Fluorinated ionic liquids for battery electrolytes
View Patent ↗An ionic liquid comprising a cationic chemical species and an anionic chemical species. The cationic chemical species comprising a nitrogen containing moiety and a partially fluorinated alkyl chain moiety, wherein the partially fluorinated alkyl chain moiety is bonded to a nitrogen atom of the nitrogen containing moiety. The ionic liquid can be used as an electrolyte, as an additive to an organic solvent, as a lubricant, as a hydrophobic coating, as a treatment for fluorinated pollutants, as an electrolyte for sensor applications, as a stabilizing additive for existing battery electrolytes, and as an emulsifier.
1. A metal-air battery comprising:
a porous cathode current collector with an air interface;
an electrolyte comprising an ionic liquid and optionally an organic solvent disposed in pores of the porous cathode current collector, the ionic liquid comprising:
a cationic chemical species comprising:
a nitrogen containing moiety and
a partially fluorinated alkyl chain moiety; and
an anionic chemical species,
wherein a first carbon atom of the partially fluorinated alkyl chain moiety is non-fluorinated and bonded to a nitrogen atom of the nitrogen containing moiety, wherein a second carbon atom of the partially fluorinated alkyl chain moiety is non-fluorinated and bonded to the first carbon atom, wherein the partially fluorinated alkyl chain moiety contains a number of carbon atoms ranging from 3 to 26;
wherein the ratio of carbon atoms to fluorine atoms in the partially fluorinated alkyl chain ranges from 1:1 to 0.53:1
a metal anode; and
a separator in contact with the electrolyte and bonded between the porous cathode current collector and the metal anode.
2. The metal-air battery of claim 1 , wherein the nitrogen containing moiety is selected from the group comprising: trimethylamine, triethylamine, tributylamine, butyl diethyl amine, pyrazole, thiazole, isothiazole, imidazole, indoline, quinoline, isoquinoline, pyrrolidine, piperidine, azocane, piperazine, morpholine, thiomorpholine, pyridine, and derivatives thereof.
3. The metal-air battery of claim 1 , wherein the partially fluorinated alkyl chain moiety contains a number of carbon atoms ranging from 5 to 26.
4. The metal-air battery of claim 1 , wherein the partially fluorinated alkyl chain moiety contains a number of fluorine atoms ranging from 4 to 49.
5. The metal-air battery of claim 1 , wherein the anionic chemical species is selected from the group comprising: tetrafluoroborate, tetrachloroaluminate, trifluoromethanesulfonate, bis(trifluoromethanesulfonyl)imide, bis(oxalate)borate, bis(perfluoroethylsulfonyl)imide, perchlorate, hexafluorophosphate, sulfate, phosphate, chloride, bromide, or iodide.
6. The metal-air battery of claim 1 , wherein the nitrogen containing moiety is a pyrrolidine ring, where a nitrogen atom of the pyrrolidine ring is bonded to an alkyl chain or a functionalized alkyl chain, and the nitrogen atom of the pyrrolidine ring is further bonded to the partially fluorinated alkyl chain moiety.
7. The metal-air battery of claim 1 , wherein the dynamic (shear) viscosity of the ionic liquid ranges from 10 to 200 cP.