Aqueous redox flow batteries comprising metal ligand coordination compounds

1. A flow battery comprising:

a first aqueous electrolyte comprising a first redox active material;

a second aqueous electrolyte comprising a second redox active material;

wherein the first and second redox active materials comprise a different metal or metalloid;

a first electrode in contact with said first aqueous electrolyte;

a second electrode in contact with said second aqueous electrolyte and

a separator disposed between said first aqueous electrolyte and said second aqueous electrolyte;

wherein the first or second redox active material, or both the first and second redox active materials comprise a metal ligand coordination compound having a formula comprising M(L1) x (L2) y (L3) z m , where M is independently a non-zero valent metal or metalloid of Groups 2-16, including lanthanides and actinides,

wherein x, y, and z are independently 0, 1, 2, or 3, wherein x, y, and z are selected from the group consisting of (a) x=3, y=z=0; (b) x=2, y=1, z=0; (c) x=1, y=1, z=1;

m is independently −5, −4, −3, −2, −1, 0, 1, 2, 3, 4, or 5; and

L1, L2, and L3 are each independently ascorbate, citrate, a glycolate, gluconate, glycinate, α-hydroxyalkanoate, β-hydroxyalkanoate, γ-hydroxyalkanoate, malate, maleate, phthalate, a polyol, sarcosinate, salicylate, lactate, or a compound having structure according to Formula I, or an oxidized or reduced form thereof:

wherein

Ar is a 5-20 membered aromatic moiety, optionally comprising one of more O, N, or S heteroatoms;

X 1 and X 2 are independently —OH, —NHR′, —SH, or an anion thereof, X 1 and X 2 being positioned ortho to one another;

R 1 is independently at each occurrence H, C 1-6 alkoxy, C 1-6 alkyl, C 1-6 alkenyl, C 1-6 alkynyl, 5-6 membered aryl or heteroaryl, a boric acid or a salt thereof, carboxy acid or a salt thereof, C 2-6 carboxylate, cyano, halo, hydroxyl, nitro, sulfonate, sulfonic acid or a salt thereof, phosphonate, phosphonic acid or a salt thereof, or a polyglycol;

R′ is independently H or C 1-3 alkyl; and

n is 0, 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10.

2. The flow battery of claim 1 , wherein both the first and second redox active materials comprise a metal ligand coordination compound.

3. The flow battery of claim 1 , wherein the first, the second, or both the first and second metal-ligand coordination compound comprises at least one ligand having a structure according to Formula I.

4. The flow battery of claim 1 , wherein the first, the second, or both of the redox-active metal ligand coordination compounds comprises at least one ligand having a structure according to Formula IA, IB, or IC:

wherein

X 1 and X 2 are independently —OH, —NHR′, —SH, or an anion thereof;

R 1 is independently at each occurrence H, C 1-6 alkoxy, C 1-6 alkyl, a boric acid or a salt thereof, carboxy acid or a salt thereof, C 2-6 carboxylate, cyano, halo, hydroxyl, nitro, sulfonate, sulfonic acid or a salt thereof, phosphonate, phosphonic acid or a salt thereof, or a polyglycol;

R′ is independently H or C 1-3 alkyl; and

n is 0-4.

5. The flow battery of claim 4 , wherein

X 1 and X 2 are both OH or an anion thereof;

R 1 is independently H, C 1-3 alkoxy, C 1-3 alkyl, a boric acid or a salt thereof, carboxy acid or a salt thereof, C 2-6 carboxylate, cyano, halo, hydroxyl, nitro, sulfonate, sulfonic acid or a salt thereof, phosphonate, phosphonic acid or a salt thereof, or a polyglycol; and

n is 1.

6. The flow battery of claim 1 , where the first, the second, or both of the redox-active metal ligand coordination compounds comprises at least one ligand of Formula I, IA, IB, or IC.

7. The flow battery of claim 6 , where the at least one ligand of Formula I, IA, IB, or IC is a catechol or pyrogallol ligand.

8. The flow battery of claim 1 , wherein either the first or the second or both the first and second metal-ligand coordination compound comprises Al, Ca, Ce, Co, Cr, Fe, Mg, Mn, Mo, Si, Sn, Ti, W, Zn, or Zr.

9. The flow battery of claim 1 , wherein one of the first or the second metal-ligand coordination compound comprises the metal ligand coordination compound having the formula comprising M(L1) x (L2) y (L3) z m , and the other comprises a cyano compound of chromium, iron, manganese, molybdenum, or ruthenium.

10. The flow battery of claim 9 , wherein the metal-ligand coordination compound is a chromium, iron, or manganese hexacyanide compound.

11. The flow battery of claim 10 , wherein the metal-ligand coordination compound is an iron hexacyanide compound.

12. The flow battery of claim 9 , wherein either or both of the first or the second metal-ligand coordination compound are present in the first or second electrolyte, respectively, at a concentration in a range of from 0.5 to 1 M.

13. The flow battery of claim 1 , wherein the first and second metal-ligand coordination compounds each exhibits substantially reversible electrochemical kinetics.

14. The flow battery of claim 1 , wherein the separator has a thickness of about 100 micron or less.

15. A system comprising a flow battery of claim 1 , and further comprising:

(a) a first chamber containing the first aqueous electrolyte and a second chamber containing the second aqueous electrolyte;

(b) at least one electrolyte circulation loop in fluidic communication each electrolyte chamber, said at least one electrolyte circulation loop comprising storage tanks and piping for containing and transporting the electrolytes;

(c) control hardware and software; and

(d) an optional power conditioning unit.

16. The system of claim 15 , wherein the system is connected to an electrical grid.