Biocide formulation and method for treating water
The present invention provides a biocide formulation comprising a biocide in a micelle, wherein the micelle comprises a block copolymer having a biocide-solubilizing part and a water-soluble part, and a quaternary ammonium stabilizing compound. The present invention also provides a method for controlling microorganisms by eliminating and/or preventing biofilm formation in an aqueous environment.
1. A biocide formulation comprising a biocide in a micelle, wherein the micelle comprises:
a block copolymer wherein the block copolymer is a poloxamer, and
a quaternary ammonium stabilizing compound wherein the quaternary ammonium stabilizing compound is selected the group consisting of n-alkyl dimethyl benzyl ammonium chloride, alkenyl dimethylethyl ammonium chloride, didecyldimethylammonium chloride (DDAC) and dimethyldioctadecylammonium bromide (DDAB),
wherein the biocide is selected from the group consisting of 2,2-dibromo-3-nitrilopropionamide (DBNPA) and 2-bromo-2-nitropropane-1,3-diol.
2. The biocide formulation of claim 1 , further comprising a membrane permeabilizer, wherein the membrane permeabilizer comprises a chelating agent or a cationic polyelectrolyte or both,
wherein the cationic polyelectrolyte is selected from the group consisting of poly(diallyldimethylammonium chloride) (PDADMAC), polyethyleneimine (PEI), polyetheramines and polyamines.
3. The biocide formulation of claim 2 , wherein it is present as a two-component formulation comprising a first component comprising the membrane permeabilizer and a second component comprising the biocide, the block copolymer and the quaternary ammonium stabilizing compound wherein the first component and the second component are arranged to be combined prior adding or dosing to an aqueous environment.
4. The biocide formulation of claim 1 , comprising about 10-25% (w/w) of the biocide.
5. The biocide formulation of claim 1 , comprising from 15 to 50% (w/w) of the block copolymer.
6. The biocide formulation of claim 1 , comprising about 5-30% (w/w) of the quaternary ammonium stabilizing compound.
7. A method for controlling biofilms by eliminating and/or preventing microorganisms in an aqueous environment, wherein the method comprises providing the biocide formulation of claim 1 , and dosing said biocide formulation to the aqueous environment.
8. The method of claim 7 , wherein the aqueous environment is an industrial water system.
9. The method of claim 8 , wherein the industrial water system is selected from papermaking systems, cooling water systems including cooling towers, open and closed loop cooling units, industrial raw water systems, drinking water distribution systems, sanitizing drinking water system, oil production or recovery systems including oil field water systems, drilling fluids, fuel storage systems, metal working systems, heat exchangers, reactors, equipment used for storing and handling liquids, boilers including steam generating units, radiators, flash evaporating units, refrigeration units, reverse osmosis equipment, gas scrubbing units, blast furnaces, sugar evaporating units, steam power plants, geothermal units, nuclear cooling units, water treatment units, pool recirculating units, mining circuits, closed loop heating units, machining fluids used in operations including drilling, boring, milling, reaming, drawing, broaching, turning, cutting, sewing, grinding, thread cutting, shaping, spinning and rolling, hydraulic fluids, and cooling fluids.
10. The method of claim 8 , wherein the industrial water system is selected from circulating water of a pulp, paper or cardboard machine, and industrial raw water.
11. The method of claim 7 , wherein the biocide formulation is dosed to a concentration of 0.3-50 ppm.
12. The method of claim 11 , wherein the biocide formulation is dosed to a concentration of 1-5 ppm.