Process for the thermal decomposition of ammonia and reactor for carrying out said process
Disclosed is a process for the catalytic thermal decomposition of ammonia into hydrogen and nitrogen by contacting ammonia at a temperature of at least 500° C. with a porous ceramic layer which comprises nickel. Also disclosed is a reactor for carrying out the process.
1. A process for the catalytic thermal decomposition of ammonia into hydrogen and nitrogen, wherein the process comprises contacting ammonia at a temperature of at least 500° C. with a porous ceramic layer which comprises nickel and has a thickness of from 0.1 mm to 1 mm.
2. The process of claim 1 , wherein the porous ceramic layer is present on a metal surface.
3. The process of claim 2 , wherein the porous ceramic layer is present on a metal sheet, a metal plate and/or a metal mesh.
4. The process of claim 2 , wherein the porous ceramic layer has a thickness of from 0.2 mm to 0.5 mm.
5. The process of claim 1 , wherein the porous ceramic layer comprises one or more of alumina, zirconia, titanium dioxide, magnesium oxide, calcium oxide, silica, tungsten carbide, silicon nitride.
6. The process of claim 1 , wherein the porous ceramic layer comprises at least 5% by weight of nickel, calculated as nickel oxide.
7. The process of claim 1 , wherein the nickel in the porous ceramic layer is present in at least partially reduced form.
8. The process of claim 1 , wherein the porous ceramic layer has been formed by thermal spraying starting from a mixture comprising a ceramic material and a combustible pore forming substance.
9. The process of claim 1 , wherein the porous ceramic layer has been formed by thermal spraying starting from a powder of a ceramic material which includes a nickel compound.
10. A process for the catalytic thermal decomposition of ammonia into hydrogen and nitrogen, wherein the process comprises contacting ammonia at a temperature of at least 500° C. with a porous ceramic layer which comprises nickel and has been formed by thermal spraying starting from a mixture comprising a ceramic material and a combustible pore forming substance.
11. The process of claim 10 , wherein the combustible pore forming substance is selected from one or more of graphite, vegetable materials, organic polymers.
12. The process of claim 10 , wherein the mixture further comprises a nickel compound.
13. The process of claim 10 , wherein the porous ceramic layer is present on a metal sheet, a metal plate and/or a metal mesh.
14. The process of claim 10 , wherein the nickel in the porous ceramic layer is present in at least partially reduced form.
15. A process for the catalytic thermal decomposition of ammonia into hydrogen and nitrogen, wherein the process comprises contacting ammonia at a temperature of at least 500° C. with a porous ceramic layer which comprises nickel and has been formed by thermal spraying of a powder of a ceramic material which includes a nickel compound.
16. The process of claim 15 , wherein the nickel compound comprises nickel oxide.
17. The process of claim 15 , wherein the nickel in the porous ceramic layer is present in at least partially reduced form.
18. A reactor for the thermal decomposition of ammonia, wherein the reactor is suitable for carrying out the process of claim 1 and comprises at least one porous ceramic layer which comprises nickel and has a thickness of from 0.1 mm to 1 mm.
19. A reactor for the thermal decomposition of ammonia, wherein the reactor is suitable for carrying out the process of claim 10 and comprises at least one porous ceramic layer which comprises nickel and has been formed by thermal spraying starting from a mixture comprising a ceramic material and a combustible pore forming substance.
20. A reactor for the thermal decomposition of ammonia, wherein the reactor is suitable for carrying out the process of claim 15 and comprises at least one porous ceramic layer which comprises nickel and has been formed by thermal spraying of a powder of a ceramic material which includes a nickel compound.