IP Library Granted Patent US 10,866,513
Granted Patent B2
US 10,866,513 · App. 15/739,808 · Granted Dec 15, 2020

Photocurable resin composition

Inventors: Takuya Ohashi (Toyama, JP); Tomoyuki Enomoto (Toyama, JP)
Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.
G03F7/0384C08F290/046C08F290/061C08F290/062C08F290/065C08F299/00C08J3/24C09D4/06C09D151/08C09J151/08G03F7/0005G03F7/038G03F7/039G03F7/0388G03F7/162G03F7/168G03F7/2004G03F7/32G03F7/38C08L67/07
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Quick Facts
Patent No.
US 10,866,513
App. No.
15/739,808
Granted
Dec 15, 2020
Kind
B2
Abstract

A novel photocurable resin composition including: a polymer with a weight average molecular weight of 1,000 to 50,000, the polymer having a structural unit of formula (1), and having a structure of formula (2) at an end: wherein X is a C 1-6 alkyl group, vinyl group, allyl group, or glycidyl group; m and n are each independently 0 or 1; Q is a divalent hydrocarbon group having a carbon atom number of 1 to 16; Z is a divalent linking group having a carbon atom number of 1 to 4, wherein the divalent linking group is attached to the —O— group in formula (1); and R 1 is a hydrogen atom or methyl group; a radical photopolymerization initiator; and a solvent.

Claims (19)

1. A photocurable resin composition comprising:

a polymer with a weight average molecular weight of 1,000 to 50,000, the polymer having a structural unit of formula (1), and having a terminal end-group structure of formula (2):

wherein

X is a methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, i-butyl group, s-butyl group, t-butyl group, n-pentyl group, 1-methyl-n-butyl group, 2-methyl-n-butyl group, 3-methyl-n-butyl group, 1,1-dimethyl-n-propyl group, 1,2-dimethyl-n-propyl group, 2,2-dimethyl-n-propyl group, 1-ethyl-n-propyl group, n-hexyl group, 1-methyl-n-pentyl group, 2-methyl-n-pentyl group, 3-methyl-n-pentyl group, 4-methyl-n-pentyl group, 1,1-dimethyl-n-butyl group, 1,2-dimethyl-n-butyl group, 1,3-dimethyl-n-butyl group, 2,2-dimethyl-n-butyl group, 2,3-dimethyl-n-butyl group, 3,3-dimethyl-n-butyl group, 1-ethyl-n-butyl group, 2-ethyl-n-butyl group, 1,1,2-trimethyl-n-propyl group, 1,2,2-trimethyl-n-propyl group, 1-ethyl-1-methyl-n-propyl group, 1-ethyl-2-methyl-n-propyl group, —CH═CH 2 , —CH 2 —CH═CH 2 , or

m and n are each independently 0 or 1;

Q is a divalent hydrocarbon group having a carbon atom number of 1 to 16;

Z is a divalent linking group having a carbon atom number of 1 to 4, wherein the divalent linking group is attached to the —O— group in formula (1); and

R 1 is a hydrogen atom or methyl group;

a radical photopolymerization initiator; and

a solvent.

2. The photocurable resin composition according to claim 1 , wherein the divalent hydrocarbon group of Q in formula (1) is a linear or branched alkylene group, a group containing two carbon atoms connected by a double bond, or a group containing, in a main chain, an alicyclic hydrocarbon group or aromatic hydrocarbon group optionally having at least one substituent.

3. The photocurable resin composition according to claim 1 , wherein the divalent linking group of Z in formula (2) is a linear or branched alkylene group optionally having at least one hydroxy group as a substituent.

4. The photocurable resin composition according to claim 1 , further comprising a bifunctional (meth)acrylate and/or a polyfunctional thiol.

5. The photocurable resin composition according to claim 1 , which is for use as an adhesive or a lens material.

6. A method for forming a film comprising the steps of:

applying the photocurable resin composition according to claim 1 onto a substrate;

pre-baking the photocurable resin composition applied onto the substrate at a temperature of 50 to 160° C.;

exposing a coating film formed on the substrate after the pre-baking to light;

and developing the coating film.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 26, 2017
From: OHASHI, TAKUYA; ENOMOTO, TOMOYUKI
To: NISSAN CHEMICAL INDUSTRIES, LTD.
Reel/Frame 044482/0330 →
Priority Claims (1)
JP 2015-129172 · Jun 26, 2015 · national
Continuity (1)
Related Publication 20180362696A1 · Dec 20, 2018