Rubber composition and tire
Provided is a rubber composition that allows for manufacturing a tread rubber that is high in braking performance on a dry surface road and also high in braking performance even on a wet road surface such as a manhole surface that is slipperier than an asphalt road surface. The rubber composition is prepared by compounding a rubber component (A) including a natural rubber by 70 mass % or more, and by further compounding, with the rubber component as 100 parts by mass: (B) at least one kind of thermoplastic resins selected from among C 5 -based resins, C 5 - to C 9 -based resins, C 9 -based resins, terpene-based resins, terpene-aromatic compound-based resins, rosin-based resins, dicyclopentadiene resins, and alkylphenol-based resins, at 5 parts by mass to 50 parts by mass; and (C) a filler including silica, at 20 parts by mass to 120 parts by mass, in which the filler (C) contains silica by 50 mass % to 100 mass %.
1. A rubber composition prepared by compounding a rubber component (A) comprising a natural rubber by 70 mass % or more, and by further compounding, with the rubber component as 100 parts by mass: (B) at least one kind of thermoplastic resins selected from among C 5 -based resins, C 5 - to C 9 -based resins, C 9 -based resins, terpene-based resins, terpene-aromatic compound-based resins, rosin-based resins, dicyclopentadiene resins, and alkylphenol-based resins, at 5 parts by mass to 50 parts by mass; and (C) a filler including silica and carbon black, at 20 parts by mass to 120 parts by mass,
wherein a ratio of silica in the filler (C) is 90 mass % or more and less than 100 mass % and a ratio of carbon black in the filler (C) is more than 0 mass % and 10 mass % or less.
2. The rubber composition according to claim 1 , wherein the rubber component (A) comprises a styrene-butadiene copolymer rubber by 10 mass % to 30 mass %.
3. A tire using the rubber composition according to claim 1 , as a tread rubber.
4. The rubber composition according to claim 1 , prepared by further compounding a naphthene oil at 10 parts by mass or less with the rubber component (A) as 100 parts by mass.
5. The rubber composition according to claim 1 , wherein the rubber component (A) comprises a natural rubber by 80 mass% or more.
6. The rubber composition according to claim 1 , wherein the rubber component (A) further comprises a rubber material selected from the group consisting of butadiene rubber, acrylonitrile-butadiene copolymer rubber, chloroprene rubber, and polyisoprene rubber.
7. The rubber composition according to claim 1 , wherein the at least one kind of thermoplastic resins is C 5 -based resins comprising a copolymer including, as main components, isoprene, cyclopentadiene, 1,3-pentadiene, and 1 -pentene; a copolymer of 2-pentene and dicyclopentadiene; and a polymer mainly composed of 1,3-pentadiene.
8. The rubber composition according to claim 1 , wherein the at least one kind of thermoplastic resins is C 5 - to C 9 -based resins comprising a copolymer including, as main components, styrene, vinyltoluene, a-methylstyrene, and indene.
9. The rubber composition according to claim 1 , wherein the at least one kind of thermoplastic resins is C 9 -based resins comprising a copolymer including, as main components, indene, a-methylstyrene, and vinyltoluene.
10. The rubber composition according to claim 1 , wherein the at least one kind of thermoplastic resins is terpene-based resins comprising ⊖-pinene resins; and α-pinene resins.
11. The rubber composition according to claim 1 , wherein the at least one kind of thermoplastic resins is terpene-aromatic compound-based resins comprising terpene-phenol resins.
12. The rubber composition according to claim 1 , wherein the at least one kind of thermoplastic resins is rosin-based resins comprising as a natural resin rosin: a gum rosin, a tall oil rosin, and a wood rosin, which are included in a raw rosin or a tall oil; and also include, as a modified rosin, a rosin derivative, and a modified rosin derivative, for example: a polymeric rosin and its partially hydrogenated rosin; a glycerin ester rosin and its partially hydrogenated rosin or completely hydrogenated rosin; and a pentaerythritol ester rosin and its partially hydrogenated rosin or polymeric rosin.
13. The rubber composition according to claim 1 , wherein the at least one kind of thermoplastic resins is dicyclopentadiene resins comprising resins obtained by polymerizing dicyclopentadiene using a catalyst for the Friedel-Crafts reaction selected from the group consisting of AlCl 3 and BF 3 .