Method for manufacturing fuel cell stack
The manufacturing method of the present invention is to manufacture a fuel cell stack by heating a stack of fuel cell single cells each of which includes organic substance-containing inorganic sealing members, a separator, an anode electrode, an electrolyte and a cathode electrode. The organic substance in the organic substance-containing inorganic sealing members is removed by heating the stack while supplying an oxygen-containing gas to fuel channels on the anode electrode side and externally applying an electric current so as to migrate charges from the anode electrode to the cathode electrode.
1. A method for manufacturing a solid oxide fuel cell stack by heating a stack of fuel cell single cells, each of the fuel cell single cells comprising organic substance-containing inorganic sealing members, a separator, an anode electrode, an electrolyte and a cathode electrode,
the method comprising an organic substance removing step of removing an organic substance in the organic substance-containing inorganic sealing members,
the organic substance removing step comprises heating the stack while positively supplying a supply of an oxygen-containing gas to fuel channels on the anode electrode side to remove the organic substance from the inorganic sealing members and externally applying an electric current to migrate charges from the anode electrode to the cathode electrode.
2. The method for manufacturing the fuel cell stack according to claim 1 , further comprising applying the electric current at a temperature of equal to or greater than an oxidation onset temperature of the anode electrode that comprises a plurality of anode electrodes,
wherein the current starts to be applied at the oxidation onset temperature of the plurality of anode electrodes.
3. The method for manufacturing the fuel cell stack according to claim 1 , further comprising controlling an amount of the electric current based on a temperature of a plurality of anode electrodes,
wherein the amount of the electric current is increased with an increase of the temperature of the plurality of anode electrodes.
4. The method for manufacturing the fuel cell stack according to claim 2 , further comprising controlling an amount of the electric current based on a temperature of the plurality of anode electrodes,
wherein the amount of the electric current is increased with an increase of the temperature of the plurality of anode electrodes.
5. The method for manufacturing the fuel cell stack according to claim 2 , wherein the organic substance removing step comprises maintaining a temperature of equal to or greater than an oxidation onset temperature of the organic substance that is higher than the oxidation onset temperature of the plurality of anode electrodes for a predetermined period of time so as to remove the organic substance.
6. The method for manufacturing the fuel cell stack according to claim 1 , wherein the oxygen-containing gas is supplied to the fuel channels on the anode electrode side at a temperature of equal to or greater than an oxidation onset temperature of the organic substance.
7. The method for manufacturing the fuel cell stack according to claim 1 , further comprising a sintering step after the organic substance removing step,
wherein the sintering step comprises cutting off supply of the oxygen-containing gas to the fuel channels on the anode electrode side and increasing a temperature relative to a temperature in the organic substance removing step.
8. The method for manufacturing the fuel cell stack according to claim 7 , wherein the sintering step comprises supplying a reducing gas to the fuel channels on the anode electrode side and cutting off application of the electric current.
9. The method for manufacturing the fuel cell stack according to claim 1 , further comprising an electrode forming step before the organic substance removing step,
wherein the electrode forming step comprises maintaining a temperature at a temperature of less than an oxidation onset temperature of the organic substance for a predetermined period of time.
10. The method for manufacturing the fuel cell stack according to claim 1 ,
wherein the anode electrode contains a metal catalyst made of a metal and/or an alloy.
11. The method for manufacturing the fuel cell stack according to claim 1 ,
wherein each of the fuel cell single cells comprises a metal-supported cell comprising a metal support layer, and
the metal support layer supports the anode electrode, the electrolyte and the cathode electrode from a side of the anode electrode.