Biodegradable aliphatic polyester fiber and method for producing the same
An objective is to improve the spinnability and the productivity and increase the tensile strength of a polyester fiber containing polyhydroxyalkanoate. Disclosed is a biodegradable aliphatic polyester fiber containing a polyhydroxyalkanoate, a nucleating agent, and a lubricant, wherein the nucleating agent contains pentaerythritol, and the lubricant contains at least one of behenic amide, stearic acid amide, erucamide, oleic amide, and a combination thereof.
1. A method for producing a biodegradable aliphatic polyester fiber, comprising:
spin-drawing a fiber from a spinning die at a temperature of from 130° C. to 190° C.; and subsequently
taking up the fiber by a first take-up roll at a take-up speed of from 300 m/min to 4,000 m/min, and continuously taking up by a second take-up roll at a take-up speed of from 600 m/min to 7,000 m/min,
wherein
the fiber comprises a polyhydroxyalkanoate, a nucleating agent, and a lubricant,
the nucleating agent comprises pentaerythritol, and
the lubricant comprises at least one selected from the group consisting of behenic amide, stearic acid amide, erucamide, and oleic amide.
2. The method of claim 1 , wherein a content of the nucleating agent in the fiber is from 0.05 parts by weight to 12 parts by weight relative to 100 parts by weight of the polyhydroxyalkanoate.
3. The method of claim 1 , wherein a content of the lubricant in the fiber is more than 0.5 parts by weight to 10 parts by weight relative to 100 parts by weight of the polyhydroxyalkanoate.
4. The method of claim 1 , wherein the lubricant is erucamide.
5. The method of claim 1 , wherein the polyhydroxyalkanoate comprises a repeating unit of the formula (1):
[—CHR—CH 2 —CO—O—] (1),
wherein R is an alkyl group represented by C n H 2n+1 and n is an integer of 1 or more and 15 or less.
6. The method of claim 1 , wherein the polyhydroxyalkanoate is at least one selected from the group consisting of poly(3-hydroxybutyric acid), poly(3-hydroxybutyric acid-co-3-hydroxyvaleric acid), poly(3-hydroxybutyric acid-co-3-hydroxyvaleric acid-co-3-hydroxyhexanoic acid), poly(3-hydroxybutyric acid-co-3-hydroxyhexanoic acid), and poly(3-hydroxybutyric acid-co-4-hydroxybutyric acid).
7. The method of claim 1 , wherein the polyhydroxyalkanoate is poly(3-hydroxybutyric acid-co-3-hydroxyhexanoic acid).
8. The method of claim 7 , wherein a monomer percentage of 3-hydroxybutyric acid in the poly(3-hydroxybutyric acid-co-3-hydroxyhexanoic acid) is from 99.5 mol % to 85.0 mol %.
9. The method of claim 1 , wherein the polyhydroxyalkanoate has a melt flow rate of from 0.1 to 100 as measured at 160° C. under a load of 5 kg.
10. The method of claim 1 , wherein a hole area of the spinning die is from 0.03 mm 2 to 3.5 mm 2 .
11. A biodegradable aliphatic polyester fiber, comprising:
a polyhydroxyalkanoate;
a nucleating agent comprising pentaerythritol; and
a lubricant comprising at least one selected form the group consisting of behenic amide, stearic acid amide, erucamide, and oleic amide,
wherein the biodegradable aliphatic polyester fiber is obtained by being spin drawn from a spinning die at a temperature of from 130° C. to 190° C., then being taken up by a first take-up roll at a take-up speed of from 300 m/min to 4,000 m/min, and continuously being taken up by a second take-up roll at a take-up speed of from 600 m/min to 7,000 m/min.
12. The method of claim 1 , wherein the take-up speed at the first take-up roll is from 600 m/min to 2,000 m/min, and the take-up speed at the second take-up roll is from 1,800 m/min to 4,000 m/min.