Barrier elements on a microstructured article having adhesive sealing layer and specified modulus of elasticity
The disclosed light directing article comprises a structured layer, an adhesive sealing layer, and barrier elements. The structured layer comprises multiple microstructured elements that are opposite a major surface. The adhesive sealing layer has a first region and a second region. The second region is in contact with the structured layer. The barrier element are at the first region. The first region with the barrier element and second region have sufficiently different properties to form a low refractive index layer between the adhesive sealing layer and the structured layer. The barrier element comprises a crosslinked polymeric matrix having a modulus of elasticity less than 4.4 GPa.
1. A light directing article, comprising:
a structured layer comprising multiple microstructured elements that is opposite a major surface;
an adhesive sealing layer having a first region and a second region wherein the second region is in contact with the structured layer; and
a plurality of barrier elements;
wherein at least one barrier element is in direct contact with both the first region of the adhesive sealing layer and the structured layer;
wherein the first region with the barrier element and second region have sufficiently different properties to form a low refractive index layer between the adhesive sealing layer and the structured layer;
wherein each barrier element comprises a crosslinked polymeric matrix having a modulus of elasticity less than 4.4 GPa and greater than 0.5 GPa.
2. The light directing article of claim 1 , where in the hardness of the crosslinked polymeric matrix is less than 370 MPa.
3. The light directing article of claim 1 , where in the hardness of the crosslinked polymeric matrix is greater than 5 MPa.
4. The light directing article of claim 1 , wherein the barrier element comprises a crosslinked polymeric matrix having a thickness greater than 1.6 microns.
5. The light directing article of claim 1 , wherein the barrier element comprises a crosslinked acrylate polymeric matrix.
6. The light directing article of claim 5 , wherein the crosslinked acrylate polymeric matrix is one of a urethane acrylate, acrylic acrylate, epoxy acrylate, or polyester acrylate.
7. The light directing article of claim 1 , wherein the barrier element comprises the reaction product of:
an acrylate polymer with at least two acrylate groups;
a photoinitiator;
wherein the reaction product mixture has a viscosity of greater than 100 and less than 2000 cPS.
8. The light directing article of claim 1 , wherein the barrier element comprises the reaction product of:
an acrylate polymer with at least two acrylate groups;
a diluent;
a photoinitiator;
wherein the reaction product mixture has a viscosity of greater than 300 and less than 1500 cPS.
9. The light directing article of claim 1 , wherein the adhesive sealing layer comprises a pressure sensitive adhesive that is in intimate contact with the microstructured elements of the structured layer.
10. The light directing article of claim 1 , wherein the adhesive sealing layer comprises a structural adhesive with legs and a base forming a well, wherein the legs of the structured adhesive are in intimate contact with the microstructured elements of the structured layer and at least one barrier element is in the well.
11. The light directing article of claim 1 , wherein the adhesive sealing layer is transparent.
12. The light directing article of claim 1 , wherein the adhesive sealing layer is opaque.
13. The light directing article of claim 1 , wherein the first region is surrounded by the second region.
14. The light directing article of claim 1 , wherein the barrier element has sufficient structural integrity to substantially prevent flow of the pressure sensitive adhesive into the low refractive index layer.
15. The light directing article of claim 1 , including multiple optically active areas and multiple optically inactive areas and at least some of the optically inactive areas and optically active areas form a pattern.
16. A method of making the light directing article of claim 1 .