Promoted ammonium salt-protected activated carbon sorbent particles for removal of mercury from gas streams
Promoted ammonium salt-protected activated carbon sorbent particles for removal of mercury from gas streams. A method of separating mercury from a mercury-containing gas stream includes contacting a mercury-containing gas stream with an activated carbon sorbent including promoted ammonium salt-protected activated carbon sorbent particles, to form a mercury-sorbent composition. The method also includes separating at least some of the mercury-sorbent composition from the mercury-containing gas stream, to give a separated gas.
1. A method for separating mercury from a mercury-containing gas stream, the method comprising:
combusting coal in a combustion chamber, to provide the mercury-containing gas stream comprising Br − , HBr, HI, I − or a combination thereof, wherein
the coal comprises an additive comprising Br 2 , a bromide, HBr, I 2 , an iodide, HI, or a combination thereof, added to the coal before the coal enters the combustion chamber, or
the combustion chamber comprises an additive comprising Br 2 , a bromide, HBr, I 2 , an iodide, HI, or a combination thereof, or
a combination thereof;
injecting an ammonium salt into the mercury-containing gas stream;
injecting activated carbon sorbent into the mercury-containing gas stream at or downstream of the injection of the ammonium salt into the mercury-containing gas stream, to add the Br − , HBr, HI, I − or the combination thereof from the mercury-containing gas stream to the activated carbon, wherein the Br − , HBr, HI, I − , or the combination thereof is 0.1 wt % to 30 wt % of the activated carbon sorbent in the mercury-containing gas stream;
contacting the mercury-containing gas stream with the activated carbon sorbent, to form a mercury-sorbent composition; and
separating at least some of the mercury-sorbent composition from the mercury-containing gas stream, to give a separated gas.
2. The method of claim 1 , wherein the mercury-containing gas stream further comprises an added mercury-stabilizing reagent selected from the group consisting of S, Se, H 2 S, SO 2 , H 2 Se, SeO 2 , CS 2 , P 2 S 5 , and combinations thereof.
3. The method of claim 1 , wherein at or downstream of the injection of the activated carbon into the mercury-containing gas stream, the activated carbon comprises ammonia, the ammonium salt, or a combination thereof.
4. The method of claim 1 , wherein at or downstream of the injection of the activated carbon into the mercury-containing gas stream, the activated carbon comprises an anionic counterion of the ammonium salt.
5. The method of claim 1 , wherein the additive comprises HBr, HI, Br 2 , BrCl, IBr, ICl, PBr 3 , Al 2 Br 6 , FeI x (x =1, 2, 3, or 4), FeBr y (y=1, 2, 3, or 4), MnBr 2 , NiBr 2 , NiI 2 , ZnBr 2 , ZnI 2 , NH 4 Br, NH 4 I, NH 4 F, or a combination thereof.
6. The method of claim 1 , wherein the additive comprises NaBr, NaI, Br′,I′, KI, LiBr, CuBr 2 , AgBr, CHI 3 , CH 3 Br, AuBr, FeI x (x=1, 2, 3, or 4), FeBr y (y=1, 2, 3, or 4), MgBr 2 , MnBr 2 , NiBr 2 , NiI 2 , ZnBr 2 , ZnI 2 , CaBr 2 , or a combination thereof.
7. The method of claim 1 , further comprising
at or downstream of the injection of the activated carbon into the mercury-containing gas stream, protecting promoted activated carbon sorbent with the ammonium salt, or
at or downstream of the injection of the activated carbon into the mercury-containing gas stream, protecting unpromoted activated carbon sorbent with the ammonium salt to form unpromoted ammonium salt-protected activated carbon sorbent, and promoting the unpromoted ammonium salt-protected activated carbon sorbent, or
a combination thereof.
8. The method of claim 1 , wherein the ammonium salt is an ammonium halide, a methylammonium halide, an ammonium salt of an oxyacid of a Group VI element, an ammonium salt of an oxyacid of a Group V element, or a combination thereof.
