Plugging agent with temperature-resistant, salt-resistant and high-expansion for plugging large fractures and preparation method thereof
A plugging agent with temperature-resistant, salt-resistant and high-expansion for plugging large fractures and a preparation method thereof of the present disclosure are provided, the plugging agent system consists of the following components: main agent: 6%˜10%, cross-linking agent: 0.6%˜1%, initiator: 0.006%˜0.01%, additive: 6%˜14%, and the rest being water; the preparation method includes the following steps: adding montmorillonite to water to prepare a montmorillonite dispersion system; adding the main agent, the cross-linking agent and the initiator to the montmorillonite dispersion system to prepare a main agent solution; putting the main agent solution into an oven with a temperature range with 90˜20° C. for 9˜48 h to obtain gelation, the adhesive strength of the agent system can reach grade H, with 50˜80 expansion multiple, good strength after being expanded and good water plugging effect under the condition of a temperature of 140° C. and 250,000 degree of mineralization.
1. A plugging agent with temperature-resistant, salt-resistant and high-expansion for plugging large fractures, consisting of the following raw materials by mass ratio:
main agent: 6%˜10%,
cross-linking agent: 0.6%˜1%
initiator: 0.006%˜0.01%,
additive: 6%˜14%, and
the rest being water; and wherein
the main agent is composed of monomer 1 and acrylamide with an equal mass ratio, the monomer 1 is a mixture of acrylic acid and 2-acrylamide-2-methylpropylsulfonic acid; the additive is montmorillonite, the cross-linking agent is phenolic cross-linking agent prepared by phenol and formaldehyde at a mass ratio of 1:9, and the initiator is azo initiator.
2. A preparation method of the plugging agent with temperature-resistant, salt-resistant and high-expansion for plugging large fractures as claimed in claim 1 , wherein the method comprises the following steps:
A1, preparing a montmorillonite dispersion system: slowly adding the montmorillonite to stirred water and stirring for 4 h˜5 h at a stirring speed of 200˜300 r/min to obtain the montmorillonite dispersion system;
A2, preparing a main agent solution: adding the main agent, the cross-linking agent and the initiator to the montmorillonite dispersion system and then stirring evenly to obtain the main agent solution; and
A3, preparing a plugging agent: putting the main agent solution into an aging tank to be sealed, and then placing the aging tank under a temperature condition with 90˜120° C. to gelatinize for 9˜48 hours, so as to obtain the plugging agent with temperature-resistant, salt-resistant and high-expansion for plugging large fractures.