Graphite power for negative electrode active material of lithium-ion secondary battery
A graphite powder, preferably including scale-like particles, which satisfies the following formulae (1) and (2), wherein e(0.5) represents the initial charge-discharge efficiency of a coin cell fabricated from an electrode (work electrode) produced by compressing an electrode material employing graphite powder as an active material under a pressure of 0.5 t/cm 2 , a lithium metal counter electrode, a separator and an electrolytic solution; and e(3) represents the initial charge-discharge efficiency of a coin cell fabricated from an electrode (work electrode) produced by compressing an electrode material employing graphite powder as an active material under a pressure of 3 t/cm 2 , a lithium metal counter electrode, a separator and an electrolytic solution: e (3)(%)− e (0.5)(%)≥1, formula (1): e (3)(%)>85. formula (2): Also disclosed is a method of producing the graphite powder; a graphite material for a battery electrode; an electrode for a lithium ion; and a lithium-ion secondary battery.
1. A negative electrode material for a battery electrode comprising a graphite powder,
wherein a total pore volume as determined by nitrogen gas adsorption method of the graphite powder is 8.0 μl/g to 20.0 μl/g, the particles of the graphite powder are scale-like particles, and a peak ratio (x) of a rhombohedral structure in the graphite powder obtained by the expression x=P2/(P1+P2) is 0.05 or less,
wherein P1 is an actually measured peak strength of a hexagonal structure (100) plane measured by powder X-ray diffraction, and P2 is an actually measured peak strength of a rhombohedral structure (101) plane by powder X-ray diffraction.
2. The negative electrode material for a battery electrode as claimed in claim 1 , further comprising a metallic substance.
3. The negative electrode material for a battery electrode as claimed in claim 2 , wherein the metallic substance comprises a metal that is capable of forming an alloy with an alkali metal and/or a metallic substance comprising an alkali metal alloy.
4. A negative electrode for a lithium battery, comprising a current collector and a negative electrode active material layer formed on the current collector, wherein the negative electrode active material layer comprises a binder and the negative electrode material for a battery electrode as claimed in claim 1 .
5. The negative electrode for a lithium battery as claimed in claim 4 , wherein the negative electrode material for a battery electrode further comprises a metallic substance.
6. The negative electrode for a lithium battery as claimed in claim 4 , wherein the negative electrode active material layer is a compressed layer.
7. The negative electrode for a lithium battery as claimed in claim 5 , wherein the negative electrode active material layer is a compressed layer.
8. A lithium ion battery comprising the negative electrode for a lithium battery as claimed in claim 4 .
9. The lithium ion battery as claimed in claim 8 , wherein the negative electrode material for a battery electrode further comprises a metallic substance.
10. The lithium ion battery as claimed in claim 8 , wherein the negative electrode active material layer is a compressed layer.
11. The lithium ion battery as claimed in claim 9 , wherein the negative electrode active material layer is a compressed layer.