9. The method of claim 1 , wherein the ammonium salt is ammonium bromide, ammonium iodide, ammonium chloride, an organic halide with a formula of CH 3 NH 3 X (wherein X is Cl, Br or I), ammonium sulfate, ammonium hydrogen sulfate, ammonium sulfite, ammonium hydrogen sulfite, ammonium persulfate, ammonium pyrosulfate, ammonium thiosulphate, ammonium dithionite, ammonium aluminium sulfate, ammonium iron sulfate, ammonium sulfamate, ammonium phosphate, diammonium phosphate, ammonium hydrogen phosphate, ammonium dihydrogen phosphate, ammonium thiophosate, ammonium nitrate, ammonium nitrite, ammonium carbonate, ammonium thiocyanate, ammonium sulfide, ammonium hydrogen sulfide, ammonium acetate, ammonium carbamate, ammonium carbonate, ammonium chlorate, ammonium chromate, ammonium fluoride, ammonium formate, ammonium hydroxide, ammonium perchlorate, or a combination thereof.
10. A method for separating mercury from a mercury-containing gas stream, the method comprising:
combusting coal in a combustion chamber, to provide the mercury-containing gas stream comprising Br′, HBr, or a combination thereof, wherein
the coal comprises an NaBr additive, a CaBr 2 additive, or a combination thereof, added to the coal before the coal enters the combustion chamber, or
the combustion chamber comprises an NaBr additive, a CaBr 2 additive, or a combination thereof, or
a combination thereof;
injecting ammonium bromide, ammonium sulfate, or a combination thereof into the mercury-containing gas stream;
injecting activated carbon sorbent into the mercury-containing gas stream at or downstream of the injection of the ammonium bromide or ammonium sulfate into the mercury-containing gas stream, to add the Br − , HBr, or the combination thereof from the mercury-containing gas stream to the activated carbon, wherein the Br − , HBr, or the combination thereof is 0.1 wt % to 30 wt % of the activated carbon sorbent in the mercury-containing gas stream;
contacting a mercury-containing gas stream with the activated carbon sorbent, to form a mercury-sorbent composition; and
separating at least some of the mercury-sorbent composition from the mercury-containing gas stream, to give a separated gas.
11. The method of claim 1 , wherein at or downstream of the injection of the activated carbon into the mercury-containing gas stream, the activated carbon sorbent comprises
active sites that bind with mercury atoms, wherein the active sites comprise carbocations bound to I − , Br − , or a combination thereof, and
ammonia, an ammonium salt, an anionic counterion of the ammonium salt, or a combination thereof, in at least a surface layer thereof.
12. The method of claim 1 , further comprising
subjecting a mixture comprising the activated carbon sorbent and the ammonium salt to heating, microwaving, irradiation, or a combination thereof, wherein the injecting of the activated carbon and the ammonium salt into the mercury-containing gas comprises injecting the heated, microwaved, or irradiated mixture of the activated carbon sorbent and the ammonium salt together into the mercury-containing gas.
13. The method of claim 1 , wherein the ammonium salt comprises an ammonium halide, wherein the additive on the coal or in the combustion chamber comprises CaBr 2 , NaBr, CaI 2 , KI, NaI, or a combination thereof.
14. The method of claim 1 , wherein the ammonium salt comprises ammonium bromide, wherein the additive on the coal or in the combustion chamber comprises CaBr 2 , NaBr, CaI 2 , KI, NaI, or a combination thereof.
15. A method for separating mercury from a mercury-containing gas stream, the method comprising:
combusting coal in a combustion chamber, to provide the mercury-containing gas stream comprising Br − , HBr, HI, I − or a combination thereof, wherein
the coal comprises an additive comprising Br 2 , a bromide, HBr, I 2 , an iodide, HI, or a combination thereof, added to the coal before the coal enters the combustion chamber, or
the combustion chamber comprises an additive comprising Br 2 , a bromide, HBr, I 2 , an iodide, HI, or a combination thereof, or
a combination thereof;
injecting an ammonium salt into the mercury-containing gas stream;
injecting activated carbon sorbent into the mercury-containing gas stream at or downstream of the injection of the ammonium salt into the mercury-containing gas stream, to add the Br − , HBr, HI, I − , or the combination thereof from the mercury-containing gas stream to the activated carbon, wherein the Br − , HBr, HI, I − , or the combination thereof is 1 wt % to 30 wt % of the activated carbon sorbent in the mercury-containing gas stream;
contacting the mercury-containing gas stream with the activated carbon sorbent, to form a mercury-sorbent composition; and
separating at least some of the mercury-sorbent composition from the mercury-containing gas stream, to give a separated gas.
16. The method of claim 1 , further comprising:
modifying, in response to a measured mercury content,
an injection rate of injecting the activated carbon sorbent into the mercury-containing gas stream.