Superhydrophobic and self-cleaning radiative cooling film and preparation method thereof
Disclosed are a superhydrophobic and self-cleaning radiative cooling film and a preparation method thereof. The preparation method includes the following steps: 1) dissolving P (VDF x -HFP y ) and PDMS in a composite polar solvent to obtain a translucent composite polymer solution of P (VDF x -HFP y )/PDMS; 2) adding a non-solvent dropwise to the obtained solution to allow for a phase separation of P (VDF x -HFP y )/PDMS to form a sol; 3) casting the sol; drying the cast sol to obtain a film are porous inside with micro/nano rough structures of low surface-energy on the surface. The preparation method of the present invention is simple, and can be used for large-scale production.
1. A method for preparing a superhydrophobic and self-cleaning radiative cooling film, comprising:
1) dissolving Poly (vinylidene fluoride-co-hexafluoropropylene) P (VDFx-HFPy) and polydimethylsiloxane (PDMS) in a composite polar solvent to obtain a translucent composite polymer solution of P (VDFx-HFPy)/PDMS;
2) adding a non-solvent dropwise to the obtained solution to allow for a phase separation of P (VDFx-HFPy)/PDMS to form a sol; and
3) casting the sol; drying the cast sol to obtain a film with a micro-nano porous structure; and
wherein the superhydrophobic and self-cleaning radiative cooling film with a micro-nano porous structure has a solar reflectance of 90.1-96.5% and a mid-infrared emissivity of 90.3-94.3% at thickness of 8-13 μm; a water contact angle on a surface of the film is 151.4-162.3°; and a water sliding angle on the surface of the film is 1.4-8.2°.
2. The method of claim 1 , wherein step 1 further comprises:
101) dissolving P (VDFx-HFPy) in an acetone solution under stirring at room temperature for 3-5 h until P (VDFx-HFPy) is completely dissolved in the acetone solution to produce a mixture;
102) adding a prepolymer A for PDMS and a tetrahydrofuran solvent to the resulting mixture in step 101) and stirring uniformly;
103) adding a curing agent B under stirring for 15-30 min until the resulting solution is uniform and translucent.
3. The method of claim 2 , wherein in step 101, a weight ratio of P (VDFx-HFPy) to acetone is 1:10-15.
4. The method of claim 2 , wherein in step 102, a weight ratio of P (VDF x -HFPy) to tetrahydrofuran is 1-2:15.
5. The method of claim 2 , wherein in step 103, a weight ratio of P (VDF x -HFPy) to PDMS is 2.0-4.0:1.0.
6. The method of claim 1 , wherein in step 2, the non-solvent is water, and an adding rate of the water is 0.05 mL per 10 s.
7. The method of claim 6 , wherein a weight ratio of P (VDF x -HFPy) to the water is 7:12-6.
8. The method of claim 1 , wherein in step 3, the sol is dried at room temperature for 3-5 h.