IP Library Granted Patent US 10,809,639
Granted Patent B2
US 10,809,639 · App. 16/670,352 · Granted Oct 20, 2020

Toner

Inventors: Kentaro Yamawaki (Mishima, JP); Satoshi Otsuji (Yokohama, JP); Masamichi Sato (Mishima, JP); Hidekazu Fumita (Gotemba, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/08782G03G9/0832G03G9/08711
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Quick Facts
Patent No.
US 10,809,639
App. No.
16/670,352
Granted
Oct 20, 2020
Kind
B2
Abstract

A toner having a toner particle including a binder resin and a wax, wherein the wax includes a specific diester compound; a proportion As of an area occupied by the wax in a region from a surface of the toner particle to 0.5 μm is 15.0% or less; wax domains are observed in the cross section of the toner particle, and an average number of the domains per cross section of one toner particle is from 10 to 2000; when a mass concentration of a polyvalent metal element in the toner particle determined by fluorescent X-ray analysis is denoted by Mi (ppm), Mi is from 3.5 ppm to 1100 ppm; and when a mass concentration of a polyvalent metal element in the toner particle determined by X-ray photoelectron spectroscopy is denoted by Ms (ppm), Mi>Ms.

Claims (15)

1. A toner comprising a toner particle including a binder resin and a wax, wherein

the wax includes at least one selected from the group consisting of diester compounds represented by following formulas (1) and (2);

when a proportion of an area occupied by the wax in a region from a surface of the toner particle to 0.5 μm in cross-sectional observation of the toner using a transmission electron microscope is denoted by As, As is 15.0% or less;

wax domains are observed in the cross section of the toner particle in cross-sectional observation of the toner using a transmission electron microscope, and an average number of the domains per cross section of one toner particle is from 10 to 2000;

when a mass concentration of a polyvalent metal element in the toner particle determined by fluorescent X-ray analysis is denoted by Mi (ppm), Mi is from 3.5 ppm to 1100 ppm; and

when a mass concentration of a polyvalent metal element in the toner particle determined by X-ray photoelectron spectroscopy is denoted by Ms (ppm), the following expression:

Mi>Ms

is satisfied;

in the formulas (1) and (2), R 1 represents an alkylene group having from 1 to 6 carbon atoms, and R 2 and R 3 each independently represent a linear alkyl group having from 11 to 25 carbon atoms.

2. The toner according to claim 1 , wherein

the binder resin has a carboxy group; and

the polyvalent metal element is at least one selected from the group consisting of iron, aluminum, copper, zinc, magnesium, and calcium.

3. The toner according to claim 2 , wherein the polyvalent metal element is aluminum, and a Net intensity based on the aluminum measured by fluorescent X-ray analysis is from 0.10 kcps to 0.50 kcps.

4. The toner according to claim 2 , wherein the polyvalent metal element is iron, and a Net intensity based on the iron measured by fluorescent X-ray analysis is from 1.00 kcps to 5.00 kcps.

5. The toner according to claim 2 , wherein the polyvalent metal element is magnesium or calcium, and a Net intensity based on the magnesium or calcium measured by fluorescent X-ray analysis is from 3.00 kcps to 20.00 kcps.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2020
From: YAMAWAKI, KENTARO; OTSUJI, SATOSHI; SATO, MASAMICHI; FUMITA, HIDEKAZU
To: CANON KABUSHIKI KAISHA
Reel/Frame 051622/0439 →
Priority Claims (1)
JP 2018-209766 · Nov 7, 2018 · national
Continuity (1)
Related Publication 20200142329A1 · May 7, 2020
Cited By (4)
US 12,210,317 US 12,405,545 US 12,429,790 US 12,474,649