IP Library Granted Patent US 10,642,178
Granted Patent B2
US 10,642,178 · App. 16/377,591 · Granted May 5, 2020

Toner

Inventors: Daisuke Yamashita (Tokyo, JP); Yuichi Mizo (Toride, JP); Koh Ishigami (Abiko, JP); Masaharu Miura (Toride, JP); Takaho Shibata (Tokyo, JP); Takeshi Ohtsu (Toride, JP); Yosuke Iwasaki (Abiko, JP); Wakiko Katsumata (Kashiwa, JP); Hitoshi Sano (Matsudo, JP); Kenta Mitsuiki (Toride, JP); Takakuni Kobori (Toride, JP); Rei Hijikawa (Kashiwa, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/08755C08G63/16C08G63/183
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Quick Facts
Patent No.
US 10,642,178
App. No.
16/377,591
Granted
May 5, 2020
Kind
B2
Abstract

A toner comprising a toner particle including a binder resin and a crystalline polyester resin, wherein the binder resin is an amorphous polyester resin having a linear alkyl group at a molecular chain terminal; the crystalline polyester resin is a polycondensate of a diol and a dicarboxylic acid; the number of carbon atoms C aPES of the linear alkyl group, the number of carbon atoms C OH of the diol, and the number of carbon atoms C Ac of the dicarboxylic acid, excluding carbon that belongs to carboxyl groups, satisfy the following relationships; and a glass transition temperature of the toner as measured by a differential scanning calorimeter is from 40.0° C. to 55.0° C. 8≤C aPES ≤20  (1) C Ac /C OH ≥3.5 and 0≤|C Ac −C aPES |≤3  (2) C OH /C Ac ≥3.5 and 0≤|C OH −C aPES |≤3  (3)

Claims (20)

1. A toner comprising a toner particle including a binder resin and a crystalline polyester resin, wherein

the binder resin is an amorphous polyester resin having a linear alkyl group at a molecular chain terminal,

the crystalline polyester resin is a polycondensate of a diol and a dicarboxylic acid,

where the number of carbon atoms of the linear alkyl group is denoted by C aPES , the number of carbon atoms of the diol is denoted by C OH , and the number of carbon atoms of the dicarboxylic acid, excluding carbon that belongs to carboxyl groups, is denoted by C Ac ,

the C aPES , the C OH , and the C Ac satisfy the following relationships (1), and (2) or (3), and

a glass transition temperature of the toner as measured by a differential scanning calorimeter is from 40.0° C. to 55.0° C.

8≤C aPES ≤20  (1)

C Ac /C OH ≥3.5 and 0≤|C Ac −C aPES |≤3  (2)

C OH /C Ac ≥3.5 and 0≤|C OH −C aPES |≤3.  (3)

2. The toner according to claim 1 , wherein the molecular chain terminal is a group formed by detachment of a hydrogen atom of a hydroxyl group of a linear alkyl monoalcohol or a group formed by detachment of a hydrogen atom of a carboxyl group of a linear alkyl monocarboxylic acid, and

the linear alkyl group is an alkyl group included in the group formed by detachment of a hydrogen atom of a hydroxyl group of a linear alkyl monoalcohol or the group formed by detachment of a hydrogen atom of a carboxyl group of a linear alkyl monocarboxylic acid.

3. The toner according to claim 1 , wherein

where a solubility parameter of the amorphous polyester resin is denoted by SP aPES (cal/cm 3 ) 1/2 , and a solubility parameter of the crystalline polyester resin is denoted by SP cPES (cal/cm 3 ) 1/2 ,

the SP aPES and the SP cPES satisfy the following relationship (4), and

a melting point of the crystalline polyester resin is from 75° C. to 100° C.

1.00 (cal/cm 3 ) 1/2 ≤(SP aPES −SP cPES )≤1.50 (cal/cm 3 ) 1/2 .  (4)

4. The toner according to claim 1 , wherein the C aPES , the C OH , and the C Ac satisfy the following relationships (1), and (2)′ or (3)′

8≤C aPES ≤20  (1)

C Ac /C OH ≥3.5 and C Ac =C aPES   (2)′

C OH /C Ac ≥3.5 and C OH =C aPES .  (3)′

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 27, 2019
From: YAMASHITA, DAISUKE; MIZO, YUICHI; ISHIGAMI, KOH; MIURA, MASAHARU; SHIBATA, TAKAHO; OHTSU, TAKESHI; IWASAKI, YOSUKE; KATSUMATA, WAKIKO; SANO, HITOSHI; MITSUIKI, KENTA; KOBORI, TAKAKUNI; HIJIKAWA, REI
To: CANON KABUSHIKI KAISHA
Reel/Frame 050835/0574 →
Priority Claims (1)
JP 2018-088149 · May 1, 2018 · national
Continuity (1)
Related Publication 20190339629A1 · Nov 7, 2019
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