Granted Patent B2

US 10,808,167 · App. 16/311,137 · Granted Oct 20, 2020

Inventors: Aaron M. Beuterbaugh (Spring, TX); Enrique Antonio Reyes (Tomball, TX)

Assignee: HALLIBURTON ENERGY SERVICES

C09K8/80C09K8/88C09K8/94E21B43/26C08L67/02C08L67/04

Abstract

Claims (32)

1. A method of propping a fracture, the method comprising:

providing a treatment fluid comprising a polyester, a water-miscible solvent, and a proppant;

then pumping the treatment fluid through an aqueous fluid within a wellbore to form an amorphous polymeric web;

then pumping the amorphous polymeric web and the proppant into the fracture within a subterranean formation; and

then allowing the amorphous polymeric web to dissolve.

2. The method of claim 1 , wherein the polyester is selected from the group consisting of poly(lactide), poly(glycolide), poly(e-caprolactone), poly(hydroxybutyrate), poly(orthoester), a copolymer thereof, a derivative thereof, and a combination thereof.

3. The method of claim 1 , wherein the water-miscible solvent is selected from the group consisting of acetonitrile, dimethylformamide, methyl ethyl ketone, tetrhydrofuran, pyridine, N-methyl-2-pyrrolidone, dimethyl sulfoxide, butyrolactone, hexafluroro-2-propanol, acetic acid, formic acid, ethyl acetate, acetone, glycol, glycerol, tetrahydrofuran, dioxane, dichloromethane, methanol, acetonitrile, diethyl ether, benzene, toluene, trifluoroacetic acid, hexafluoro-2-propanol, dichloromethane, chloroform, carbon tetrachloride, pentane, hexane, heptane, octane, halogenated derivatives thereof, alkylated derivatives thereof, isomers thereof, or any mixture thereof.

4. The method of claim 1 , wherein the proppant comprises sand, natural sand, quartz sand, bauxite, ceramic materials, glass materials, particulate garnet, metal particulates, nylon pellets, polymer materials, polytetrafluoroethylene materials, nut shell pieces, seed shell pieces, fruit pit pieces, wood, silica, alumina, fumed carbon, carbon black, graphite, mica, titanium dioxide, meta-silicate, calcium silicate, kaolin, halloysite, nacrite, smectite, saponite, sepiolite montmorillonite, talc, zirconia, boron, slag, fly ash, hollow glass microspheres, solid glass, microparticulates, or combinations thereof.

5. The method of claim 1 , wherein the concentration of the proppant in the treatment fluid ranges from about 0.1% by weight of the treatment fluid to about 50% by weight of the treatment fluid.

6. The method of claim 1 , wherein the proppant has a particle size in a range of about 0.1 μm to about 100 μm.

7. The method of claim 1 , wherein the proppant has a particle size in a range of about 200 μm to about 5 mm.

8. The method of claim 1 , wherein the treatment fluid is foamed.

9. A method of propping a fracture, the method comprising:

providing a treatment fluid comprising a polyester, a water-miscible solvent, and a proppant;

then mixing the treatment fluid with an aqueous fluid to form an amorphous polymeric web at the surface;

then pumping the amorphous polymeric web and the proppant into a wellbore;

then pumping the amorphous polymeric web and the proppant into the fracture within a subterranean formation;

then allowing the amorphous polymeric web to dissolve.

10. The method of claim 9 , wherein the polyester is selected from the group consisting of poly(lactide), poly(glycolide), poly(e-caprolactone), poly(hydroxybutyrate), poly(orthoester), a copolymer thereof, a derivative thereof, and a combination thereof.

11. The method of claim 9 , wherein the water-miscible solvent is selected from the group consisting of acetonitrile, acetic acid, formic acid, ethyl acetate, acetone, glycol, glycerol, tetrahydrofuran, dioxane, dichloromethane, methanol, and a combination thereof.

12. The method of claim 9 , wherein the proppant comprises sand, natural sand, quartz sand, bauxite, ceramic materials, glass materials, particulate garnet, metal particulates, nylon pellets, polymer materials, polytetrafluoroethylene materials, nut shell pieces, seed shell pieces, fruit pit pieces, wood, silica, alumina, fumed carbon, carbon black, graphite, mica, titanium dioxide, meta-silicate, calcium silicate, kaolin, halloysite, nacrite, smectite, saponite, sepiolite montmorillonite, talc, zirconia, boron, slag, fly ash, hollow glass microspheres, solid glass, microparticulates, or combinations thereof.

13. The method of claim 9 , wherein the concentration of the proppant in the treatment fluid ranges from about 0.1% by weight of the treatment fluid to about 50% by weight of the treatment fluid.

14. The method of claim 9 , wherein the proppant has a particle size in a range of about 0.1 μm to about 100 μm.

15. The method of claim 9 , wherein the proppant has a particle size in a range of about 200 μm to about 5 mm.

16. The method of claim 9 , wherein the treatment fluid is foamed.

17. A system for propping a fracture, the system comprising:

a treatment fluid comprising an amorphous polymeric web, a water-miscible solvent, and a proppant;

a tubular; and

a pump capable of pumping the treatment fluid through the tubular and into the fracture.

18. The system of claim 17 , wherein the amorphous polymeric web is formed from a polyester selected from the group consisting of poly(lactide), poly(glycolide), poly(e-caprolactone), poly(hydroxybutyrate), poly(orthoester), a copolymer thereof, a derivative thereof, and a combination thereof.

19. The system of claim 17 , wherein the water-miscible solvent is selected from the group consisting of acetonitrile, acetic acid, formic acid, ethyl acetate, acetone, glycol, glycerol, tetrahydrofuran, dioxane, dichloromethane, methanol, and a combination thereof.

20. The system of claim 17 , wherein the concentration of the proppant in the treatment fluid ranges from about 0.1% by weight of the treatment fluid to about 50% by weight of the treatment fluid.

Assignments (1)

Continuity (1)

Cited By (9)

US 12,365,828 US 12,466,992 US 12,521,764 US 12,540,273 US 12,637,611 US 12,649,875 US 12,650,066 US 12,662,624 US 12,674,380