Retardation film and utilization thereof
The retardation film according to the present invention is characterized by: including a polymer material that includes at least one cellulose derivative which includes specific monomer units: having an in-plane retardation Re(550) of 105-160 nm, reverse wavelength dispersion property, Re(450)/Re(550), of 0.80-0.89, and a thickness of 20-50 μm; and containing inorganic particles. In particular, the present invention exhibits the effect of reducing the photoelastic coefficient.
1. A retardation film, comprising:
a polymer material including at least one cellulose derivative having a monomeric unit of formula (1),
where R 1 , R 2 , and R 3 in the formula (1) are each independently hydrogen, an aliphatic alkyl group or an aromatic acyl group; and
a plurality of inorganic particles,
wherein the retardation film has an in-plane retardation Re(550) of 105 nm to 160 nm, a reverse wavelength dispersion property Re(450)/Re(550) of 0.80 to 0.89, and a thickness of 20 μm to 50 μm,
the cellulose derivative has a total degree of substitution D1 of 2.00 to 210 for substitution by an aliphatic alkyl group, and a degree of substitution D2 of 0.30 to 1.00 for substitution by an aromatic acyl group, satisfying D1+D2≤3.0 in the cellulose derivative, and
the polymer material has a total degree of substitution D3 of 0.40 to 0.50 for substitution by an aromatic acyl group in the polymer material.
2. The retardation film of claim 1 , wherein at least one of R 1 , R 2 , and R 3 in the formula (1) is an aromatic acyl group.
3. The retardation film of claim 1 , wherein the retardation film has a photoelastic coefficient of less than 42.0×10 −12 m 2 /N.
4. The retardation film of claim 1 , wherein the inorganic particles comprise an inorganic material having an unsaturated bond.
5. The retardation film of claim 1 , wherein the inorganic particles comprise an inorganic material having an acryloyl group.
6. The retardation film of claim 1 , wherein the inorganic particles are included in an amount of from 5 parts by weight to 40 parts by weight with respect to 100 parts by weight of the cellulose derivative.
7. The retardation film of claim 1 , wherein the inorganic particles comprise silica particles.
8. The retardation film of claim 1 , wherein the inorganic particles have an average particle diameter of 5 nm to 30 nm.
9. The retardation film of claim 1 , wherein the inorganic particles are spherical particles.
10. The retardation film of claim 1 , wherein the aliphatic alkyl group is an ethyl group.
11. The retardation film of claim 1 , wherein the at least one cellulose derivative comprises a plurality of cellulose derivatives.
12. The retardation film of claim 11 , wherein each of the cellulose derivatives has the total degree of substitution D 1 of 2.00 to 2.70 for substitution by an aliphatic alkyl group, and the degree of substitution D 2 of 0.30 to 1.00 for substitution by an aromatic acyl group, satisfying D 1 +D 2 ≤3.0 in each of the cellulose derivatives.
13. The retardation film of claim 11 , wherein each of the cellulose derivatives has the total degree of substitution D 1 of 2.30 to 2.60 for substitution by an aliphatic alkyl group, and the degree of substitution D 2 of 0.35 to 0.70 for substitution by an aromatic acyl group, satisfying D 1 +D 2 ≤3.0 in each of the cellulose derivatives, and the polymer material has the total degree of substitution D 3 of 0.44 to 0.48 for substitution by an aromatic group in the polymer material.
14. A circular polarizer plate, comprising:
one or more of the retardation film of claim 1 .
15. An image display device, comprising:
the circular polarizer plate of claim 14 .
16. A method of manufacturing the retardation film of claim 1 , comprising:
drawing a production film comprising the polymer material at a draw ratio of 20% to 200%.
17. The method of claim 16 , wherein the drawing is conducted at a temperature in a range of from (Tg−30) ° C. to (Tg+30) ° C., where Tg is a glass transition temperature of the production film.
18. The retardation film of claim 1 , wherein at least one of R 1 , R 2 , and R 3 is an aliphatic alkyl group, and at least one of the other two of R 1 , R 2 , and R 3 is an aromatic acyl group.
19. The retardation film of claim 1 , wherein at least one of R 1 , R 2 , and R 3 in the formula (1) is an aromatic acyl group, which is a substituted or unsubstituted naphthoyl group, a substituted or unsubstituted phenanthrene carbonyl group, or a substituted or unsubstituted anthracene carbonyl group.
20. The retardation film of claim 19 , wherein at least one of R 1 , R 2 , and R 3 in the formula (1) is an aliphatic alkyl group, which is an ethyl group.