Rubber composition comprising a styrene-butadiene copolymer having a low glass transition temperature, and a high content of filler and of plasticizer
View Patent ↗A rubber composition is based on at least 80 phr (parts by weight per hundred parts by weight of elastomer) of a styrene/butadiene elastomer (SBR) referred to as low-Tg SBR, the glass transition temperature (Tg) of which is less than −60° C.; at least 130 phr of reinforcing filler; at least 110 phr in total of a plasticizing system comprising a hydrocarbon-based resin at a content within a range extending from 70 to 100 phr and a plasticizing oil at a content within a range extending from 10 to 40 phr; and a vulcanization system.
1. A rubber composition based on:
100 phr (parts by weight per hundred parts by weight of elastomer) of a low-Tg styrene/butadiene elastomer, the glass transition temperature Tg of which is less than −60° C.;
145 to 155 phr of reinforcing filler;
115 to 130 phr in total of a plasticizing system comprising a hydrocarbon-based resin at a content within a range extending from 85 to 90 phr and a plasticizing oil at a content within a range extending from 20 to 30 phr; and
a vulcanization system;
wherein the reinforcing filler comprises at least 130 phr of silica and 1 to 5 phr of carbon black.
2. The rubber composition according to claim 1 , wherein said low-Tg styrene/butadiene elastomer has a styrene content within a range extending from 3 to 40% by weight.
3. The rubber composition according to claim 1 , wherein said low-Tg styrene/butadiene elastomer has a butadiene fraction having a content of 1,2-vinyl bonds of between 4% and 30% (mol %).
4. The rubber composition according to claim 1 , wherein said low-Tg styrene/butadiene elastomer is functionalized by a function selected from the group consisting of functional groups comprising a carbon-tin bond, amino functional groups, functional groups comprising a silanol, functional groups comprising an alkoxysilane, carboxyl groups, polyether groups, epoxide groups and mixtures thereof.
5. The rubber composition according to claim 1 , wherein the hydrocarbon-based resin has a Tg of greater than 0° C.
6. The rubber composition according to claim 5 , wherein the hydrocarbon-based resin has a Tg of greater than 30° C.
7. The rubber composition according to claim 1 , wherein the hydrocarbon-based resin has a number-average molecular weight of between 400 and 2000 g/mol.
8. The rubber composition according to claim 1 , wherein the hydrocarbon-based resin has a polydispersity index PI of less than 3.
9. The rubber composition according to claim 1 , wherein the plasticizing oil is selected from the group consisting of naphthenic oils, paraffinic oils, medium extracted solvates oils, treated distillate aromatic extracts oils, mineral oils, vegetable oils, ether plasticizers, ester plasticizers, phosphate plasticizers, sulfonate plasticizers and mixtures thereof.
10. A tire comprising the rubber composition according to claim 1 .
11. The tire according to claim 10 , wherein the rubber composition comprises all or part of the tread.