Porous film and lithium-ion battery
The application provides a porous film and a lithium-ion battery. The porous film according to the present application has excellent adhesion, and the pore structure of the porous film can still be well maintained after being immersed in the electrolyte, thereby reducing the probability of pore blockage of the porous film and allowing the lithium-ion battery to have high ionic conductivity. Therefore, the rate performance of the lithium-ion battery is greatly improved, and the lithium-ion battery provided has excellent rate performance and cycle performance.
1. A porous film, comprising:
a binder; and
inorganic particles;
wherein the porous film comprises pores formed by the binder, the pores at least comprises a part of the inorganic particles, and the average wall thickness between the pores is in a range of 20 nm to 500 nm, wherein the inorganic particles have particle sizes that Dv10 is in a range of 0.015 μm to 3 μm, Dv50 is in a range of 0.2 μm to 5 μm, Dv90 is in a range of 1 μm to 10 μm; Dv10 is less than Dv50, and Dv50 is less than Dv90; and the ratio of Dv90 to Dv10 is in a range of 2 to 100.
2. The porous film according to claim 1 , wherein the porous film has an average pore size of 0.3 μm to 20 μm.
3. The porous film according to claim 1 , wherein a pore size distribution coefficient of the pores in the porous film is in a range of 1 to 5.
4. The porous film according to claim 1 , wherein the inorganic particles are at least one of alumina, silica, magnesia, titanium oxide, hafnium dioxide, tin oxide, cerium dioxide, nickel oxide, zirconia, zinc oxide, calcium oxide, boehmite, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, and barium sulfate.
5. The porous film according to claim 1 , wherein the binder is at least one of polyvinylidene fluoride, vinylidene fluoride-hexafluoropropylene copolymer, polyamide, polyacrylonitrile, polyacrylate, polyacrylic acid, polyacrylic acid salt, sodium carboxymethylcellulose, polyvinylpyrrolidone, polyvinyl ether, polymethyl methacrylate, polytetrafluoroethylene and polyhexafluoropropylene.
6. The porous film according to claim 1 , wherein the porous film has a porosity of 20% to 90%, and the porous film has a thickness of 0.2 to 10 μm.
7. The porous film according to claim 1 , wherein a volume ratio of the inorganic particles to the binder is in a range of 0.2 to 3.0.