IP Library › Granted Patent US 10,519,331
Granted Patent B2
US 10,519,331 · App. 15/574,217 · Granted Dec 31, 2019

Ink, inkjet recording method, inkjet recording apparatus, and recorded matter

Inventors: Masahiro Kido (Kanagawa, JP); Hidefumi Nagashima (Kanagawa, JP); Juichi Furukawa (Kanagawa, JP); Yuta Nakamura (Kanagawa, JP)
Assignee: Ricoh Company, Ltd.
C09D11/38C09D11/102C09D11/322B41M5/0011B41M5/0047B41M5/0064
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Quick Facts
Patent No.
US 10,519,331
App. No.
15/574,217
Granted
Dec 31, 2019
Kind
B2
Abstract

Provided is an ink containing water, a plurality of organic solvents, a color material, and resin particles, wherein the plurality of organic solvents contain at least one compound having a hydrogen bond term δH, which is a Hansen solubility parameter, of 4.1 MPa 1/2 or higher but 9.5 MPa 1/2 or lower and a boiling point of 170° C. or higher and at least one diol compound containing 3 or 4 carbon atoms.

Claims (68)

1. An ink, comprising:

water;

a plurality of organic solvents;

a color material; and

resin particles,

wherein the plurality of organic solvents comprise:

a first compound, which has a hydrogen bond term δH, which is a Hansen solubility parameter, of 4.1 MPa 1/2 or higher but 9.5 MPa 1/2 or lower and a boiling point of 170° C. or higher;

a diol compound that comprises 3 or 4 carbon atoms; and

a second compound having an alkoxy group, where the second compound comprises 3-methoxy-3-methyl-1-butanol.

2. The ink according to claim 1 ,

wherein the diol compound comprises at least one selected from the group consisting of 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, and 2,3-butanediol.

3. The ink according to claim 1 ,

wherein a ratio Fh of the first compound is 16% or higher but 25% or lower, wherein the ratio Fh is represented by a mathematical formula 1:

Fh (%)=[δ H /(δ D+δP+δH )]×100  <Mathematical formula 1>

wherein δD represents a dispersion term, which is a Hansen solubility parameter, and δP represents a polarity term, which is a Hansen solubility parameter.

4. The ink according to claim 1 ,

wherein the first compound comprises at least one selected from the group consisting of 3-methoxy-N,N-dimethylpropionamide, 3-butoxy-N,N-dimethylpropionamide, diethylene glycol diethylether, tetramethylurea, 2-pyrrolidone, 1-n-octyl-2-pyrrolidone, and 1,3-dimethyl-2-imidazolidinone.

5. The ink according to claim 1 ,

wherein a content of the first compound is greater than or equal to 10% by mass but less than or equal to 50% by mass of a total content of the plurality of organic solvents.

6. The ink according to claim 1 ,

wherein a boiling point of the plurality of organic solvents is 170° C. or higher but 250° C. or lower.

7. The ink according to claim 1 ,

wherein a total content of the plurality of organic solvents is greater than or equal to 20% by mass but less than or equal to 70% by mass.

8. The ink according to claim 1 ,

wherein the resin particles comprise polyurethane resin particles.

9. An inkjet recording method, comprising:

applying a stimulus to an ink to fly the ink and record an image over a base material,

wherein the ink comprises:

water;

a plurality of organic solvents;

a color material; and

resin particles,

wherein the plurality of organic solvents comprise:

a first compound, which has a hydrogen bond term δH, which is a Hansen solubility parameter, of 4.1 MPa 1/2 or higher but 9.5 MPa 1/2 or lower and a boiling point of 170° C. or higher;

a diol compound that comprises 3 or 4 carbon atoms; and

a second compound having an alkoxy group, where the second compound comprises 3-methoxy-3-methyl-1-butanol.

10. The inkjet recording method according to claim 9 , further comprising:

heating the base material over which the image is recorded.

11. The inkjet recording method according to claim 9 ,

wherein the base material is an impermeable base material that comprises an acrylic resin coating layer.

12. The inkjet recording method according to claim 9 ,

wherein the base material is a polyvinyl chloride film or a polyethylene terephthalate film.

13. An inkjet recording apparatus, comprising

an ink flying unit configured to apply a stimulus to an ink to fly the ink and record an image over a base material,

wherein the ink comprises:

water;

a plurality of organic solvents;

a color material; and

resin particles,

wherein the plurality of organic solvents comprise:

a first compound, which has a hydrogen bond term δH, which is a Hansen solubility parameter, of 4.1 MPa 1/2 or higher but 9.5 MPa 1/2 or lower and a boiling point of 170° C. or higher;

a diol compound that comprises 3 or 4 carbon atoms; and

a second compound having an alkoxy group, where the second compound comprises 3-methoxy-3-methyl-1-butanol.

14. The inkjet recording apparatus according to claim 13 , further comprising:

a heating unit configured to heat the base material over which the image is recorded.

15. The inkjet recording apparatus according to claim 13 ,

wherein the base material is an impermeable base material that comprises an acrylic resin coating layer.

16. The inkjet recording apparatus according to claim 13 ,

wherein the base material is a polyvinyl chloride film or a polyethylene terephthalate film.

17. A recorded matter, comprising:

a base material; and

an image recorded over the base material with the ink according to claim 1 .

18. The ink according to claim 1 , wherein a content of the second compound is greater than or equal to 1% by mass but less than or equal to 10% by mass of a total content of the plurality of organic solvents.

19. The ink according to claim 1 , wherein a content of the second compound is greater than or equal to 2% by mass but less than or equal to 6% by mass of a total content of the plurality of organic solvents.

20. The ink according to claim 1 ,

wherein a content of the first compound is greater than or equal to 10% by mass but less than or equal to 50% by mass of a total content of the plurality of organic solvents,

a content of the diol compound is greater than or equal to 5% by mass but less than or equal to 40% by mass of the total content of the plurality of organic solvents, and

a content of the second compound is greater than or equal to 1% by mass but less than or equal to 10% by mass of the total content of the plurality of organic solvents.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 15, 2017
From: KIDO, MASAHIRO; NAGASHIMA, HIDEFUMI; FURUKAWA, JUICHI; NAKAMURA, YUTA
To: RICOH COMPANY, LTD.
Reel/Frame 044455/0330 →
Priority Claims (2)
JP 2015-117636 · Jun 10, 2015 · national
JP 2016-006579 · Jan 15, 2016 · national
Continuity (1)
Related Publication 20180127610A1 · May 10, 2018