addition of a binder of vegetable origin to said composition as a replacement for a part or all of the bitumen of petroleum origin, wherein the binder of vegetable origin comprises:

30 to 50% of a plasticizing fraction comprising an oil;

50 to 70% of a structuring fraction comprising a modified vegetable resin;

the % being % by weight relative to the weight of the binder;

in which the modified vegetable resin is a phenolic terpene resin that has a softening point above 120° C. and a residual acidity of less than 50 milligrams of KOH per gram of phenolic terpene resin.

12. A liquid sealing system composition comprising:

the binder of vegetable origin according to claim 1 ;

a solvent or polymerizable plasticizer;

an additive;

a prepolymer;

optionally a filler.

13. A method for reducing the amount of bitumen of petroleum origin in a liquid sealing system composition as described in claim 12 , said method comprising the addition of a binder of vegetable origin to said composition as a replacement for a part or all of the bitumen of petroleum origin, wherein the binder of vegetable origin comprises:

30 to 50% of a plasticizing fraction comprising an oil;

50 to 70% of a structuring fraction comprising a modified vegetable resin;

the % being % by weight relative to the weight of the binder;

in which the modified vegetable resin is a phenolic terpene resin that has a softening point above 120° C. and a residual acidity of less than 50 milligrams of KOH per gram of phenolic terpene resin.

14. An asphalt mix coating composition or asphalt coating composition comprising:

the binder of vegetable origin according to claim 1 ;

a polymer;

a filler and/or aggregates;

optionally an additive.

15. A method for reducing the amount of bitumen of petroleum origin in an asphalt mix coating composition as described in claim 14 , said method comprising the addition of a binder of vegetable origin to said composition as a replacement for a part or all of the bitumen of petroleum origin, wherein the binder of vegetable origin comprises:

30 to 50% of a plasticizing fraction comprising an oil;

50 to 70% of a structuring fraction comprising a modified vegetable resin;

the % being % by weight relative to the weight of the binder;

in which the modified vegetable resin is a phenolic terpene resin that has a softening point above 120° C. and a residual acidity of less than 50 milligrams of KOH per gram of phenolic terpene resin.

16. A primer, varnish, mastic or adhesive composition comprising:

the binder of vegetable origin according to claim 1 ;

solvent;

an additive;

optionally a polymer;

optionally a filler.

17. A method for reducing the amount of bitumen of petroleum origin in a primer, varnish, mastic, or adhesive composition as described in claim 16 , said method comprising the addition of a binder of vegetable origin to said composition as a replacement for a part or all of the bitumen of petroleum origin, wherein the binder of vegetable origin comprises:

30 to 50% of a plasticizing fraction comprising an oil;

50 to 70% of a structuring fraction comprising a modified vegetable resin;

the % being % by weight relative to the weight of the binder;

in which the modified vegetable resin is a phenolic terpene resin that has a softening point above 120° C. and a residual acidity of less than 50 milligrams of KOH per gram of phenolic terpene resin.

18. A binder emulsion composition comprising:

the binder of vegetable origin according to claim 1 ;

a surfactant;

a polymer;

water;

optionally an additive.

19. A method for reducing the amount of bitumen of petroleum origin in a binder emulsion composition as described in claim 18 , said method comprising the addition of a binder of vegetable origin to said composition as a replacement for a part or all of the bitumen of petroleum origin, wherein the binder of vegetable origin comprises:

30 to 50% of a plasticizing fraction comprising an oil;

50 to 70% of a structuring fraction comprising a modified vegetable resin;

the % being % by weight relative to the weight of the binder;

in which the modified vegetable resin is a phenolic terpene resin that has a softening point above 120° C. and a residual acidity of less than 50 milligrams of KOH per gram of phenolic terpene resin.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 5, 2016
From: KERBRAT, MARION; CHATILLON, MATTHIEU
To: OLEON SAS
Reel/Frame 039076/0580 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 5, 2016
From: BINDSCHEDLER, PIERRE ETIENNE; PERRIN, RÉMI; ROBACH, CHRISTINE; RAYMOND, FRANCK
To: SOPREMA
Reel/Frame 039076/0595 →
Continuity (1)
Related Publication 20160304698A1 · Oct 20, 2016
Cited By (1)
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