Antibacterial medical product and method for producing same
The present invention relates to a medical product, comprising an antibacterial hard material coating, which is applied to a main body and which comprises biocide. Said hard material coating includes at least one inner layer and one outer layer, wherein the biocide concentration in the outer layer is substantially constant and greater than the biocide concentration in the inner layer and the biocide concentration in the inner layer is greater than or equal to 0.2 at %.
1. A method of applying a hard material coating on a main body of a medical product by a physical vapor deposition process, comprising first depositing a biocide-free material applied from a first target via arc ion plating onto the main body, and then depositing a biocide-containing material applied from a second target via magnetron sputter ion plating onto the biocide-free material, wherein the method is conducted at a temperature of less than or equal to 300° C.
2. The method of claim 1 , wherein the method is conducted in an atmosphere comprising argon and nitrogen.
3. The method of claim 1 , wherein the method is conducted at a pressure of 0.02 mbar.
4. The method of claim 1 , further comprising depositing a bonding layer via arc ion plating on the main body prior to deposition of the hard material coating.
5. The method of claim 4 , wherein the bonding layer has a thickness of less than or equal to 0.3 μm.
6. The method of claim 1 , wherein the main body is subjected to mechanical or electro-chemical treatment prior to deposition of the hard material coating.
7. The method of claim 1 , wherein the hard material coating comprises an inner layer and an outer layer, wherein the inner layer is between the outer layer and the main body, the outer layer has a biocide concentration (bcI) of 2 at % to 15 at %, and the inner layer has a biocide concentration (bcII) that is greater than or equal to 0.2 at % and less than bcI.
8. The method according to claim 7 , wherein bcI and bcII are controlled by varying an arc current of the first target and/or by varying a sputtering power of the second target.
9. The method of claim 7 , wherein the outer layer is subjected to polishing, wet blasting, and/or lapping.
10. The method of claim 1 , the first target comprising titanium.
11. The method of claim 1 , the second target comprising silver.
12. The method according to claim 1 , wherein the hard material coating being applied comprises both biocide-free material applied from the first target via arc ion plating and biocide-containing material applied from the second target via magnetron sputter ion plating, wherein a biocide concentration in the hard material coating is controlled by varying an arc current applied to the first target and/or by varying a sputtering power applied to the second target.
13. The method according to claim 12 , wherein the biocide in the biocide-containing material applied from the second target is silver.